1. Dimethyl N,N′-(1,2-phenylene)dicarbamate.
- Author
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García-Báez, Efrén V., López-Romero, Beatriz A., Martínez-Martínez, Francisco J., Höpfl, Herbert, and Padilla-Martínez, Itzia I.
- Subjects
- *
PHENYL compounds , *CARBAMATES , *CARBAMIC acid , *AROMATIC compounds , *ATOMS , *HYDROGEN bonding , *MOLECULAR association - Abstract
The title compound, C10H12N2O4, crystallizes in the monoclinic non-centrosymmetric space group Pn with Z = 2. The two methyl carbamate groups, —N(H)—C(=O)—OCH3, are twisted away from the aromatic ring mean plane, but form a semiflexible eight-membered cavity involving the atoms of the MeO—C(=O)—N(H)—CH2—CH2—N(H)—C(=O)—OMe group. The NH groups act as hydrogen-bond donors and the C=O groups as acceptors to form intermolecular N—H⋯O hydrogen bonding with an R21(7) motif, generating extended ribbons along the b direction. [ABSTRACT FROM AUTHOR]
- Published
- 2004
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