1. Improving long-term thermal stability in twin-roll cast Al-Mg-Si-Cu alloys by optimizing Mg/Si ratios.
- Author
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Zhang, Shao-You, Mo, Yuan-Ting, Hua, Zhen-Ming, Liu, Xu, Liu, Ze-Tian, and Wang, Hui-Yuan
- Subjects
ALUMINUM alloys ,THERMAL stability ,MECHANICAL alloying ,THERMAL resistance ,ALLOYS - Abstract
• The Fe-containing phase selection can be controlled by optimizing the Mg/Si ratio. • The good ductility of Mg-riched alloys correlates with the fine α-AlFeSi phase. • Mg-riched alloys exhibit a stable high yield strength during thermal exposure. • The superior thermal stability of Mg-riched alloys is related to the L phase. • The reason for the high thermal resistance of the L phase is discussed. Achieving high thermal stability in the 6xxx series alloys remains a challenging task, which limits their engineering application. Herein, Al-Mg-Si-Cu alloys with various Mg/Si ratios (0.5, 1, 2, and 4) were fabricated by twin-roll casting (TRC), and the microstructure evolution and mechanical properties during long-term thermal exposure of 150 °C/1000 h were studied. The results disclosed that alloys with a high Mg/Si ratio exhibited better thermal stability. The alloys with the Mg/Si ratio of 2 (Mg/Si∼2) achieved a stable high yield strength of ∼330 MPa and meanwhile maintained a satisfactory fracture elongation (> 10 %) throughout the thermal exposure process. This excellent thermal stability can be attributed to the microstructure consisting of high-density L phases and fine α-AlFeSi phases, which was related to the optimized Mg/Si ratio. Specifically, L phases were dominated in peak-aged Mg/Si∼2 alloys, while the counterparts in alloys with the Mg/Si ratio of 1 (Mg/Si∼1) were β'' and Q' phases. During the thermal exposure process, the L phases remained stable without coarsening, which was mainly due to the high coherence and low interfacial energy of the L -matrix interface. Meanwhile, the main Fe-containing phases in Mg/Si∼2 and Mg/Si∼1 alloys were fine near-spheroidal α-AlFeSi and large-size needle-like β-AlFeSi, respectively, which lead to a better ductility of Mg/Si∼2 alloys. This work may provide a strategy for the preparation of 6xxx series alloys with high thermal stability. [ABSTRACT FROM AUTHOR]
- Published
- 2025
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