9 results on '"Yun, Tae Gwang"'
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2. Transpiration Driven Electrokinetic Power Generator
- Author
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Yun, Tae Gwang, Bae, Jaehyeong, Rothschild, Avner, and Kim, Il-Doo
- Abstract
Transpiration is the process by which water is carried in plants from the roots to the leaves where evaporation takes place. Here, we report a transpiration driven electrokinetic power generator (TEPG) that exploits capillary flow of water in an asymmetrically wetted cotton fabric coated with carbon black. Accumulation of protons induced by the electrical double layer formed at the solid (carbon black)/liquid (water) interface gives rise to potential difference between the wet and dry sides. The conductive carbon black coating channels electrical current driven by the pseudostreaming mechanism. A TEPG of 90 mm × 30 mm × 0.12 mm yields a maximum voltage of 0.53 V, maximum current of 3.91 μA, and maximum energy density of 1.14 mWh cm–3, depending on the loading of the carbon black. Multiple TEPGs generate enough power to light up a light-emitting diode (20 mA × 2.2 V) or charge a 1 F supercapacitor.
- Published
- 2019
- Full Text
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3. All-Transparent Stretchable Electrochromic Supercapacitor Wearable Patch Device
- Author
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Yun, Tae Gwang, Park, Minkyu, Kim, Dong-Ha, Kim, Donghyuk, Cheong, Jun Young, Bae, Jin Gook, Han, Seung Min, and Kim, Il-Doo
- Abstract
Flexible and stretchable electrochromic supercapacitor systems are widely considered as promising multifunctional energy storage devices that eliminate the need for an external power source. Nevertheless, the performance of conventional designs deteriorates significantly as a result of electrode/electrolyte exposure to atmosphere as well as mechanical deformations for the case of flexible systems. In this study, we suggest an all-transparent stretchable electrochromic supercapacitor device with ultrastable performance, which consists of Au/Ag core–shell nanowire-embedded polydimethylsiloxane (PDMS), bistacked WO3nanotube/PEDOT:PSS, and polyacrylamide (PAAm)-based hydrogel electrolyte. Au/Ag core–shell nanowire-embedded PDMS integrated with PAAm-based hydrogel electrolyte prevents Ag oxidation and dehydration while maintaining ionic and electrical conductivity at high voltage even after 16 days of exposure to ambient conditions and under application of mechanical strains in both tensile and bending conditions. WO3nanotube/PEDOT:PSS bistacked active materials maintain high electrochemical–electrochromic performance even under mechanical deformations. Maximum specific capacitance of 471.0 F g–1was obtained with a 92.9% capacity retention even after 50 000 charge–discharge cycles. In addition, high coloration efficiency of 83.9 cm2C–1was shown to be due to the dual coloration and pseudocapacitor characteristics of the WO3nanotube and PEDOT:PSS thin layer.
- Published
- 2019
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4. High throughput combinatorial analysis of mechanical and electrochemical properties of Li[NixCoyMnz]O2cathode
- Author
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Kim, Donghyuk, Shim, Hyung Cheoul, Yun, Tae Gwang, Hyun, Seungmin, and Han, Seung Min
- Abstract
In this study, Li[NixCoyMnz]O2cathode composition library was fabricated using combinatorial methodology and characterized using nanoindentation to create a mechanical properties database as a function of Li[NixCoyMnz]O2composition. A single sputter deposition from LiCoO2, LiNiO2, and LiMn2O4compound targets resulted in a composition range of 3–44 at.% Co, 20–80 at.% Ni, and 5–50 at.% Mn. Young’s modulus and hardness values were evaluated before and after charge–discharge cycles, and a strong dependency of the mechanical properties on composition was found; Mn-rich composition showed highest retention of its mechanical properties whereas the properties degraded more significantly for the Ni-rich composition. Electrochemical performance was analyzed and compared to mechanical properties at various Li[NixCoyMnz]O2compositions and a strong correlation between enhanced mechanical properties retention leading to superior discharge capacity retention was found for the Mn-rich compositions. Li[Ni0.33Co0.30Mn0.34]O2composition showed optimized electrochemical and mechanical properties, where it retained 38% and 50% of its Young’s modulus and hardness after cycling while demonstrating 91% discharge capacity retention after 20 cycles at 1 C-rate.
- Published
- 2016
- Full Text
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5. Ion-permselective conducting polymer-based electrokinetic generators with maximized utility of green water.
- Author
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Yun, Tae Gwang, Bae, Jaehyeong, Nam, Hyeon Gyun, Kim, Dongyeon, Yoon, Ki Ro, Han, Seung Min, and Kim, Il-Doo
- Abstract
Hydro-electric technology has gathered much attention by the virtue of water as the energy source. However, the low energy density of this technology severely limits its practical use. Here, we demonstrate a PEDOT:PSS-based transpiration-driven electrokinetic power generator (p-TEPG) that enables the utilization of a wider variety of real-world water resources for maximizing energy generation efficiencies. In addition to the conventional electrical double layer on the material surface, the p-TEPG builds an additional potential difference in the polymer matrix by the selective penetration of cations into the matrix that contains sulfonate functional groups. p-TEPG exhibits 80–250% higher energy density than carbon-based TEPG at the same resistance. Moreover, seawater produced enhanced volumetric energy/power densities (34.36 mJ cm
−3 and 44.70 μW cm−3 ) and areal energy/power densities (410 μJ cm−2 and 0.45 μW cm−2 ), respectively, compared to DI water on a single p-TEPG device, which is sufficient to charge electrical energy storage systems and directly operate low-powered electronic. • p-TEPG maximizes energy harvesting efficiency by ion-permselective PEDOT:PSS. • Green water resources improve performance of p-TEPG. • p-TEPG adsorbs more cations into its polymer matrix by sulfonate groups. • p-TEPG can increases energy harvesting efficiency by using anions and cations with smaller radii. • p-TEPG can be fueled with seawater, demonstrating its potential for blue energy generating system. [ABSTRACT FROM AUTHOR]- Published
- 2022
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6. Polypyrrole–MnO2-Coated Textile-Based Flexible-Stretchable Supercapacitor with High Electrochemical and Mechanical Reliability
- Author
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Yun, Tae Gwang, Hwang, Byung il, Kim, Donghyuk, Hyun, Seungmin, and Han, Seung Min
- Abstract
Carbon-nanotube (CNT)-based textile supercapacitors with MnO2nanoparticles have excellent power and energy densities, but MnO2nanoparticles can be delaminated during charge–discharge cycles, which results in significant degradation in capacitance. In this study, polypyrrole conductive polymer was coated on top of MnO2nanoparticles that are deposited on CNT textile supercapacitor to prevent delamination of MnO2nanoparticles. An increase of 38% in electrochemical energy capacity to 461 F/g was observed, while cyclic reliability also improved, as 93.8% of energy capacity was retained over 10 000 cycles. Energy density and power density were measured to be 31.1 Wh/kg and 22.1 kW/kg, respectively. An in situ electrochemical–mechanical study revealed that polypyrrole–MnO2-coated CNT textile supercapacitor can retain 98.5% of its initial energy capacity upon application of 21% tensile strain and showed no observable energy storage capacity change upon application of 13% bending strain. After imposing cyclic bending of 750 000 cycles, the capacitance was retained to 96.3%. Therefore, the results from this study confirmed for the first time that the polypyrrole–MnO2-coated CNT textile can reliably operate with high energy and power densities with in situ application of both tensile and bending strains.
- Published
- 2015
- Full Text
- View/download PDF
7. Ion-permselective conducting polymer-based electrokinetic generators with maximized utility of green water
- Author
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Yun, Tae Gwang, Bae, Jaehyeong, Nam, Hyeon Gyun, Kim, Dongyeon, Yoon, Ki Ro, Han, Seung Min, and Kim, Il-Doo
- Abstract
Hydro-electric technology has gathered much attention by the virtue of water as the energy source. However, the low energy density of this technology severely limits its practical use. Here, we demonstrate a PEDOT:PSS-based transpiration-driven electrokinetic power generator (p-TEPG) that enables the utilization of a wider variety of real-world water resources for maximizing energy generation efficiencies. In addition to the conventional electrical double layer on the material surface, the p-TEPG builds an additional potential difference in the polymer matrix by the selective penetration of cations into the matrix that contains sulfonate functional groups. p-TEPG exhibits 80–250% higher energy density than carbon-based TEPG at the same resistance. Moreover, seawater produced enhanced volumetric energy/power densities (34.36 mJ cm−3and 44.70 μW cm−3) and areal energy/power densities (410 μJ cm−2and 0.45 μW cm−2), respectively, compared to DI water on a single p-TEPG device, which is sufficient to charge electrical energy storage systems and directly operate low-powered electronic.
- Published
- 2022
- Full Text
- View/download PDF
8. Organism epidermis/plant-root inspired ultra-stable supercapacitor for large-scale wearable energy storage applications.
- Author
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Yun, Tae Gwang, Jang, Ji-Soo, Cheong, Jun Young, and Kim, Il-Doo
- Abstract
Wearable energy storage system must maintain robust electrochemical performance under severe mechanical and chemical deformations. Here, we demonstrate wearable supercapacitor system assembled with electrodes composed of one-step carbonized plant epidermis and gelatin based hydrogel electrolyte which possesses high electrochemical performance and superior reliability under ambient condition. The carbonized mulberry paper (MP) was used as an electrode to achieve improved volumetric energy density as well as mechanical-chemical reliability (e.g. mechanical toughness and acid resistance). Rationally designed active materials composed of vertically grown WO 3 NRs and reduced graphene oxide (rGO) anchored on MP, were employed for developing organism epidermis based supercapacitor. Such electrode exhibits high volumetric energy and power densities of 30.28 mWh cm
−3 and 7.67 W cm−3 , retaining the volumetric capacitance of 96.0% even after 110,000 charge-discharge cycles. As the final step, we employed the gelatin based electrolyte with high ionic conductivity to solve evaporation and leakage problems of conventional electrolytes. Organism epidermis based supercapacitor integrated with hydrogel electrolyte showed high electrochemical performance and long-term stability under ambient condition even after exposure to acid, demonstrating its gareat suitability as a large-scale wearable energy storage system. We demonstrate wearable supercapacitor system assembled with electrodes composed of one-step carbonized plant epidermis and gelatin based hydrogel electrolyte which possesses high electrochemical performance and superior reliability under ambient condition. Organism epidermis based supercapacitor integrated with hydrogel electrolyte showed high electrochemical performance and long-term stability under ambient condition even after exposure to acid, demonstrating its great suitability as a large-scale wearable energy storage system. [Display omitted] • We maximized areal and volumetric electrochemical performance (energy & power densities) and mechanical/chemical toughness through carbonized mulberry paper integrated with reduced graphene oxide (rGO) layer. Mulberry fibers inherently show excellent mechanical flexibility and acid resistance, since they have lower portion of lignin cellulose (~40%) compared with conventional paper fiber. However, electrochemically inactive mulberry fiber exhibits still low areal/volumetric energy densities and electrochemical reliability. Thus, we used carbonized mulberry paper as a substrate and electrode in this study, which was maximized for volumetric energy/power densities and mechanical/chemical toughness. • We have designed the plant-root inspired active materials structure with excellent electrochemical reliability and performances. Inspired from plant-root, we synthesized active materials structure by one-step reduction heat treatment, where WO 3 nanorods (NRs) vertically grow within the spaces of rGO and are anchored as strongly as plant-root on the carbonized mulberry fibers. The anchored structure can effectively maintain electrochemical performance and flexibility of carbonized paper by preventing delamination of WO 3 NRs even without protection layer. WO 3 NRs anchored carbonized mulberry paper (thickness 110 µm) with rGO layer exhibits volumetric capacitance retention of 96% for 110,000 cycles. In addition, maximum volumetric energy and power densities were increased to 30.28 mWh cm−3 and 7.67 W cm−3 (improvement of 220%). • Conventional liquid and gel-type electrolyte have critical issues including evaporation under ambient condition and leakage under mechanical bending-twisting deformation. Such problems are main causes of rapid electrochemical performance degradation. In our work, gelatin based hydrogel electrolyte extracted from porcine skin was integrated with electrode, in order to fabricate wearable energy storage system that is capable of operating in ambient conditions. The gelatin based hydrogel electrolyte can retain water contents and high ionic conductivity under ambient condition over 2 weeks. Ionic conductivity maintained 90.3% (228 mS cm−1 ) after two weeks of exposure to ambient condition, and the moisture content was maintained 98.0%. • We further extended organism epidermis based supercapacitor to large-scale application capable of operation in ambient condition. High hydrophilicity of mulberry paper enables the uniform deposition of precursor material for growth of WO 3 , i.e, WO 3 precursor, that is dispersed in the aqueous solution. As a result, GO and WO 3 precursor were uniformly deposited on large-area electrode with 9, 25, 49 cm2 followed by carbonization, resulting in the fabrication of large-scale organism epidermis based supercapacitor. [ABSTRACT FROM AUTHOR]- Published
- 2021
- Full Text
- View/download PDF
9. Organism epidermis/plant-root inspired ultra-stable supercapacitor for large-scale wearable energy storage applications
- Author
-
Yun, Tae Gwang, Jang, Ji-Soo, Cheong, Jun Young, and Kim, Il-Doo
- Abstract
Wearable energy storage system must maintain robust electrochemical performance under severe mechanical and chemical deformations. Here, we demonstrate wearable supercapacitor system assembled with electrodes composed of one-step carbonized plant epidermis and gelatin based hydrogel electrolyte which possesses high electrochemical performance and superior reliability under ambient condition. The carbonized mulberry paper (MP) was used as an electrode to achieve improved volumetric energy density as well as mechanical-chemical reliability (e.g. mechanical toughness and acid resistance). Rationally designed active materials composed of vertically grown WO3NRs and reduced graphene oxide (rGO) anchored on MP, were employed for developing organism epidermis based supercapacitor. Such electrode exhibits high volumetric energy and power densities of 30.28 mWh cm-3and 7.67Wcm-3, retaining the volumetric capacitance of 96.0% even after 110,000 charge-discharge cycles. As the final step, we employed the gelatin based electrolyte with high ionic conductivity to solve evaporation and leakage problems of conventional electrolytes. Organism epidermis based supercapacitor integrated with hydrogel electrolyte showed high electrochemical performance and long-term stability under ambient condition even after exposure to acid, demonstrating its great suitability as a large-scale wearable energy storage system.
- Published
- 2021
- Full Text
- View/download PDF
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