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Many psychological researchers use some form of a visual diagram in their research processes. Model diagrams used with structural equation models (SEMs) and causal directed acyclic graphs (DAGs) can guide causal-inference research. SEM diagrams and DAGs share visual similarities, often leading researchers familiar with one to wonder how the other differs. This article is intended to serve as a guide for researchers in the psychological sciences and psychiatric epidemiology on the distinctions between these methods. We offer high-level overviews of SEMs and causal DAGs using a guiding example. We then compare and contrast the two methodologies and describe when each would be used. In brief, SEM diagrams are both a conceptual and statistical tool in which a model is drawn and then tested, whereas causal DAGs are exclusively conceptual tools used to help guide researchers in developing an analytic strategy and interpreting results. Causal DAGs are explicitly tools for causal inference, whereas the results of a SEM are only sometimes interpreted causally. A DAG may be thought of as a “qualitative schematic” for some SEMs, whereas SEMs may be thought of as an “algebraic system” for a causal DAG. As psychology begins to adopt more causal-modeling concepts and psychiatric epidemiology begins to adopt more latent-variable concepts, the ability of researchers to understand and possibly combine both of these tools is valuable. Using an applied example, we provide sample analyses, code, and write-ups for both SEM and causal DAG approaches.