1. Investigation of Pre-lithiation in Graphite and Hard-Carbon Anodes Using Different Lithium Source Structures.
- Author
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Shellikeri, A., Watson, V., Adams, D., Kalu, E. E., Read, J. A., Jow, T. R., Zheng, J. S., and Zheng, J. P.
- Subjects
GRAPHITE ,LITHIATION ,ENERGY density - Abstract
Energy storage devices like batteries and supercapacitors, have become indispensable in portable devices and electric vehicles. But, the carbon anodes used in these devices, exhibit a significant loss in their initial capacity (graphite: 6.6% and hard carbon: 29.8%) due to the consumption of Li ions from electrolyte during solid electrolyte interface layer formation and other non-reversible reactions, and if unaddressed, can potentially diminish this advantage. Pre-lithiation treatment of carbon anodes can mitigate this loss, apart from improving the cell working potential, hence enhancing cell energy density and cyclability. We investigate in this report a direct-contact lithiation process in graphite and hard carbon anodes using four distinct lithium source structures. The results show that the type of Li-source structure employed for anode pre-lithiation can have a major impact on the electrode physical properties, pre-lithiation times and the pre-lithiation anode potentials achieved, potentially effecting the SEI properties, cycle life, and the electrode processing costs. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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