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Keywords: Allylboration; Boron; Silicon; Chemoselectivity; Enantioselectivity EN Allylboration Boron Silicon Chemoselectivity Enantioselectivity 2205 2205 1 04/29/21 20210427 NES 210427 The B front cover picture b , provided by Seung Hwan Cho and co-workers, illustrates ( I R i )-TRIP-catalyzed kinetic resolution of -silyl-substituted allylboronate esters through chemo-, diastereo-, and enantioselective allylation of aldehydes. The reaction is proposed to proceed via a chair-like transition state by the double coordination of ( I R i )-TRIP to the C-H bond of aldehydes and the oxygen atom of Bpin group, thus effectively resolving -silyl-substituted allylboronate esters with high enantiomeric ratios. Front Cover Picture: Kinetic Resolution of -Silyl-Substituted Allylboronate Esters via Chemo- and Stereoselective Allylboration of Aldehydes (9/2021). [Extracted from the article]