1. Research on the Simultaneous Desulfurization and Denitrification of Fumes by Combining Ozone Oxidation and the Double Alkali Method
- Author
-
Bang Fa Peng, Min Xu, Ming Li, Zhao Ji Hu, and Lin Sheng Wei
- Subjects
chemistry.chemical_compound ,Reaction mechanism ,Ozone ,Denitrification ,chemistry ,Inorganic chemistry ,General Engineering ,Partial pressure ,Absorption (electromagnetic radiation) ,Chemical reaction ,NOx ,Flue-gas desulfurization - Abstract
This paper introduced the fundamental principle of the simultaneous desulfurization and denitrification by combining ozone oxidation and the NaOH double alkali method. And the total chemical reaction equations were achieved by analyzing the process of the absorption of the productions of ozone oxidation by NaOH double alkali method. Then, based on thermodynamic principle, the partial pressure of SOx, NOx and CO2 when reactions reached equilibrium were calculated respectively. This paper also studied the reaction mechanism of the absorption of SOx and NOx and analyzed the absorption characteristic of SOx and NOx in absorption solution. The results showed that the simultaneous desulfurization and denitrification by combining ozone oxidation and NaOH double alkali method was feasible. Not only the elimination ratio of SOx and NOx were almost up to 100%, but also CO2 was removed on a considerable scale. The partial pressure of SOx and NOx was very important to the pH value of the absorption solution which affected the elimination ratio of SOx and NOx greatly.
- Published
- 2014