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Start Over Author "Liangliang Luo" Journal acs catalysis
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1. C–H Activation Relay (CHAR): An Efficient Construction of Isatin Skeleton by Aerobic Oxidation of Glycine Esters

Author

Liang Zhang, Xuewen Zhang, Xiaodong Jia, Shiwei Lü, Liangliang Luo, Yu Yuan, and Yingzu Zhu

Subjects
010405 organic chemistry, Isatin, General Chemistry, 010402 general chemistry, 01 natural sciences, Medicinal chemistry, Catalysis, 0104 chemical sciences, chemistry.chemical_compound, Catalytic oxidation, chemistry, Intramolecular force, Glycine, Organic chemistry, Char
Abstract

Directed by the strategy of C–H activation relay (CHAR), an efficient construction of isatin skeleton was developed through catalytic oxidation of glycine esters. The mechanistic study reveals that the oxidation of the relatively active C–H bonds initiated the followed activation of remote and inert C–H bonds, and an intramolecular 1,6-hydrogen shift was involved as a key step.

Published
2016
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