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Near‐infrared exciplex can weaken molecular design difficulties, and has the advantage of easy bathochromic‐shift spectra via selecting the suitable electron donors and acceptors. In this contribution, exciplex is applied to fabricate near‐infrared (NIR) organic light‐emitting diodes (OLEDs) incorporating a synthesized fluorescent material 3‐([1,1″:3′,1″‐terphenyl]‐5′‐yl)acenaphtho[1,2‐b]pyrazine‐8,9‐dicarbonitrile (APDC‐tPh) and a commercially available material 4,4′,4″‐tris(carbazol‐9‐yl)triphenylamine (TCTA). The device having a mixed TCTA:APDC‐tPh as an emitting layer shows a 730 nm NIR emission with a maximum external quantum efficiency (EQE) of about 0.1%, while the device having 2‐[4‐(diphenylamino)phenyl]‐10,10‐dioxide‐9H‐thioxanthen‐9‐one (TXO‐TPA):APDC‐tPh as the emitting layer exhibits an emission peak of 704 nm with a maximum EQE of 1.27%. These results prove the feasibility of fabricating the efficient exciplex‐based NIR OLEDs. [ABSTRACT FROM AUTHOR]