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The title compound, C14H12N2S2O, contains a dithio­carbazate group. The phenyl ring is disordered and perpendicular [dihedral angle of 48.0 (3)°] to the rest of the mol­ecule, which is planar. [ABSTRACT FROM AUTHOR]

A third modification of [RuCl2(PPh3)3] has been characterized, this time as the title compound, [RuCl2(C18H15P)3]·0.5CH2Cl2. As seen for the previous modifications, the complex has a distorted square-pyramidal geometry with an ortho-H atom `blocking' the site trans to the apical PPh3 ligand. There is no evidence for a strong C—H⋯Ru inter­action nor any specific directional force in the solid state. [ABSTRACT FROM AUTHOR]

The title tagatos­amine, C20H25NO5.CH4O, formed in the Amadori rearrangement of d-galactose with di­benzyl­amine, is shown to crystallize as the α-anomer, in contrast to the β-anomer formed in the Amadori reaction of d-glucose with di­benzyl­amine. [ABSTRACT FROM AUTHOR]

The title compound, [Pd(C2H3O2)(C18H15P)(C12H11N2O)]·CH2Cl2, crystallizes readily from a mixture of di­chloro­methane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakajima (1998). Polyhedron, 18, 533–543]. [ABSTRACT FROM AUTHOR]

The title compound, [Ti2(C4H9N)2Cl2(C5H5N)4]·2C6D6, posses­ses a dinuclear structure featuring two six-coordinate pseudo-octahedral titanium(IV) centres with bridging Cl atoms. The complex is located on a crystallographic inversion centre. [ABSTRACT FROM AUTHOR]

The title compound {systematic name: [(2-carboxyl­atophen­yl)­(phen­yl)meth­yl]- N,N-dimethyl­ammonium}, C16H17NO2, crystallizes as a hydrogen-bonded zwitterion. [ABSTRACT FROM AUTHOR]

The title compound, [Pd(C11H13N2)Cl(C18H15P)]·CH2Cl2, crystallizes readily from a mixture of di­chloro­methane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered ring heterocycles [Nonoyama & Nakajima (1998). Polyhedron 18, 533–543.]. [ABSTRACT FROM AUTHOR]

The title compound, C10H17NO6, was prepared by carrying out three SN2 displacements on a branched sugar derivative, one of which was not planned. Its crystal structure was determined to confirm the identity and stereochemistry of the product. [ABSTRACT FROM AUTHOR]

The title compound, C19H34O7Si, is derived from the minor component of a Kiliani reaction on d-fructose. Its crystal structure has been determined in order to confirm its structure and stereochemistry. [ABSTRACT FROM AUTHOR]

The title compound, SiF4(NH2Et)2 or C4H14F4N2Si, was isolated as an intermediate in the attempted solvothermal synthesis of a nitride-containing microporous material. Its structure at 150 K displays intermolecular hydrogen bonding leading to infinite sheets of molecules (each of point symmetry) running parallel to the bc plane. [ABSTRACT FROM AUTHOR]

The crystal structure of the title compound, C22H25F5N4O9, an important inter­mediate in the synthesis of novel biopolymers containing branched carbon chains, establishes the relative stereochemistry at all six chiral centres of the dipeptide. The structure may indicate a predisposition to the organization of secondary structure by novel dipeptide isosteres. An inter­molecular hydrogen bond between the NH group and one of the N atoms of the azide group contributes to the stabilization of the packing. [ABSTRACT FROM AUTHOR]

In the crystal structure of the title compound, C14H12N6S2, the mol­ecules are linked into centrosymmetric dimers through N—H⋯N hydrogen inter­actions, forming two-dimensional layers parallel to (010). [ABSTRACT FROM AUTHOR]

The title compound, C5H10O2, was prepared by a modified zone-refining technique, and has a layered structure with a high degree of disorder within the layers. [ABSTRACT FROM AUTHOR]

A second crystalline diacetonide, the title compound, C13H20O7, has been isolated from the sequential treatment of d-tagatose with aqueous sodium cyanide, followed by acetone in the presence of acid. Structural ambiguities with regard to the size of both the lactone and ketal rings are resolved by the X-ray crystallographic analysis. [ABSTRACT FROM AUTHOR]

The crystal structure of meth­yl acetoacetate, C5H8O3, at 150 K contains discrete mol­ecules. [ABSTRACT FROM AUTHOR]

The structure of cyclo­hexa­none, C6H10O, at 150 K is that of discrete mol­ecules, with no strong intermolecular interactions. [ABSTRACT FROM AUTHOR]

The title compound, C6H12O2, was prepared by a modified zone-refinement method at 150 K and consists of discrete molecules in van der Waals contact. [ABSTRACT FROM AUTHOR]

The structure of n-octanol, C8H17OH, at 150 K consists of infinite hydrogen-bonded chains forming a ribbon parallel to the b axis. [ABSTRACT FROM AUTHOR]

The title compound, trans-[PdBr(C7H2F5O3S)(C18H15P)2], was obtained in quantitative yield by oxidative addition of the electrophile 1-bromo-3,4-difluoro-2-(trifluoromethylsulfonyloxy)benzene to Pd(PPh3)4 in toluene, and was recrystallized from a mixture of tetrahydrofuran and pentane. The structure was resolved by single-crystal X-ray diffraction and turned out to be one of the few known examples among complexes of general formula trans-[(PAr3)2Pd( X)Ar′] that exhibit double π–π stacking intramolecular interactions (three aromatic rings are piled above each other). [ABSTRACT FROM AUTHOR]

The solid-state conformation of the title compound, C14H20N2O3·0.33H2O, a potent hexosaminidase inhibitor, prepared from d-lyxonolactone, has been established by X-ray crystallography. The asymmetric unit contains three mol­ecules, which have very similar conformations, together with a mol­ecule of water. [ABSTRACT FROM AUTHOR]