1. Absorbing Visible Light Materials of Subphthalocyanine and C70 for Efficient Planar-Mixed Organic Photovoltaic Devices.
- Author
-
Shun-Wei Liu, Wei-Cheng Su, Chih-Chien Lee, Ching-Wen Cheng, Chia-Chang Chou, and Chun-Feng Lin
- Subjects
PHOTOVOLTAIC power systems ,HETEROJUNCTIONS ,PHTHALOCYANINES ,ENERGY conversion ,ATOMIC force microscopy ,PHASE separation method (Engineering) - Abstract
The authors report on a highly efficient small-molecule organic photovoltaic device employing a planar-mixed heterojunction structure with subphthalocyanine (SubPc) as the donor and C70 as the acceptor. By changing the mixing ratio of SubPc and C
70 , the power conversion efficiency can be significantly improved from 1.8% to 6.0% under air mass 1.5 G solar illumination. From the internal quantum efficiency measurement, the highest carrier extraction is observed when an optimized weight ratio for SubPc to C70 of 1:7 is used. Besides, atomic force microscopy images demonstrate that a good phase separation of the blend layer is realized under such an optimized mixing ratio. This phenomenon may contribute to the improved fill factor and hence the bulk resistance. As a result, the JSC of our device is significantly enhanced to 13.0 mA/cm², which is almost twice the conventional value for planar heterojunction SubPc devices. [ABSTRACT FROM AUTHOR]- Published
- 2013
- Full Text
- View/download PDF