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The development of stretchable electronics requires the invention of compatible high-performance power sources, such as stretchable supercapacitors and batteries. In this work, two-dimensional (2D) titanium carbide (Ti3C2Tx) MXene is being explored for flexible and printed energy storage devices by fabrication of a robust, stretchable high-performance supercapacitor with reduced graphene oxide (RGO) to create a composite electrode. The Ti3C2Tx/RGO composite electrode combines the superior electrochemical and mechanical properties of Ti3C2Txand the mechanical robustness of RGO resulting from strong nanosheet interactions, larger nanoflake size, and mechanical flexibility. It is found that the Ti3C2Tx/RGO composite electrodes with 50 wt % RGO incorporated prove to mitigate cracks generated under large strains. The composite electrodes exhibit a large capacitance of 49 mF/cm2(∼490 F/cm3and ∼140 F/g) and good electrochemical and mechanical stability when subjected to cyclic uniaxial (300%) or biaxial (200% × 200%) strains. The as-assembled symmetric supercapacitor demonstrates a specific capacitance of 18.6 mF/cm2(∼90 F/cm3and ∼29 F/g) and a stretchability of up to 300%. The developed approach offers an alternative strategy to fabricate stretchable MXene-based energy storage devices and can be extended to other members of the large MXene family.

Piezoelectric organic–inorganic lead halide perovskites have recently attracted much attention in the field of optoelectronic devices. However, their piezoelectric properties as a possible way to modulate device performances have rarely been reported. Here, we study experimentally a photodetector based on CH3NH3PbI3(MAPbI3) single crystals, whose performance is effectively modulated viaan emerging effect—the piezo-phototronic effect, which is to use the piezoelectric polarization charges to tune the optoelectronic processes at the interface. A piezoelectric coefficient of 10.81 pm/V of the CH3NH3PbI3single crystal is obtained. Under 680 nm laser illumination with a power density of 3.641 mW/cm2and at an external bias of 2 V, compared to the case without straining, the light current of the photodetector is enhanced by ∼120% when a 43.48 kPa compressive pressure is applied. The response speed of the photocurrent is 3 and 2 times faster than the cases without applying pressure for the light-on and light-off states, respectively. This work proves that the performance of the photodetector based on MAPbI3single crystals can be effectively enhanced by the piezo-phototronic effect, providing a good method for optimizing the performance of future perovskite-based optoelectronic devices.

Realizing active interaction with external environment/stimuli is a great challenge for current electronics. In this paper, a tribotronic tuning diode (TTD) is proposed by coupling a variable capacitance diode and a triboelectric nanogenerator in free-standing sliding mode. When the friction layer is sliding on the device surface for electrification, a reverse bias voltage is created and applied to the diode for tuning the junction capacitance. When the sliding distance increases from 0 to 25 mm, the capacitance of the TTD decreases from about 39 to 8 pF. The proposed TTD has been integrated into analog circuits and exhibited excellent performances in frequency modulation, phase shift, and filtering by sliding a finger. This work has demonstrated tunable diode and active analog signal modulation by tribotronics, which has great potential to replace ordinary variable capacitance diodes in various practical applications such as signal processing, electronic tuning circuits, precise tuning circuits, active sensor networks, electronic communications, remote controls, flexible electronics, etc.