Search

Trifluoroiodomethane CF 3 I has been recently considered as a potential alternative to SF 6 , thanks to its high electronegativity and extremely low environmental effect. However, due to its high boiling point, CF 3 I should be mixed with other gases such as N 2 or CO 2 in order to avoid the liquefaction at low temperature. In this paper, we present breakdown measurements carried out in CF3I and CF 3 I-N 2 gas mixtures, under dc voltage, and with a pressure-distance product (p.d) up to 5 mmbar. Pure CF3I has a higher breakdown voltage (V b ) than SF 6 . However, the favourable synergistic effect observed in SF 6 gas mixtures with N 2 , at low SF 6 content, is not observed in CF 3 I gas mixtures. In CF 3 I-N 2 mixtures, the dc breakdown voltage increases proportionally to the CF 3 I content. As a consequence, breakdown voltages for mixtures containing up to 50% CF 3 I are lower than with SF 6 at the same ratio. These results are in good agreement with calculated values using breakdown model and reduced critical field strength (E/N) crit reported by others authors. In CF3I, the appearance of solid by-products (particles) generated by breakdown is also observed. The nature of these particles is tentatively attributed to the formation of iodine. In our sphere-sphere geometry, the accumulation of such solid particles leads to a measurable conductivity.

In gas insulated switchgears (GIS), high voltage electrodes are supported by solid insulators. A "triple junction" (TJ) exists at the interface between metal, insulating solid, and gas. This area constitutes a preferential zone were partial discharges (PDs) can appear. A further degradation of insulation performance can occur if solid particles accumulate at that place. This paper presents experiments carried out to obtain a quantitative account of the influence of a metallic particle located close to a triple junction area, both in dry air and SF6. PDs are detected and measured by conventional electrical measurements, and observed optically with a high-sensitivity intensified camera. Measurements under AC voltage show the influence of the particle on PD inception and flash-over voltage, in comparison with the same geometry without particle. In SF6, the particle induces a large decrease of PD inception and breakdown voltages, which become nearly independent of the gas pressure.