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Water wave energy is regarded to be a promising renewable energy source to relieve the pressure of fossil energy shortage and achieve a sustainable future. A cylindrical wave‐driven linkage mechanism triboelectric nanogenerator (WLM‐TENG) with unidirectional rotation is designed and fabricated to effectively harvest water wave energy. The enormous force generated by water waves, which is up to 424.3 N m−2, is used to drive the TENG through its simple and smart mechanical structure. This force allows the rotor to overcome the large resistance caused by the full contact between rabbit furs and electrodes. The output current can reach about 30 µA and the output power arrives at 50 mW. Moreover, self‐powered applications powered by the WLM‐TENG are successfully demonstrated, including indicating light‐emitting diodes (LEDs), multifunctional barometer, portable anemometer, and multifunctional water quality detection pen. This work renders an effective approach to harness the enormous force generated by the water waves, enhancing the water wave energy harvesting ability of the TENG, toward practical applications of marine environment monitoring. [ABSTRACT FROM AUTHOR]

Utilizing hydrogen energy produced by water electrolysis is conducive to carbon neutrality from a technological point of view. However, this perspective is restrained by the high electricity cost in commercial development. Powering electrochemical reactions by renewable electricity converted from distributed mechanical energy can lead to commercial electric energy saving and cost reduction. In this work, a self‐powered electrochemical system (SPECS) is proposed for the conversion from blue energy of ocean waves to green energy via hydrogen fuel. This system consists of triboelectric nanogenerator (TENG) devices and an electrolyzer, where the TENG devices serve as ocean wave energy harvesters for electricity generation, while the seawater‐containing electrolyzer is employed for hydrogen generation. After power management on the output of the TENGs and electrochemical reaction optimization, the system can generate hydrogen at a rate of 814.8 µL m‐2 d‐1 and a Faraday efficiency of 69.1% under ideal operation conditions, demonstrating the practical potential of the constructed system toward carbon neutralization. [ABSTRACT FROM AUTHOR]