1. Dephasing and Quantum Beating of Excitons in Methylammonium Lead Iodide Perovskite Nanoplatelets
- Author
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Alexander F. Richter, Alexander S. Urban, Bernhard J. Bohn, Lakshminarayana Polavarapu, Thomas Simon, Moritz Gramlich, and Jochen Feldmann
- Subjects
Materials science ,Condensed Matter::Other ,Exciton ,Dephasing ,Physics::Optics ,02 engineering and technology ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,Atomic and Molecular Physics, and Optics ,0104 chemical sciences ,Electronic, Optical and Magnetic Materials ,Condensed Matter::Materials Science ,Quantization (physics) ,Four-wave mixing ,Nanocrystal ,Chemical physics ,Emission spectrum ,Electrical and Electronic Engineering ,0210 nano-technology ,Spectroscopy ,Biotechnology ,Perovskite (structure) - Abstract
Perovskite nanocrystals have emerged as an interesting material for light-emitting and other optoelectronic applications. Excitons are known to play an important role in determining the optical properties of these nanocrystals and their energetic levels as well as quantization properties have been extensively explored. Despite this, there are still many aspects of perovskites that are still not well-known, for example, the homogeneous and inhomogeneous line widths of the energetic transitions, quantities that cannot be directly extracted by linear absorption optical spectroscopy on nanocrystal ensembles. Here, we present temperature-dependent absorption and four-wave mixing (FWM) experiments on thick methylammonium lead iodide (MAPI) perovskite nanoplatelets exhibiting bulk-like absorption and emission spectra. Dephasing times T2 of excitons are determined to lie in the range of several hundreds of femtoseconds at low temperatures. This value enables us to distinguish between the homogeneous and inhomogen...
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