1. Time-Dependent Field Effect in Three-Dimensional Lead-Halide Perovskite Semiconductor Thin Films
- Author
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Annamaria Petrozza, James M. Ball, Munirah D. Albaqami, Mario Caironi, and Anil Reddy Pininti
- Subjects
Electron mobility ,Materials science ,Energy Engineering and Power Technology ,Field effect ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Article ,metal-halide perovskites ,Materials Chemistry ,Electrochemistry ,Chemical Engineering (miscellaneous) ,Microelectronics ,Electrical and Electronic Engineering ,Thin film ,carrier mobility ,Perovskite (structure) ,business.industry ,field-effect transistors ,021001 nanoscience & nanotechnology ,charge transport ,0104 chemical sciences ,Semiconductor ,Optoelectronics ,Field-effect transistor ,Charge carrier ,solution-processed semiconductors ,0210 nano-technology ,business - Abstract
Charge transport in three-dimensional metal-halide perovskite semiconductors is due to a complex combination of ionic and electronic contributions, and its study is particularly relevant in light of their successful applications in photovoltaics as well as other opto- and microelectronic applications. Interestingly, the observation of field effect at room temperature in transistors based on solution-processed, polycrystalline, three-dimensional perovskite thin films has been elusive. In this work, we study the time-dependent electrical characteristics of field-effect transistors based on the model methylammonium lead iodide semiconductor and observe the drastic variations in output current, and therefore of apparent charge carrier mobility, as a function of the applied gate pulse duration. We infer this behavior to the accumulation of ions at the grain boundaries, which hamper the transport of carriers across the FET channel. This study reveals the dynamic nature of the field effect in solution-processed metal-halide perovskites and offers an investigation methodology useful to characterize charge carrier transport in such emerging semiconductors.
- Published
- 2021