1. Direct chemical synthesis of ultrathin holey iron doped cobalt oxide nanosheets on nickel foam for oxygen evolution reaction.
- Author
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Li, Ying, Li, Fu-Min, Meng, Xin-Ying, Wu, Xin-Ru, Li, Shu-Ni, and Chen, Yu
- Abstract
Abstract The oxygen evolution reaction (OER) on the anode is a vital electrocatalytic reaction in the field of energy conversion. Currently, transition metals-based nanomaterials are promising Ir/Ru-alternative OER electrocatalysts in alkaline media. In this work, we report that in-situ direct growth of atomically thick Fe doped Co 3 O 4 holey nanosheets on nickel foam (Fe-Co 3 O 4 H-NSs/NF) using a simple cyanogel−NaBH 4 route, which effectively avoids the tedious post-etch process of nanosheets using plasma, acid, alkali, and so on. Benefiting from ultrathin thickness (1.5 nm), numerous holes, and synergistic effect between Co and Fe atoms, Fe-Co 3 O 4 H-NSs/NF provide a large specific surface area (199.12 m
2 g−1 ) and highly active catalytic sites for the OER. Meanwhile, nickel foam substrate with three-dimensionally porous structure and high conductivity accelerates molecules/ions/gases transportation and electron transfer. Consequently, Fe-Co 3 O 4 H-NSs/NF with optimal Co/Fe composition show super electrocatalytic performance for the OER, including an overpotential as small as ∼204 mV at 10 mA cm−2 current density and a small Tafel slope of 38 mV dec−1 , which is much better than commercial RuO 2 nanoparticles. Graphical abstract fx1 Highlights • Fe-Co 3 O 4 H-NSs/NF are obtained by a simple cyanogel−NaBH 4 route. • CoIII -CoII cyanogel precursor plays a key role for Fe-Co 3 O 4 H-NSs/NF formation. • The thickness of Fe-Co 3 O 4 H-NSs is only ca. 1.5 nm. • Fe-Co 3 O 4 H-NSs/NF with abundant pores own the high surface area and numerous defected atoms. • Fe-Co 3 O 4 H-NSs/NF have a very small overpotential for the oxygen evolution reaction in the alkaline media. [ABSTRACT FROM AUTHOR]- Published
- 2018
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