1. A Physical Insight of Phase-Dependent Electron Transfer Kinetic Behaviors and Electrocatalytic Activity of an Iron Oxide-Based Sensing Nanoplatform Towards Chloramphenicol.
- Author
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Ngo, Xuan Dinh, Phung, Thi Lan Huong, Nguyen, Ngoc Huyen, Nguyen, Tuan Anh, Vinh, Nguyen Thanh, Quy, Nguyen Van, and Le, Anh-Tuan
- Subjects
CHARGE exchange ,CHLORAMPHENICOL ,ELECTROCHEMICAL sensors ,ELECTROLYTIC reduction ,IRON ,OXYGEN reduction - Abstract
Insight into the phase-dependent electron transfer kinetics and electrocatalytic activity of metal oxide nanostructures is important in the rational design of functional nanostructures for realizing high-performance electrochemical sensors. This study focuses on elucidating the effect of the crystalline phase on the electron transfer kinetics and electrocatalytic activity of iron(III) oxide. The α -FeOOH, γ -Fe
2 O3 , and α -Fe2 O3 nanorods were designed by using a simple chemical method and calcining process. The phase-dependent difference in the electron transfer kinetics and electrocatalytic activity toward the sensitive response of chloramphenicol (CAP) is observed by the transformation from α -FeOOH to γ -Fe2 O3 , and from α -FeOOH to α -Fe2 O3 nanorods. We found that the oxygen vacancies formed in phase transformation from α -FeOOH to α -Fe2 O3 is a key factor in promoting the electrochemical reduction of chloramphenicol. The α -Fe2 O3 nanorods-based electrochemical sensors showed a linear response in the CAP concentration range from 0.1 to 75 μ M with a limit of detection of 60 nM and an electrochemical sensitivity of 2.86 μ A μ M−1 cm−2 . This work further provides valuable physical insight into the phase-dependent electron transfer kinetics and electrocatalytic activity of metal oxide nanostructures for the rational design of sensing interface. [ABSTRACT FROM AUTHOR]- Published
- 2024
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