Search

Your search keyword '"Volochnyuk, Dmitriy M."' showing total 7 results
Start Over Author "Volochnyuk, Dmitriy M." Journal advanced synthesis & catalysis
7 results on '"Volochnyuk, Dmitriy M."'

1. Electrochemical Scaled‐up Synthesis of Cyclic Enecarbamates as Starting Materials for Medicinal Chemistry Relevant Building Bocks

Author

Tereshchenko, Oleksandr D., primary, Perebiynis, Maryana Y., additional, Knysh, Irina V., additional, Vasylets, Olesia V., additional, Sorochenko, Anna A., additional, Slobodyanyuk, Eugeniy Y., additional, Rusanov, Eduard B., additional, Borysov, Oleksandr V., additional, Kolotilov, Sergey V., additional, Ryabukhin, Sergey V., additional, and Volochnyuk, Dmitriy M., additional

Published
2020
Full Text
View/download PDF

6. Transition Metal‐free gem‐difluorocyclopropanation of Alkenes with CF3SiMe3−NaI System: a Recipe for Electron‐deficient Substrates.

Author

Nosik, Pavel S., Ryabukhin, Sergey V., Grygorenko, Oleksandr O., and Volochnyuk, Dmitriy M.

Subjects
ALKENES, STYRENE derivatives, CYCLOPROPANATION, CYCLOPROPANE, CARBOXYLIC acids
Abstract

Reaction of various electron‐deficient alkenes, as well as functionalized styrene derivatives with CF3SiMe3−NaI system is studied. Relative reactivity of the substrates is established. It is shown that many α,β‐unsaturated esters can be difluorocyclopropanated efficiently under "slow addition protocol" conditions, which provides access to mono‐ and spirocyclic gem‐difluorocyclopropyl‐substituted carboxylic acids with good yields (36–79% for two steps) on up to 100 g scale. [ABSTRACT FROM AUTHOR]

Published
2018
Full Text
View/download PDF

Catalog

Books, media, physical & digital resources
See catalog results