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Encrypted storage of optical information has attracted increasing interest for anticounterfeiting, information transmission, and military applications. In this study, an inverse opal-structured titanium dioxide/heptadecafluorodecyltrimethoxysilane (IOS-T/F) panel is developed. Based on a unique wetting-enhanced mechanism of structural color vision derived from a reduced light scattering and strengthened effective refractive index, this panel is capable of reversible writing/erasing and encryption/decryption of optical information. Multiple levels of information can be compiled, concealed, and erased simply using controlled ultraviolet irradiation to form patterned hydrophilic/hydrophobic differences, and the process of revealing or concealing the information only requires a few drops of water or evaporation, respectively. Importantly, the functions of the IOS-T/F panel can be well maintained under harsh conditions, including strongly acidic/alkaline environments or extreme temperatures (from -40 to 80 °C), as well as can be recovered after staining by various pollutants. This system provides simple encryption, rapid decryption, and the ability to store multiple sets of information under diverse application scenarios, which represents a novel material design strategy for security-related applications and smart optical systems.

Coating of metal-organic frameworks (MOFs) on flexible substrates is a crucial technology for applications such as purification/separation, sensing, and catalysis. In this work, a facile coordination replication strategy was developed to coat various MOFs onto flexible fibrous materials where a dense layer of an insoluble precursor template, such as a layered hydroxide salt, was first deposited onto a fiber substrate via a mild interfacial reaction and then rapidly transformed into a MOF coating in a ligand solution at room temperature. Spatiotemporal harmonization of solid precursor dissolution and MOF crystallization enabled precise replication of the precursor layer morphology to form a continuous MOF coating composed of intergrown crystals. The resulting flexible, highly robust, and processable fibrous MOF/textile composites demonstrated tremendous potential for industrially relevant applications such as continuous removal of the organosulfur compound dibenzothiophene from simulated gasoline and ammonia capture. This rapid, versatile, eco-friendly, and scalable MOF coating process at room temperature gives rise to new possibilities for preparing MOF-coated functional materials.

It is challenging to explore a unified solution for the treatment of oily wastewater from complex sources. Thus, membrane materials with flexible separation schemes are highly desired. Herein, we fabricated a smart membrane by electrospinning TiO2 doped polyvinylidene fluoride (PVDF) nanofibers. The as-formed beads-on-string structure and hierarchical roughness of the nanofibers contribute to its superwetting/resisting property to liquids, which is desirable in oil/water separation. Switched simply by UV (or sunlight) irradiation and heating treatment, the smart membrane can realize reversible separation of oil/water mixtures by selectively allowing water or oil to pass through alone. Most importantly, the as-prepared nanofiber membrane possesses outstanding antifouling and self-cleaning performance resulting from the photocatalytic property of TiO2, which has practical significance in saving solvents and recycling materials. This work provides a route for fabricating cost-effective, easily scaled up, and recyclable membranes for on-demand oil/water separation in versatile situations, which can be of great usage in the new green separation technology.

To develop an efficient water-collecting surface that integrates both fast water-capturing and easy drainage properties is of high current interest for addressing global water issues. In this work, a superhydrophobic surface was fabricated on cotton fabric via manipulation of both the surface roughness and surface energy. This was followed by a subsequent spray coating of TiO2 nanosol that created light-induced superhydrophilic bumps with a unique raised structure as a result of the interfacial tension of the TiO2 nanosol sprayed on the superhydrophobic fiber surface. These raised TiO2 bumps induce both a wettability gradient and a shape gradient, synergistically accelerating water coalescence and water collection. The in-depth study revealed that the quantity and the distribution of the TiO2 had a significant impact on the final water collection efficiency. This inexpensive and facilely fabricated fabric biomimicks the desert beetle's back and spider silk, which are capable of fog harvesting without additional energy consumption.