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The stability of foams is commonly linked to the interfacial properties of the proteins and other surfactants used. This study aimed to use these relationships to explain differences in foam stability observed among similar beer samples from different breweries. The foam stability was different for each sample (Nibem foam stability ranged from 206 to 300 s), but ranking was similar for all three foaming methods used, thus independent of the method, gas, etc. Differences in foam stability were dominated by differences in coalescence, as illustrated by the correlation with the stability of single bubbles and thin liquid films. The differences in coalescence stability could not be explained by the measured interfacial properties (e.g. surface pressure, adsorption rate, dilatational modulus and surface shear viscosity), or the bulk properties (concentration, pH, ionic strength, viscosity), since they were similar for all samples. The drainage rates and disjoining pressure isotherms measured in thin liquid films were also similar for all samples, further limiting the options to explain the differences in foam stability using known arguments. The differences in coalescence stability of the thin films was shown to depend on the liquid in between the adsorbed layers of the thin film, using a modified capillary cell to exchange this liquid (to a buffer, or one of the other samples). This illustrates the need to review our current understanding and to develop new methods both for experimental study and theoretical description, to better understand foam stability in the future.

Neurodegenerative disorders (NDDs) are caused by progressive loss of functional neurons following the aggregation and fibrillation of proteins in the central nervous system. The incidence rate continues to rise alarmingly worldwide, particularly in aged population, and the success of treatment remains limited to symptomatic relief. Graphene nanomaterials (GNs) have attracted immense interest on the account of their unique physicochemical and optoelectronic properties. The research over the past two decades has recognized their ability to interact with aggregation-prone neuronal proteins, regulate autophagy and modulate the electrophysiology of neuronal cells. Graphene can prevent the formation of higher order protein aggregates and facilitate the clearance of such deposits. In this review, after highlighting the role of protein fibrillation in neurodegeneration, we have discussed how GN-protein interactions can be exploited for preventing neurodegeneration. A comprehensive understanding of such interactions would contribute to the exploration of novel modalities for controlling neurodegenerative processes.

Microgels are soft, deformable, permeable, and stimuli-responsive microscopic polymeric particles that are now emerging as prospective multifunctional soft materials for delivery systems, interface stabilization, cell cultures and tissue engineering. Cellulose microgels are emerging biopolymeric microgels with unique characteristics such as abound hydroxyl structure, admirable designability, multiscale pore network and excellent biocompatibility. This review summarizes the fabrication strategies for microgel, then highlights the fabrication routes for cellulose microgels, and finally elaborates cellulose microgels' bright application prospects with unique characteristics in the fields of controlled release, interface stabilization, coating, purification, nutrition/drug delivery, and bio-fabrication. The challenges to be addressed for further applications and considerable scope for development in future of cellulose microgels are also discussed.

The most effective corrosion inhibitors are organic compounds, especially heterocyclic ones with a certain balance of hydrophilicity, hydrophobicity, and conjugation. Most dyes develop the critical characteristics of a substance that can be utilized as an effective corrosion inhibitor. These include the presence of polar functional groups, nonbonding electrons and multiple bonds of the aromatic ring(s) and side chains. In aqueous electrolytes, dyes efficiently bind to metal surfaces through their electron-rich spots, known as adsorption centers. Literature studies show that many dye series have excellent anticorrosive properties for many metal/electrolyte combinations. They contain many electron-donating sites and behave as polydentate and chelating ligands. The polar functional for instance -OH, -CONH

Today, the development of multifunctional and versatile packaging materials based on green ingredients has received a lot of attention from researchers and consumers due to their biodegradability, biocompatibility, sustainability, and renewable nature of biomaterials. These emerging packaging materials in addition to increasing the shelf life of food products (active packaging), informs the consumer about the freshness and spoilage of the product in real-time (smart packaging). The limitations reported for biopolymers-based packaging, such as hydrophilicity and poor mechanical resistance, can be modified and improved by combining biopolymers with various materials including nanomaterials, cross-linkers, bioactive compounds, and other polymers. Consequently, the use of innovative, high performance, and green bio-nanocomposites reveal a promising opportunity to replace conventional non-biodegradable petroleum-based plastics. Likewise, interest in making polymeric bio-nanocomposites for active and smart packaging purposes has been increased in response to a global request for more effective and safe food packaging systems. There are various factors affecting the quality of bio-nanocomposites, such as biomaterials type, additives like nanoparticles, foods type, storage conditions, and the approaches for their preparation. In this review paper, we aimed to discuss the main challenges of the techniques commonly employed to prepare polymeric bio-nanocomposites, including casting, melt mixing (extrusion), electrospinning, and polymerization techniques. The casting has captured scientists' interest more than other techniques, due to the easy handling. The extrusion methods showed a more industrial approach than other techniques in this field. The electrospinning process has attracted a lot of interest due to the production of fibrous membranes, able to encapsulate and stabilize bioactive molecules. The polymerization technique shows less interest amongst scientists due to its complicated conditions, its reaction-based process and the use of toxic and not green reactants and solvents. In conclusion, all techniques should be optimized based on relevant specific parameters to obtain bio-nanocomposites with notable mechanical behaviors, barrier and permeability properties, contact angle/wettability, uniform structures, low cost of production, environmental-friendly nature, migration and penetration, and biodegradability features.

Impelled by the need to find solutions to new challenges of modern technologies new materials with unique properties are being explored. Among various new materials that emerged over the decades, magnetic fluids exhibiting interesting physiochemical properties (optical, thermal, magnetic, rheological, apparent density, etc.) under a magnetic stimulus have been at the forefront of research. In the initial phase, there has been a fervent scientific curiosity to understand the field-induced intriguing properties of such fluids but later a plethora of technological applications emerged. Magnetic nanofluid, popularly known as ferrofluid, is a colloidal suspension of fine magnetic nanoparticles, has been at the forefront of research because of its magnetically tunable physicochemical properties and applications. Due to their stimuli-responsive behaviour, they have been finding more applications in biology and other engineering disciplines in recent years. Therefore, a critical review of this topic highlighting the necessary background, the potential of this material for emerging technologies, and the latest developments is warranted. This review also provides a summary of various applications, along with the key challenges and future research directions. The first part of the review addresses the different types of magnetic fluids, the genesis of magnetic fluids, their synthesis methodologies, properties, and stabilization techniques are discussed in detail. The second part of the review highlights the applications of magnetic nanofluids and nanoemulsions (as model systems) in probing order-disorder transitions, scattering, diffraction, magnetically reconfigurable internal structures, molecular interaction, and weak forces between colloidal particles, conformational changes of macromolecules at interfaces and polymer-surfactant complexation at the oil-water interface. The last part of the review summarizes the interesting applications of magnetic fluids such as heat transfer, sensors (temperature, pH, urea detection, cations, defect detection sensors), tunable optical filters, removal of dyes, dynamic seals, magnetic hyperthermia-based cancer therapy and other biomedical applications. The applications of magnetic nanofluids in diverse disciplines are growing day by day, yet there are challenges in their practical adaptation as field-worthy or packaged products. This review provides a pedagogical description of magnetic fluids, with the necessary background, key concepts, physics, experimental protocols, design of experiments, challenges and future directions.

In recent years, the rapid development of microfluidic technology has caused a revolutionary impact in the fields of chemistry, medicine, and life sciences. Also, droplet control is one of the most important technologies in the field of microfluidics. In order to achieve different degrees of droplet transport, the dynamic balance of the competing processes of droplet driving force and fluid resistance should be controlled to achieve good selectivity of droplet transport. Here, we focus on the principles of droplet transport in microfluidic devices, including the driving forces for droplet transport in fluids and the effects of transport properties on droplet transport. After that, the effects of external fields on the directional transport of droplets and the advantages and disadvantages of each external field in droplet transport are discussed in detail. Finally, the applications and challenges of droplet microfluidics in chemical, biomedical, and mechanical systems are comprehensively introduced.

Halloysite nanotubes (HNTs) are naturally aluminosilicate clay minerals that have the benefits of large surface areas, high mechanical properties, easy functionalization, and high biocompatibility, HNTs have been developed as multifunctional nanoplatforms for various bioapplications. Although some reviews have summarized the properties and bioapplications of HNTs, it remains unclear how to functionalize the modifications of HNTs for their personalized bioapplications. In this review, based on the physicochemical properties of HNTs, we summarized the methods of functionalized modifications (surface modification and structure modification) on HNTs. Also, we highlighted their personalized bioapplications (anti-bacterial, anti-inflammatory, wound healing, cancer theranostics, bone regenerative, and biosensing) by stressing on the main roles of HNTs. Finally, we provide perspectives on the future of functionalized modifications of HNTs for docking specific biological applications.

Adequate intake of live probiotics can provide benefits to human health and wellbeing. However, free probiotics tend to lose their viability during the production, storage, and distribution of foods, as well as during their passage through the human gastrointestinal tract. A well-designed probiotic encapsulation system can enhance the viability of probiotics in foods and within the gastrointestinal tract, thereby ensuring more live bacteria reach the colon in an active form. This review summarizes the design of encapsulated probiotics and focuses on recent progress on the development of co-encapsulation systems containing mixed probiotics, mixtures of probiotics and prebiotics ("synbiotics"), or mixtures of probiotics and nutraceuticals ("nutrabiotics"). It then discusses the application of these co-encapsulation systems in functional foods, and highlights their potential benefits for human health, including regulating intestinal flora balance, safeguarding intestinal barrier integrity, maintaining immune homeostasis, and regulating blood glucose levels. Finally, challenges facing the large-scale commercialization of probiotic-loaded functional foods are discussed and suggestions for improving their performance are highlighted.

Fog on a solid surface is prejudicial to its optical properties and will even cause hygienic and safety concerns in some exceptional cases. Thus, antifogging coatings have attracted great interest in fundamental research and industry applications. Superhydrophilic and superhydrophobic coatings have been mainly explored and described in the antifogging field. In recent years, hygroscopic antifogging coatings of hydrophilic and hydrophobic parties have been introduced due to their unique properties. In this review, three antifogging mechanisms are reviewed to provide design strategies for antifogging surfaces. The current techniques for fabricating polymeric antifogging coatings are discussed in depth. The recent progress in materials and structures for antifogging surfaces is briefly summarize. Finally, the practical applications and outlooks related to multifunctional antifogging coatings are mentioned.

Nanotechnological drug delivery platforms represent a new paradigm for cancer therapeutics as they improve the pharmacokinetic profile and distribution of chemotherapeutic agents over conventional formulations. Among nanoparticles, lipid-based nanoplatforms possessing a lipid core, that is, lipid-core nanoparticles (LCNPs), have gained increasing interest due to lipid properties such as high solubilizing potential, versatility, biocompatibility, and biodegradability. However, due to the wide spectrum of morphologies and types of LCNPs, there is a lack of consensus regarding their terminology and classification. According to the current state-of-the-art in this critical review, LCNPs are defined and classified based on the state of their lipidic components in liquid lipid nanoparticles (LLNs). These include lipid nanoemulsions (LNEs) and lipid nanocapsules (LNCs), solid lipid nanoparticles (SLNs) and nanostructured lipid nanocarriers (NLCs). In addition, we present a comprehensive and comparative description of the methods employed for their preparation, routes of administration and the fundamental role of physicochemical properties of LCNPs for efficient antitumoral drug-delivery application. Market available LCNPs, clinical trials and preclinical in vivo studies of promising LCNPs as potential treatments for different cancer pathologies are summarized., MCIN/AEI FPU18/05336, European Social Fund (ESF), Ph.D. program of Biomedicine of the University of Granada, MCIN/AEI/FEDER "Una manera de hacer Europa" RTI2018.101309B-C21 RTI2018.101309B-C22

Osteoarthritis is the most common degenerative and highly prevalent joint disease, characterized by progressive loss and destruction of articular cartilage. The damaged cartilage surface has an increased friction, which causes patients to suffer from serious pain. Restoring the lubrication ability of the joint is central to the treatment of osteoarthritis, a key topic in medical research. A variety of lubricants have been designed to reduce friction in joints and promote cartilage tissue repair to alleviate the symptoms of osteoarthritis. Herein, we review the recent progress of lubricants from the three perspectives of natural, bioinspired, and alternative strategies for osteoarthritis treatment, as well as the structural characterization and lubrication properties of such lubricants. Specifically, natural lubricants include glycosaminoglycans, lubricin and lipids in joints, bioinspired lubricants include scaffolds mimicking hyaluronic acid or lubricin, and alternative lubricants include modified lubricants based on hyaluronic acid, lipids, nanoparticles, and peptides. We also discuss the current challenges and long-term perspectives for further research in this area.

Light-driven photocatalytic (PC) and photoelectrocatalytic (PEC) systems are vital technologies being extensively explored for wastewater treatment and energy production. Although the photo(electro)catalytic applications in both the energy production and wastewater remediation function on the similar principle of photo-induced charge transfer, most preceding research has been focused on either the energy recovery or wastewater treatment as these two applications demand distinct reaction parameters and catalyst properties. The present review reveals the scientific progress in dual-functional PC and PEC processes that enable simultaneous energy recovery (e.g., H

Multiphase displacement in porous media can be adjusted by micro/nanoparticle suspensions, which is widespread in many scientific and industrial contexts. Direct visualization of suspension flow dynamics and corresponding multiphase patterns is crucial to understanding displacement mechanisms and eventually optimizing these processes in geological, biological, chemical, and other engineering systems. However, suspension flow inside the opaque realistic porous media makes direct observation challenging. The advances in microfluidic experiments have provided us with alternative methods to observe suspension influence on the interface and multiphase flow behaviors at high temporal and spatial resolutions. Macroscale processes are controlled by microscale interfacial behaviors, which are affected by multiple physical factors, such as particle adsorption, capillarity, and hydrodynamics. These properties exerted on the suspension flow in porous media may lead to interesting interfacial phenomena and new displacement consequences. As an underpinning science, understanding and controlling the suspension transport process from interface to flow patterns in porous media is critical for a lower operating cost to improve resource production while reducing harmful emissions and other environmental impacts. This review summarizes the basic properties of different micro/nanoparticle suspensions and the state-of-the-art microfluidic techniques for displacement research activities in porous media. Various suspension transport behaviors and displacement mechanisms explored by microfluidic experiments are comprehensively reviewed. This review is expected to boost both experimental and theoretical understanding of suspension transport and interfacial interaction processes in porous media. It also brings forward the challenges and opportunities for future research in controlling complex fluid flow in porous media for diverse applications.

Organic-inorganic hybrid nanoflowers (HNFs) are hierarchical flower-shaped microstructures that are assembled by nanoscale petal-like nanosheets composed of both organic and inorganic constituents. Generally, inorganic parts of HNFs are transition metal phosphates and organic components are mostly enzymes and proteins; however, non-protein molecules could be also used as organic phase in some types of newly described HNFs. Recent findings indicate that they are constructed through the coordination between organic and inorganic components. HNFs are mainly used for efficient biocatalysis and highly sensitive biosensing, while they have also some other noteworthy applications such as antimicrobial agents, antigen careers, and delivery platforms for anticancer drugs. It is believed that the high surface-to-volume ratio of HNFs could tackle mass transfer limitations leading to enhance the activity of their organic constituents. The environment-friendly route of synthesis and stabilization of biomolecules upon storage are the advantages of enzyme-based HNFs. In the present review, the focuses are on designs, preparations, formation mechanisms, and remarkable applications of the conventional forms and also magnetic, multi-component, and enzyme-free HNFs. Considering the fact that HNFs are in the early stages of development, the unknown aspects and future directions of research in this field are also discussed.

Liquid metal (LM)-based polymer composites are currently new breakthrough and emerging classes of soft multifunctional materials (SMMs) having immense transformative potential for soft technological applications. Currently, room-temperature LMs, mostly eutectic gallium‑indium and Galinstan alloys are used to integrate with soft polymer due to their outstanding properties such as high conductivity, fluidity, low adhesion, high surface tension, low cytotoxicity, etc. The microstructural alterations and interfacial interactions controlling the efficient integration of LMs with rubber are the most critical aspects for successful implementation of multifunctionality in the resulting material. In this review article, a fundamental understanding of microstructural alterations of LMs to the formation of well-defined percolating networks inside an insulating rubber matrix has been established by exploiting several existing theoretical and experimental studies. Furthermore, effects of the chemical modifications of an LM surface and its interfacial interactions on the compatibility between solid rubber and fluid filler phase have been discussed. The presence of thin oxide layer on the LM surface and the effects and challenges it poses to the adequate functionalization of these materials have been discussed. Plausible applications of SMMs in different soft matter technologies, like soft robotics, flexible electronics, soft actuators, sensors, etc. have been provided. Finally, the current technical challenges and further prospective to the development of SMMs using non‑silicone rubbers have been critically discussed. This review is anticipated to infuse a new impetus to the associated research communities for the development of next generation SMMs.