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We describe an alternate way to estimate Broad Line Region (BLR) radii for type-1 AGN based on determination of physical conditions in the BLR under the assumption that the line emitting gas is photoionized by a central continuum source. We derive “diagnostic” intensity ratios involving UV lines Al iii λ 1860, Si iii ] λ 1892 and C iv λ 1549 which enable us to compute the ionizing photon flux, and hence BLR radius from the ionization parameter definition. We compare our estimates of BLR radii with values independently obtained from reverberation monitoring of H β and, in a few cases, of C iv λ 1549. We analyze the interpretation of the photoionization estimates in the 4D eigenvector 1 context, and discuss in some detail the case of 3C 390.3. For this object we are able to provide not only the ionizing photon flux, but also an estimate of density and ionization parameter from the measured diagnostic ratios. We also compare black hole masses obtained from this method with values derived from widely-applied correlations between mass, line broadening and luminosity. Good agreement is found for both radius and black hole mass comparisons.