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The agriculture waste material can give benefit to many production industries. The studied crop is corn (Zea Mays)stalk. The objective of this work was to analysis the chemical composition; to study chemical pulping and papermaking properties of corn stalk and; to investigate the fiber morphology of properties of those crops. Firstly, the chemical composition of corn stalk were determined and compared with other non-woods. After that, chemical corn stalk was conducted in this analysis followed the physical and mechanical properties. The result showed that, corn stalk have cellulose (39.0%) and lignin content is the lowest (7.3%) content rather than other composition. In chemical pulping, reached high pulp yields had been produced and the strength properties: tear index, tensile index, burst and fold verified that they were of an acceptable quality for papermaking. This crop morphology was observed by Scanning Electron Microscopic (SEM), which showed a condensed composition of fiber structure. This study can developed a friendly product and promote the green technology, suitable to be used as an alternative pulp in paper making industry.Keywords:Fiber, Corn stalk, Composition, Green technology, Pulp and paper making.

The aim of this study was to study the morphology and structural characteristic of NCC hydrolyzed from filter paper. The NCCs were extracted by acid hydrolysis at 50°C for 1 hour, using 55% conc. H2SO4 under vigorous mechanical stirring, centrifugation at 12000 rpm in distillate water and followed by homogenizing at 7000 rpm. The morphology and surface profiles of the NCC suspension was characterized using field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and atomic force microscopy (AFM). The crystalline structure of the NCC was evaluated by using X-ray diffraction (XRD) technique. As a result, hydrolysed NCC was found to have a rod liked shape with diameter in the range of 100-300nm length and 10-50nm width, with the aspect ratio value of 10.3 nm. According to XRD investigations, the semi-crystalline cellulose was observed with the presence of an amorphous broad hump and crystalline peaks at 2θ of 15o and 22.7o, respectively. The crystalinity index of the raw filter paper was calculated as 86.7 % and increased to 94.4 % as it was extracted to NCC. Crystallite size of raw filter paper and NCC was calculated as 20.6 nm and 11.4 nm, respectively

This project investigated the use of facile pulping methods to produce pulp from mixed bio-plantation waste fibres using sodium hydroxide, ethanol and garbage enzyme. Papers were successfully made from mixture of corn husk fibres with other bio-based green fibres such as banana stems and pineapple leaves. Soda pulping was found to be efficient in converting the cellulosic bio-fibres to the pulps used for paper making. The papers produced have low tensile strength, high water absorption, high bio-decomposition and degradation rate, as compared to commercial papers. SEM observation revealed that paper made from mixed bio-fibres have lightly cross-linked structures compared to heavily cross-linked or compact network structures found in commercial papers. The paper can be used in applications that require high water absorbency. The paper making process is more environmental friendly as it reduces the usage of wood fibres and hence reduces the environmental problem caused by deforestation.

Homemade water in water cationic polyacrylamide (CPAM) emulsion was applied in cigarette paper pulp as dry strengthening agent with other strengthening agent. Good collaborative effect was achieved when CPAM was used in bleached wheat straw pulp with strengthening agent E and with cationic additives L as paper pulp strengthening agent. It was also showed that distinct strengthening effect was obtained when CPAM emulsion was applied in mixture of bleached needle kraft pulp (NBKP) and wheat straw pulp, breaking length and tearing index of cigarette handsheet made of mix pulp was respectively increased by 22.2% and17.0% when the dosage of CPAM was 0.8% of dry fiber. Through analysis of cigarette handsheet section scanning electron microscopy (SEM) photos, strengthening mechanism of CPAM emulsion to cigarette paper pulp was preliminary studied.

In this article, Fenton oxidation treatment technology was employed to the improving of quality of post treated wastewater from pulp & paper mills in order to increase the recycling ratio of final treated wastewater. The reaction conditions were optimized through single-factor experiments and the removal of color were tested for the optimizing. It was found in this study that the color of Fenton oxidation treated water was variegated with the extending of settling time. The optimized conditions were: Dosage of H2O2 was 682.1mg/L(30% m/m), 1.5 times theoretical consumption, 205mg/L FeSO47H2O (H2O2:FeSO4=15:1), the initial pH and the reaction time were 4.5 and 40min, respectively. The removal of the color and COD were 51.3% and 80% after Fenton treatment. GC-MS analysis shown that the contents of organic extracts and most of organic compounds reduced significantly after the oxidational treatment.

Both water repellency and water vapour barrier properties were endowed at paper surface by coating with beeswax-chitosan latex. It was found that the water vapour transmission rate of coated paper decreased as the drying temperature increased. However, water contact angle was not affected with it. Although the surface morphology deformed at high drying temperature, the roughness values maintained at micro-scale. Further analysis indicated that the water vapour barrier property of coated paper was influenced by the density of the coating layer.

Graphene paper (GP) with layered structure and highly conductive network is fabricated by a facile technique of vacuum filtration and studied as a single-component and binder-free anode of lithium ion batteries (LIBs). The process of fabrication of GP without any binder and high-temperature treatment, in the meantime, great improvement in both the capacity and cycling performance of the GP electrodes have compared with other kinds of traditional graphite electrode materials. Given the simplifying anode fabrication, low manufacturing costs and many electrochemical properties of the GP anode, it is regarded as an excellent anode material of LIB with great promise for its both excellent cycling performance and electrochemical properties. The specific capacity can reach to over 200 mAhg-1after 60 charge-discharge cycles under the current rate of 50 mAg-1.

The study aimed to describe the alkaline treatment advantage to remove ash component from natural rice straws. Most of the ash component in the rice straw is silica. High ash content is particularly harmful to cutting tools and to chemical to recovery systems in the pulp paper industry. In this study, the silica content has been removed simply through by immersion process in the 5% sodium hydroxide solution to obtain de-silicated rice straw. The study revealed the effectiveness of this alkaline process and the compatibility in commercial practice. The rice straw pulping is considered competitively to complement the global demand of raw material in paper production. Therefore, the treated rice straw plays an important role in providing raw material in the form of wood and rice straw blend feedstock for pulp and paper industry.

Pulp from the oil palm empty fruit bunches (EFB) was extracted via Alkaline Peroxide Pulping (APP). The pulping process was conducted through three main steps; dewaxing of EFB, impregnation of alkaline peroxide (AP) into EFB and refining of biomass to finally produce the pulp. The varying peroxide levels and number of impregnation stages were found to affect the refining energy consumption and the properties of the resultant pulp and paper. Diagnosis by electron microscopic imaging revealed a strong correlation between paper properties development and paper surface morphologies. By multiplying the stages of the low alkaline peroxide level (2:2.5% AP) impregnation, refining energy could be reduced by 30% while improving brightness and paper mechanical properties. Higher alkaline peroxide level (4:5% AP) could reduce the refining energy by 50% while still improving brightness. Beyond these AP levels (8:10% AP), refining energy could be reduced by 67% by increasing the number of impregnation stages, with positive effects on brightness and paper mechanical properties. The findings suggest that increasing the AP impregnation stages had exposed more active sites to react with AP. The enhanced AP accessibility to EFB structures facilitated mechanical fibrillation of EFB vascular bundles through the refining process. The proper synergy between AP and the adopted mechanical refining was the factor that triggered the liberation of nanocells from EFB biomass and this had ultimately improved paper properties.

The treatment on the secondary biochemical effluent of pulp and paper wastewater by Fenton oxidation was studied and the influence of H2O2dosage, Fe2+dosage, pH and reaction time on the treatment effect was investigated by the orthogonal test and single-factor test. The treatment effect was eminent when the H2O2dosage was 3.75mmol/L, Fe2+dosage was 3.20mmol/L, pH was 4.00 and the reaction time was 80.00min. The removal rate of UV254and chromaticity significantly increased as H2O2dosage was 1.88 ~ 3.75mmol /L, but the COD removal rate declined as H2O2dosage was more than 2.81mmol/L; each removal rate increased and then decreased slightly with the increase of Fe2+dosage, each removal rate dropped obviously as pH was more than 5.00; within 80.00min, the removal rate increased significantly, it changed little with the continuous increase of reaction time. Under the optimal conditions, the COD removal with Fenton oxidation was more effective and its removal rate could achieve 88.33%, it was advantageous compared with ozone oxidation; but the elimination effect of UV254and chromaticity to pulp and paper wastewater with ozone oxidation was better, the two removal rate achieved 83.70% and 92.00% in a short time, respectively. Although it could reach such a removal effect by Fenton oxidation, it did not have the superiority in reaction time.

Due to a shortage of wood source fibre in paper making industrys interest to agriculture residues fibre as a potential fibre sources in this industry. In this situation, importance has been developing in the paper industry from agriculture residue that will replace the wood fibre. Cocoa pod husk and Corn stalk are agriculture residues, which is good materials for paper production. The objectives of this study are to investigate the chemical characterization and surface morphology structure of these materials. The main components of materials which are cellulose, hemicellulose, lignin and ash content were parameters that involved in determination of chemical characterization in this study. The determination of chemical composition was accordance to Kurshner-Hoffner approach (cellulose), Chlorine Method (hemicellulose), T 222 om-06 (lignin) and T 211 om-07 (ash content). Scanning electron microscopy was used to observe the surface structure of materials. From results obtained, corn stalk shows the higher amount in cellulose (39%) and hemicellulose (42%) content compared to the cocoa pod husk. In addition, lower lignin content also obtained in Corn stalk (7.3%) rather than that Cocoa pod husk (14.7%). From Scanning electron microscopy images, Corn stalk and Cocoa pod husk contained abundance lignocellulosic and rough surface structure due to the untreated materials. The result either chemical characterization or surface morphology that obtained in Corn stalk and Cocoa pod husk fibre wastes can be used successfully as an alternative fibres sources in papermaking application.

The physical structure of coating layer have an important influence on transferring and setting of the printing ink. In this study, the effect of pigment on surface microstructure and surface free energy was investigated. The findings indicated that the pigment affected the pore size, depth and distribution of the coated paper surface. Kaolin pigment compared with calcium carbonate pigment was good to improve the paper surface smoothness. Surface free energy of kaolin pigment coating was higher than calcium carbonate pigment coating, which showed that surface wettability of coating with kaolin pigment was better than calcium carbonate pigment.

This research were examined the characteristics chemical and physicalof paper mulberry fiber and also developed the spinning processes of paper mulberry yarn to make the fabric by weaving and knitting. The chemical composition of paper mulberry fiber was approximately 72.5% cellulose, while hemi-cellulose, lignin, pectin, and water-soluble were 17, 2.6, 2.3, and 5.6%, respectively. The characteristics and physical properties of paper mulberry fabric were also investigated.

The application of hydrated calcium silicate as filler in paper from wheat straw pulp is studied in this paper. It shows that that with the increase of dosage of hydrated calcium silicate, the stiffness of paper improves, and the whiteness and the printing color density of paper improve, but the tightness and tensile strength of paper decrease. When the dosage of CPAM is 0.45 g/kg, the tightness, tensile strength, tearing index, whiteness and printing color density reach the large value. Paper ash content increased with the increase of amount of hydrated calcium silicate, but paper ash gains is not big after the dosage of hydrated calcium silicate reaches 20%.

The Paper studied the effects of pigments and base paper on binder migration and affected factors. The z-direction distribution of the coating binder which was tagged with Br in coating layer and its concentration in coating surface were examined quantitatively by using SEM-EDXA and ESCA analysis. The results showed that the increase of the ratio of calcium carbonate in the pigment content, coating surface binder concentration increased, and coating surface binder concentration increased with the increase of particle size of pigments. The result also indicated to small base paper absorbency, coating surface has high binder migration level, the coating layer bottom (base paper direction) has low binder concentration. To high absorbency base paper, the opposite is true.

A nano-material named opal blended with polymer, then were added into slurry, after a series of special paper-making process, the rice paper releasing anion was successfully prepared by us. By test of SEM, we observed nano-structure morphology in the image of opal particle and rice paper sample. A series of mechanical properties had been tested as GB18739 or QB/T3515 standard. After testing of anion concentration, maximum of rice paper reached -9510cm-3，meet the needs of human health. There is no doubt opal is a kind of environmental material for human health.

Two silane-based hybrid coatings were developed to modify the surface energy of phenolic resin impregnated paper. The coated paper samples were further pressed onto surfaces of plywood. The surface properties and water repellence of coated paper were investigated by AFM, XPS and water contact angle measurements. The water absorption of plywood with pressed paper was studied by water uptake tests. It was found that the sol-gel coatings had slightly improved the water repellence of the impregnated paper. The water absorption of plywood was also slightly decreased.

Application in paper pulp as dry strengthening agent of homemade water in water cationic polyacrylamide (CPAM) emulsion was studied. Good collaborative effect was achieved when Homemade CPAM was used in bleached wheat straw pulp with strengthening agent E and with cationic additives L as paper pulp strengthening agent. It was also showed that distinct strengthening effect was obtained when homemade CPAM emulsion was applied in mixture of wood pulp which was needle bleached kraft pulp (NBKP) and straw pulp, breaking length and tearing index of hand sheet made of mix pulp was respectively increased by 22.2% and17.0% when the dosage of CPAM was 0.8% of dry fiber. Through analysis of handsheet section scanning electron microscopy (SEM) photos, strengthening mechanism of CPAM emulsion to paper pulp was preliminary studied.

During the manufacture of recycled paper, paper sludge is discharged as an industrial waste. The amount of sludge discharged from manufacturing plants increases annually. In this study, the organic constituents, such as cellulose, in the sludge were converted into carbonaceous heavy metal absorbents using sulfur treatment. Paper sludge was washed with 5 M HCl solution to remove inorganic content, and then immersed in 1 M K2S solution for 24 h. After immersion, the sample was heated at 800 °C for 1 h under N2 atmosphere, and then cooled to room temperature to obtain the product. The sludge was mainly composed of inorganic content, such as calcite, kaolinite and talc, and organic content. Calcite was removed with acid washing and sulfur was impregnated into the sludge by immersing it into the K2S solution. The product with sulfur impregnation indicated higher removal abilities for lead and nickel than those without sulfur impregnation.

Due to the presence of recalcitrant organic compounds, the pulp and paper effluents after treatment by conventional biological processes still contain high concentration of chemical oxygen demand (COD) and colored substances and do not satisfy the national emission standard. The objectives of this work are to present the research process on environmental materials with application of ozone-based technologies in removal of characteristic pollutants in pulp and paper effluents and suggest the feasible development trend. In this work, basic mechanisms of degradation of organic pollutants by ozone-based technologies in the presence of environmental materials as catalyst are described. The removal efficiencies of characteristic pollutants commonly found in pulp and paper effluents, such as absorbable organic halogens (AOX), resin and fatty acids, phenolic compounds, lipophilic wood extractives and ethylenediaminetetraacetic acid (EDTA), are presented.

Tertiary treatment wascarried out to treat pulp and paper effluent from secondary treatment processby a three-dimensional electrode system equipped with modifiedbentonites as powdery electrode. The cetyl trimethylammonium bromide modified bentonite (CTAB-bent) and hydroxy-aluminum pillaredorganic bentonite (OH-Al-CTAB-bent) were synthesized and characterized by XRDand FTIR spectroscopy analysis.The impacts such as the dosage of particle electrode, electrolysis times,current density were on the COD removal efficiency and decolorization effect ofeffluent were also investigated. The results showed that the experimentscarried out by three-dimensional electrode system with OH-Al-CTAB-bent weresufficient for the COD and color removal efficiency. A current density of 30mA/cm2, electrolysis time of 40min, and the particle electrodedosage of 1.6g/L were selected as an optimum conditions that allows fast andlow cost treatment. The effluent can achieve the discharge standard of waterpollutants for pulp and paper industry (GB3544-2008) after electrolysis.

Waste paper sludge ash (WPSA) is a byproduct and problematic waste of paper industries. The investigation was driven by the increasing demand for reuse options in paper-recycling industry. This paper present on the morphology and physical analysis studies on polymerization of WPSA mortar. Two (2) types of polymeric mortar mixes containing WPSA with alkaline activators and without alkaline activators were prepared. The morphology of each mixes was determined using Spectra Electron Microscope (SEM) and the physical test is focus on compressive strength. However, the element diffraction of each mixes using Energy Dispersive X-Ray Spectroscopy (EDX) was also carried out as a method to identify the polymerization of polymeric mortar. From the result obtained it is found that the utilization of WPSA reduced the polymerization of polymeric mortar due to more pores. From the EDX analysis it is also revealed that the WPSA polymeric mortar also contained less synthetic aluminous silicate compound. However, the strength gain up to 6MPa and it is comparable with other high calcium material mortar.

Experimental studies on biogas yield of Ulva pertusa were carried out at different fermentation conditions. At 25°C, 35°C and 45°C, the biogas yield from fermentation of Ulva pertusa were 223.2mL/gVS, 256.2mL/gVS and 300.0mL/gVS,respectively, while the methane content in the biogas produced at 35°C was the highest. In addition, biogas yield reached to 482.5mL/gVS and 499.6mL/gVS by adding waste paper of 3.5g and 7.0g to the fermentation liquor, the corresponding methane content in the biogas were 56.0% and 51.2%, respectively. Comparatively, higher biogas yield, methane content and system stability could obtain from Ulva pertusa by adding 3.5g ~ 7.0g of waste paper and fermentation at 35°C.The fermentation process of Ulva pertusa for biogas production generally lasted for 19~25 days.

A novel hollow microsphere plastic pigment was prepared by the soap-free seeded emulsion polymerization. This pigment, with polyacrylate as core and with polystyrene as shell (PA/PSt) had hollow structure after dryness. The latex was characterized by transmission electron microscopy (TEM), Fourier transform infrared spectra (FTIR), and particle size analysis. The synthetic pigment was applied in the paper coating, and its influence on the printablility of the coated paper was investigated. The results show that the overall properties of the coated paper can be effectively improved when the clay in the base formulation is replaced by a small amount of hollow microsphere plastic pigment.

Fibers of dissolved air flotation rejects were been carboxymethylated to make dry strengthening agent. The effects of carboxymethylated time on carboxyl content, water retention value and physical properties of paper sheets were discussed. The effects of pH, dose of additive agent and additive aluminum sulfate on paper properties were discussed. The result show that carboxyl content and water retention values increased with the increasing of carboxymethylated time according to the research. IR analysis indicates that carboxymethyl has been connected to the surface of fibers. SEM micrographs shown that fibers were intergraded more closely benefit from the addition of dry strengthening agent. Tensile index, burst index and folding endurance respectively increased by 90.1% 101.8% and 833.3% on the condition: the additive agent amount 3%, pH 5, additive aluminum sulfate 0.5% of original pulp. Tensile index, burst index and folding endurance respectively increased by 74.0%, 87.8% and 877.8% when the carboxymethylated time was 110min for recycled pulp. This paper can be used as the theoretical basis for reusing of fiber of dissolved air flotation rejects.

In present time, recycled paper from xerographic and laser-printed wastepaper plays an important role as alternatives to paper from virgin pulp because of their good pulp quality and high amount of wastepaper each year. This type of paper is classified as Mixed Office Wastepaper (MOW). The xerographic and laser-printed inks are usually called “toner” which its formulation is different from conventional ink. This work aimed to investigate paper recycling by flotation deinking process. The flotation experiments were conducted using SDS (sodium dodecyl sulfate) and Triton X-100 (C14H22O(C2H4O)n). The experimental results demonstrated that ink removal was more efficient with the use of non-ionic surfactant (Triton X-100) than anionic surfactant (SDS). The efficiency of ink removal was determined by ERIC and the pulp’s brightness. In addition, the quality of de-inked pulps was evaluated by pulp physical properties such as burst strength, tear strength and tensile strength.

In this paper, a kind of sizing synergist,AKD,cationic rosin(CRS) and oil resistance agent were mixed in different proportions, we make it as a kind of new water repellent agent ,and for internal sizing. The best dosage and the composite ratio of the synergist, AKD, cationic rosin and oil resistance agent was discussed mainly in this experiment. And then the copy paper were tested of the substanceweight and contact angle, and compared with the water resistance when the domestic water repellent agent or AKD was added alone. Conclusions of this experiment are following: the optimal conditions were that the mass ratio of AKD and CRS is 6:4, the additive level of AKD and the cationic rosin is 6% (based on dry weight of pulp), the quantity of the sizing synergist is 0.5% , and no oil resistance agent was added, the effect of water resistance is best.

In this paper, the domestic old book paper(DOBP) was subjected to deinking process. Surface and colloid characterisitics of DOBP deinking pulp(DIP) system was investigated. The relation between surface and colloid characterisitic changes and efficiency of deinking (brightness and residual ink particles content) was studied. Technical conditions that affect the deinking pulp’s colloid chemical behavior were also analyzed here.The results showed that colloid-chemical behavior of DOBP deinking system could be changed during the deinking process. The colloid-chemical behavior, such as Zeta potential and surface tention, had a certain corresponding relation with deinking efficiency of DOBP deinking system. When Zeta potential of the deinking system was more great, and surface tension was more low in a certain range(Zeta potential was -17.0~ -16.0mV and surface tension was 59.0~61.0mN/m), brightness and ink removal efficiency of DOBP will be improved.

High consistency refining (HCR) and low consistency refining (LCR) of unbleached Masson’s pine kraft pulps for sack paper were studied in this article. The properties of their refined pulp and handsheet were analyzed comparatively. The results showed a high consistency refining was more suitable for sack paper with unbleached Masson’s pine kraft pulp than a low consistency refining. High consistency refining is of advantage to retain the fiber length. The tear index of the handsheet of high consistency refining were higher than that of low consistency refining. The TtensileT TenergyT Tabsorption (TEA)T index and air permeability of the handsheet of high consistency refining which were crucial properties of sack papers were better, though higher tensile index could be obtained with low consistency refining.

The intention of this paper is to review of some recent innovative novelties about paper and board pigment coating raw materials. First an overview is given of “traditional” coating raw materials and the coating process. Then new starch based pigments and binders as well as novel plastic pigments are reviewed regarding their effect on coated paper properties. Finally it is concluded that further innovations and research are needed.

To enhance printing qualities, this study used refluxed silica (SiO2) from rice husk by hydrochloric acid (HCl) at different molarities and reaction times as coating agent for printed paper. Characterization of the refluxed silica from 2M HCl 120 min elucidated the purity of 98.7% and amorphous structure. Particle size of the silica exhibited uniform size of 3 μm and the color measurement (CIE L*a*b*) indicated 94.79+0.48+1.24, whiteness and color difference (E) were 84.85, 3.28, respectively. The coating agent was prepared by water-based varnish of acrylic resin mixed with the synthesized silica at different proportions: 0.0, 0.5, 1.0, and 1.5 (%wt), and later was applied on 170 g/m2-white kraft papers. The results showed that the water-based coating varnish with silica exhibited an increase of viscosity as increasing the amount of the silica. Printing qualities indicated that the vanished printed paper with 1.0% silica elucidated the highest details in shadow tone and text (font) sharpness. The color gamut yielded a wider scope than the printed papers which were varnished with the silica at 0.0%, 0.5% and 1.5%. Nonetheless, the color density showed insignificant difference to 1.5% silica varnished paper.

This paper describes the precipitated calcium carbonate filler applied to paper industry, which was prepared by adding a specific crystal control agent. And a series of influencing factors in carbonation process was studied, such as carbonization temperature, concentration of milk of lime, carbon dioxide concentration and the crystal shape control dosage. Therefore the optimum conditions for preparation of chrysanthemum-shaped crystalline calcium carbonate were determined.

The physical structure and chemical properties of coating layer have an important influence on transferring and setting of the printing ink. In this study, the effect of pigment on coating layer structure and surface properties was investigated. The surface topography was explored using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The findings indicated that the pigment affected the pore size, depth and distribution of the coated paper surface. The conclusions were drawn that coating could improve coating surface topography and calcium carbonate pigment compared with kaolin pigment was not good to the paper surface properties, which resulted in high roughness, low paper gloss, high ink absorption and low paper surface efficiency.

In this paper, the effect of the charge of hydrophilic and lipophilic nanosized TiO2 on the optical properties and printability of coated paper was investigated. The parameters including brightness, opacity, surface strength and sizing degree were used to evaluate the optical properties and printability of coated paper. The effects of hydrophilic and lipophilic TiO2 on the properties of coated paper were discussed. It was shown that the optical properties and printability of coated paper increase persistently with the change of nanosized TiO2 charged from 5% to 15%. Once the charge of nanosized TiO2 was over 15%, the main properties of coated paper took on a downward tendency. The properties of coated paper were related to the surface properties of nanosized TiO2 samples. It was found that the lipophilicity of nanosized TiO2 sample played a more important role in the improvement of the coated paper properties, which was believed to be based on the fact that lipophilic nanosized TiO2 could be well compatible with the binders used in the paper coating.

In this work, acrylic acid and N-methylolacrylamide were used as functional monomers for preparation of styrene-acrylic emulsion, in combination with styrene and acrylic ester, as primary monomers. Also, 4 optimized emulsifier blends, including OP-10/FR-1, ER-30/FR-1, S-201/RE610, and CO-630/OF-40, were employed. A series of styrene-acrylic emulsion for automobile filter paper was successfully synthesized by preemulsification and semicontimuous copolymerization methods. The dilution stability, electrolyte stability, freeze-thaw stability, viscosity, pH and particle structure of emulsions after different storage time were monitored; the water resistance, bursting strength, stiffness of automobile filter paper after application were tested to study the effects of storage time. The results showed that the emulsions had good storage stability, while using all the 4 emulsifier blends. The pH value of emulsions decreased slowly, viscosity, dilution stability, particle size and distribution of emulsions were good; stabilities of freeze-thaw, storage and electrolyte changed slightly. Emulsions from emulsifier blends of OP-10/FR-1, ER-30/FR-1 and CO-630/OF-40 gave good water resistance property to filter paper. After 6 months, the paper bursting strength was almost unchanged, although the emulsion was stored for 6 months. The stiffness of papers reached the highest value, when the emulsion was stored for 2 weeks, and kept consistent until storage time of 6 months.

The culture of Chinese white spirit is time-honored, and it’s loved by all Chinese people, so it’s also important of white spirit packaging. The paper puts forward a new and green solution of white spirit packaging with paper bottle, it’s made with mulberry/rice paper and animal blood. The paper bottle is light and green, and increases the white spirit’s nutrition value. There are several physical and chemical tests in the paper just to justify the new bottle’s performance. Physical performance test includes appearance defect test, compression and stacking test, impact resistance test, water impact strength test, permeability test and so on. Chemical performance evaluation includes stability, compatibility and endurance.

AKD is an important internal size for paper pulp fiber. With recycled economy development, regenerated paper fiber becomes an important resource. In this paper, AKD is used as a modification aid by internal sizing method. It shows that the change of the dosage of AKD influences regenerated paper fiber Cobb value, but has no influence to paper surface strength. The proper pH value is from 7 to 9. The temperature has no influence to regenerated paper fiber Cobb value and paper surface strength. Appropriate modified starch is good for AKD modification fiber and increase of the surface strength of paper made from modified fiber by AKD. Amphoteric starch is better than cationic starch. Other added substances such as PEI, MPEI and PAE can improve the modification of paper fiber modified by AKD. So the adsorption of modified paper fiber decrease and the surface strength of paper modified fiber increase.

Different degrees of high degree of substitution cationic starch (HCS) were prepared and applied in paper coating. Effects of HCS on coating properties and coated paper properties were investigated, and the comparison of effects of HCS and PDMDAAC was made. The results show that the best amount of HCS in coating formula is between 2% and 4%. When the amount of HCS is 4%, whiteness of coated paper was the highest. The color density was the highest when the amount of HCS is about 4% and the degree of substitution is 0.64. HCS with degree of substitution 0.849 is better than PDMDAAC in some respects, and the print image density achieved satisfactorily.

First attempt to predicting physical properties of paper by Near Infrared Spectroscopy (abbreviated as NIRS) mathematical model, Acacia is a kind of fast-growing tree which is a potential resource in pulp and paper industry. The mathematical models of physical properties of Acacia unbleached kraft paper were established by software OPUS6.5 of Near Infrared Spectroscopy. Spectral data of Acacia unbleached kraft paper were acquired by Near-Infrared. Physical properties, which include quality, whiteness, tensile index, burst index and tear index, of the paper were measured by GB methods. NIRS mathematical models between the spectral data and the laboratory reference values were established and optimized by software OPUS6.5 partial least squares (abbreviated as PLS). The NIRS mathematical models were evaluated by its parameters, and used to predict the physical properties of unknown samples rapidly and accurately. Compared with NIRS mathematical model of physical properties of Acacia unbleached kraft pulp, the NIRS mathematical models of paper have a better prediction on unknown samples; Compared with traditional laboratory methods, predicting properties of paper by the NIRS mathematical models of paper is rapid, accurate and non-destructive.

The object of this work is to evaluate the optimal process of stickies removal on steam-explosion pulping from recovered paper. OCC (Old Corrugated Container), offset paper and coated art paper are presented for steam-explosion treatment. The parameters tested by single-factor tests are: liquor, explosion pressure, heat preservation time, and the charge of sodium hydrate and sodium silicate. The criterion used to characterize the stickies removal efficiency is the consistence of macrostickies and DCS in pulp after treatment. The compositional analysis are achieved the optimal explosion conditions. The use of steam explosion would be desirable in dealing with recovered paper.

In recent years, conductive paper produced by in-situ chemical polymerization of pyrrole and aniline in aqueous electrolytes has aroused a great interest. The in-situ chemical polymerization process is a process in which a monomer such as aniline or pyrrole is polymerized in the presence of pulp fibers. This approach can not only impart to paper specific functions, but also provide a new possibility for the processing and utilization of conductive polymers. In this paper, the research progress on inherently conducting polymer coated paper was overviewed.

The main objective of this study was to investigate the effect of drying condition on the binder distribution and characterize the binder migration in the method of numerical and visual analysis by Scanning Electrical Microscopy (SEM), Atomic Force Microscopy (AFM), and Laser Scanning Confocal Microscope (LSCM). In this study, Rhodamine B was used to stain the binder and as the probe to characterize z-directional distribution of the binder using LSCM. The results implied that it was reliable and effective method using LSCM to characterize the z- directional distribution of binder and analyze the influence of dry condition on binder migration. It could be concluded that the dry temperature played an important effect on binder distribution in coated paper and high dry temperature accelerated binder migration to the coating surface, however low drying temperature made binder migrate towards the interior of base paper. Moderate drying is good to binder distribution and coating layer forming.

In this paper, Water glass and sulfuric acid were used as raw materials to do the synthesis of hydrated silica by the method of precipitation, and then hydrated silica is applied in paper coating. By examining the changes of the coated paper’s various properties to study the effects of different reaction conditions to the final products. And then we obtained a optimal synthesis conditions: sulfuric acid concentration 25%, reaction time 50min, reaction temperature 80°C, sodium silicate modulus 2.8, stirring speed 150r/min, the relative amount of sodium sulfate content compared to SiO2 is 25% .And at last the outward appearance of the hydrated silica and the structural changes in paper coating were observed by scanning electron microscopy.

As one of the main emission sources of PCDD/Fs, the pulp and paper industry has always been public concerns. In China, the consumption of non-wood fiber as raw material of pulp accounts for a relatively larger proportion in the total productivity. Here, the unintentionally produced PCDD/Fs emissions of five Chinese non-wood pulp and paper mills were investigated. The results showed that the increment of PCDD/Fs after bleaching with chlorine was about 1.71-28.19 times in pulp and 3.96-28.82 times in wastewater based on the existing technologies. In order to reduce the unintentional production of PCDD/Fs, the BAT/BEP transformation program was proposed as cleaner production initiatives featured by less or free use of chlorine in bleaching process, and evaluated by reduction effects and costs. The study showed the application of Elemental Chlorine Free (ECF) sequences in bleaching process with improving technologies in other production stages would effectively decrease the generation of PCDD/Fs, other pollutant load as well as the water consumptions.

A proprietary in situ chemical vapor deposition (CVD) process was developed to grow a layer of pyrocarbon on carbon paper preform for proton exchange membrane fuel cells (PEMFC). The carbon paper preform is continuously manufactured by dry method. The characteristics of the carbon paper such as surface morphology, polarized light characteristics, and cross-section morphology were characterized using electron microscope, polarized light microscope, respectively. Fuel cell performance of the carbon paper was evaluated using single cell with hydrogen/air at various relative humidity (RH) conditions. The carbon paper with in situ growth of pyrocarbon showed significant improvement in lowering in-plane electrical resistance as well as fuel cell performance at dry condition. The carbon paper as seen under scanning electron microscope showed excellent surface morphology with pyrocarbon connecting carbon fibers tightly by CVD process.

Effect of wood pulp fiber and filler on the mechanical properties and harmful substance of reconstituted tobacco sheet were investigated. Experiments result showed that added lower lignin content pulp reduced phenols produced by reconstituted tobacco sheet combustion. As addition of bleached hardwood kraft pulp and precipitated calcium carbonate (PCC) increased, the amount of phenols release was dropped dramatically, but in order to ensure the normal operation of papermaking mechine, wood pulp and PCC addition should not be more than 20%. If wood pulp addition was above 20%, it had negative effect on the bulk, carbon monoxide and cigarette smoke flavor of reconstituted tobacco sheet; when PCC addition was more than 20%, it has negative effect on the normal operation of papermaking mechine.

The bio-drying characteristics and its influencing factors of paper mill sludge (PMS) were investigated detailedly, by means of the heat generated by aerobic degradation of the organic substances in the PMS. In the orthogonal experiments, the good results were achieved with the followed optimization technics: starch (25.0g/500.0g), sawdust (40.0g/500.0g), inoculation (15.0mL/500.0g) and KH2PO4(5.0g/500.0g). During bio-drying, the matrix temperature increased to 47.2°C within 12-24h rapidly under the given operation parameters, and the maximum was about 48.0°C. In the whole process the pH changed in the range of 6.11-7.87. The quantity of amylolytic bacteria reduced to the minimum in the first day, and the amylolytic bacteria grew well until the process of bio-drying finished. The ATP content was increased drastically in the first day and peaked in the fifth day, with the maximum ATP content was about 6.4×10-6μmol/g. When bio-drying of PMS was finished, the VS content and moisture content (MC) reduced from 58.4% to 49.5% and 62.2% to 50.3% respectively.

A test paper tape on the determination of nitrite in food was designed, which is based on the diazotization of nitrite with sulfanilic acid under weakly acidic conditions then coupled with N-(1-Naphthyl)-ethylenediamine dihydrochloride in forming the colour-producing response. Then the reaction membrane turned to purple-red. The deeper purple-red film was obtained in an increased nitrite concentration-dependent manner. Experimental results showed that nitrite concentrations were proportional to a values of the L a b color system. A favorable linearity was presented in the range of 25 to 5000 μg/mL. The correlation coefficient(r) was 0.984 and the whole testing time needed was about 1.5 min at room temperature.

The wettability of the carbon composite electrode on paper substrate was studied using contact angle measurement. Y-Shield HSF54 carbon composite material were coated on paper substrates with a mask using squeegee coating technique. Contact angles of the ten polar probe liquids with the HSF54 electrodes were measured using a customed-built image acquisition system. With the contact angles obtained for each probe liquid placed on the electrodes, the surface tension of the electrodes was determined using Fox-Zisman theory. The result showed that the critical surface tension of HSF54 carbon composite electrodes was 37.2 mN/m which is considered to be moderately hydrophobic.

There are high organic matter and cation exchange capacity (CEC) in paper mill sludge, which can be used efficiently to amend soil properties and promote the growth of crops. The batch method was used to investigate effects of paper sludge on adsorption and desorption of Cd (II) and Pb (II) in two types paddy soil (red soil, purple soil), through adding paper sludge to red soil and purple soil. The results showed that isothermal sorption process of Cd (II) and Pb (II) by soils and paper sludge could be well described by Langmuir equation and Freundlich equation, and all coefficients (r) were higher than 0.9. The purple soil had a higher sorption capacity of Cd (II) and Pb (II) than red soil. The sorption capacities of Cd (II) and Pb (II) in soils increased after added paper sludge, and they reached adsorption equilibrium as the percentages of paper sludge were 10%, 1% in red soil and purple soil, respectively. The desorption capacities of Cd (II) and Pb (II) in soils decreased after added paper sludge, and they reached minimum as the percentages of paper sludge were 5%, 2% in red soil and purple soil, respectively. It was better to immobilize Cd (II) and Pb (II) after added paper sludge, thus paper mill sludge can relieve the migration of heavy metals in soil-crop systems. It can provide a new way for safe using of heavy metal contaminated soil and resource utilization of paper sludge.