Search

Your search keyword '"Liu, Shunying"' showing total 1 results
Start Over Author "Liu, Shunying" Topic rhodium compounds Journal angewandte chemie
1 results on '"Liu, Shunying"'

1. An Ylide Transformation of Rhodium(I) Carbene: Enantioselective Three-Component Reaction through Trapping of Rhodium(I)-Associated Ammonium Ylides by β-Nitroacrylates.

Author

Ma, Xiaochu, Jiang, Jun, Lv, Siying, Yao, Wenfeng, Yang, Yang, Liu, Shunying, Xia, Fei, and Hu, Wenhao

Subjects
YLIDES, IONS, AMINE ylides, RHODIUM carbenes, RHODIUM compounds
Abstract

The chiral RhI-diene-catalyzed asymmetric three-component reaction of aryldiazoacetates, aromatic amines, and β-nitroacrylates was achieved to obtain γ-nitro-α-amino-succinates in good yields and with high diastereo- and enantioselectivity. This reaction is proposed to proceed through the enantioselective trapping of RhI-associated ammonium ylides by nitroacrylates. This new transformation represents the first example of RhI-carbene-induced ylide transformation. [ABSTRACT FROM AUTHOR]

Published
2014
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results