1. Crystal structure of 1'-ethyl-spiro[chroman-4,4'-imidazolidine]-2',5'-dione: a hydantoine derivative
- Author
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M. Madaiah, M. M. M. Abdoh, Neratur Krishnappagowda Lokanath, S. Naveen, S. B. Benaka Prasad, and Ismail Warad
- Subjects
crystal structure ,chroman ,Stereochemistry ,Hydantoin ,Crystal structure ,Ring (chemistry) ,C—H⋯π interactions ,Crystal ,lcsh:Chemistry ,chemistry.chemical_compound ,C—H...π interactions ,Imidazolidine ,General Materials Science ,Physics::Chemical Physics ,Hydrogen bond ,General Chemistry ,Condensed Matter Physics ,hydrogen bonding ,Data Reports ,hydantoin derivatives ,Crystallography ,chemistry ,lcsh:QD1-999 ,Pyran ,imidazolidine ,spiro ,Derivative (chemistry) - Abstract
The title compound, C13H13N2O3, a hydantoin derivative, crystallized with two molecules (AandB) in an asymmetric unit. In moleculeA, the imidazolidine ring is twisted about the C—N bond involving the spiro C atom, while in moleculeBthis ring is flat (r.m.s. deviation = 0.010 Å). The pyran rings in both molecules have distorted half-chair conformations. The mean plane of the imidazolidine ring is inclined to the aromatic ring of the chroman unit by 79.71 (11)° in moleculeAand 82.83 (12)° in moleculeB. In the crystal, pairs of N—H...O hydrogen bonds link the individual molecules to formA–AandB–Binversion dimers. The dimers are linkedviaN—H...O and C—H...O hydrogen bonds, forming sheets lying parallel to thebcplane,viz.(011). Within the sheets, theAandBmolecules are linked by C—H...π interactions.
- Published
- 2015