1. Ion Dynamics in Organic-Inorganic Composite Superionic Conductor Glasses.
- Author
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Asayama, Ryo, Kuwata, Naoaki, and Kawamura, Junichi
- Subjects
- *
SUPERIONIC conductors , *GLASS transition temperature , *ELECTRIC conductivity , *GLASS , *MOLECULAR dynamics , *CHEMICAL bonds - Abstract
Ionic conductivity of organic-inorganic composite superionic conductor glasses composed of AgI and alkylammoniumiodides is measured as a function of frequency, temperature and composition. A clear transition from insulator to superionic conductor is confirmed at the volume fraction [lowercase_phi_synonym] of AgI is about 35 %. The dc component of the conductivity is fitted to the σ∼([lowercase_phi_synonym]-[lowercase_phi_synonym]c)μ with [lowercase_phi_synonym]c=0.36, μ=2.5 for the present data. Near the percolation threshold, a power-law type frequency dependence of ωn (n∼0.67) is seen in mid frequency and ω1.0 at higher frequency corresponding to the constant loss region power-law is observed. The activation energies and preexponential factors derived from the temperature dependence increase from 0.3 to 0.7 eV approaching to the threshold. From these results, the ion dynamics in these glasses can be explained by the static site percolation theory at first approximation, but require the consideration on the chemical bond variation between the Ag and I modified by the organic ions. © 2006 American Institute of Physics [ABSTRACT FROM AUTHOR]
- Published
- 2006
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