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Your search keyword '"Zeng, Yaxin"' showing total 2 results
Start Over Author "Zeng, Yaxin" Publication Year Range Last 3 years Journal angewandte chemie
2 results on '"Zeng, Yaxin"'

1. Rhodium‐Catalyzed Enantio‐ and Regioselective Allylation of Indoles with gem‐Difluorinated Cyclopropanes.

Author

Yang, Hui, Zeng, Yaxin, Song, Xiangyu, Che, Lin, Jiang, Zhong‐Tao, Lu, Gang, and Xia, Ying

Subjects
*ALLYLATION, *INDOLE compounds, *RHODIUM, *BIOCHEMICAL substrates, *FUNCTIONAL groups, *RHODIUM compounds
Abstract

The use of gem‐difluorinated cyclopropanes (gem‐DFCPs) as fluoroallyl surrogates under transition‐metal catalysis has drawn considerable attention recently but such reactions are restricted to producing achiral or racemic mono‐fluoroalkenes. Herein, we report the first enantioselective allylation of indoles under rhodium catalysis with gem‐DFCPs. This reaction shows exceptional branched regioselectivity towards rhodium catalysis with gem‐DFCPs, which provides an efficient route to enantioenriched fluoroallylated indoles with wide substrate scope and good functional group tolerance. [ABSTRACT FROM AUTHOR]

Published
2024
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