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Practical aqueous Zn-ion batteries are appealing for grid-scale energy storage with intrinsic safety and cost-effectiveness, yet their cycling stability and reversibility are limited by unwanted dendrite growth and water-induced erosions on Zn. Herein, a hydrophilic and Zn2+-conductive Ni–Al layered double hydroxide (NiAl–LDH) interphase layer is constructed on the surface of Zn, in which NiAl–LDH enables a more uniformly distributed Zn2+concentration and interfacial electric field owing to its large internal Zn2+channels and favorable charge redistribution effect. Consequently, the NiAl–LDH-integrated Zn anode achieves low voltage hysteresis and high reversibility of Zn plating/stripping with uniform underneath deposition behaviors. Remarkably, the resultant NiAl-2 LDH@Zn delivers superior cycling durability over 2800 h (∼4 months, 0.5 mA cm–2), realizes high reversibility with 99.4% average Coulombic efficiency over 1400 cycles, and confers stable operation of full Zn cells with high V2O5mass loadings. This work offers a facile and instructive interface design approach for achieving highly stable Zn metal anodes.