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Mechanochromic mechanophores have promising applications in stress sensing and damage detection. Here we report a simple mechanofluorochromic mechanophore based on aminothiomaleimide (ATM). Poly(methyl acrylate) containing this mechanophore (ATM-PMA) was synthesized by atom transfer radical polymerization (ATRP) using an ATM-derived difunctional initiator. To investigate its mechanofluorochromism, the solution of ATM-PMA was subjected to ultrasonication, and size exclusion chromatography (SEC) and fluorescence spectroscopy were employed to monitor the changes in molecular weight and fluorescence emission. The results showed that the molecular weight of ATM-PMA decreased upon ultrasonication, accompanied by a shift of fluorescence emission from bright yellow to light blue. This mechanophore of a simple functional group of ATM has great potential to be used in mechanochromic polymer materials.

Molecular bottlebrushes featuring brush-on-brush (BoB) architecture were prepared by combining azide-alkyne click chemistry, ring-opening polymerization (ROP), and atom transfer radical polymerization (ATRP). Primary side chains of diblock copolymers with a poly(ε-caprolactone) (PCL) block and a poly(α-bromo-ε-caprolactone) (P(CL-Br)) block were synthesized by ROP and then grafted onto PCL backbone by the click reaction. Then the secondary side chains of poly(oligo(ethylene glycol) acrylate) (POEGA) were grafted from the P(CL-Br) block by ATRP, yielding an amphiphilic core/shell structure. Imaging of individual macromolecules by atomic force microscopy (AFM) demonstrated dramatically thickened wormlike formation with distinct hairy side chains. Interestingly, for the BoB molecular bottlebrushes with enough long primary and secondary side chains, sufficient tension can be generated along the backbone and thus lead to its cleavage.