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This review article is focused on the development and application of two types of emerging two-dimensional (2D) materials, namely MXenes and MBenes, in the field of gas detection. Owing to its excellent electrical conductivity, specific surface area, and tunable surface functionality, MXenes have demonstrated high sensitivity and rapid response in detecting a variety of gases, such as volatile organic compounds (VOCs), nitrogen dioxide (NO2), and ammonia (NH3). MBenes are relatively newly discovered materials with excellent electronic stability and gas adsorption capabilities. Both of these materials demonstrate significant potential in improving sensor selectivity and stability through surface functionalization and heterostructure designs. However, despite the impressive gas detection performance of these materials, challenges remain in achieving long-term stability, cost-effectiveness, and commercialization. We summarize the prominent research insights on these materials and offer an outlook on future research directions and potential applications. With ongoing research and technological advancements, MXenes and MBenes are anticipated to have a substantial impact in critical areas such as environmental monitoring and industrial safety.

Monodisperse, hierarchical α-MoO3hollow spheres were fabricated using a facile template-free solvothermal method combined with subsequent calcination. Various quantities of Au nanoparticles (NPs) were deposited on the α-MoO3hollow spheres to construct hybrid nanomaterials for chemical gas sensors and their BTX sensing properties were investigated. The 2.04 wt % Au-loaded α-MoO3sensor can detect BTX effectively at 250 °C, especially, its responses to 100 ppm toluene and xylene are 17.5 and 22.1, respectively, which are 4.6 and 3.9 times higher than those of pure α-MoO3hollow spheres at 290 °C. Besides, Au loading decreased the response times to toluene and xylene from 19 and 6 s to 1.6 and 2 s, respectively, lowered the working temperature from 290 to 250 °C as compared with those of pure α-MoO3. The surface status of Au/α-MoO3hollow spheres before and after contacting with toluene at 250 °C was analyzed through XPS technique. Possible oxidization product of toluene was confirmed by GC for the first time. The gas-sensing mechanism of the Au/α-MoO3was speculated as the oxidation of toluene to water and carbon dioxide by chemisorbed oxygen and lattice oxygen. The possible reason related with improved gas-sensing properties of the Au-functionalized α-MoO3was discussed.

The toxicity of soil irrigated with treated domestic wastewater (site A) and untreated gray wastewater (site B) were investigated. Soil extracts were prepared using distilled water, acid solvent (0.1 mol·L−1HCl), and organic solvent (acetone:petroleum ether: cyclohexane = 1:1:1) to understand the type of pollutants responsible for the ecotoxicity associated with wastewater irrigation. The soil toxicity was assessed using a luminescence inhibition assay with Vibrio fischerifor acute toxicity, a micronucleus assay with Vicia fabaroot tips and a single cell gel electrophoresis assay of mice lymphocytes for genotoxicity. The physicochemical properties and the heavy metal (HM) contents of the irrigated soil were also analyzed. The results indicated that the wastewater irrigation at site A had no effects on the soil properties. With the exception of Pb, Zn, Fe, and Mn, the accumulation of HMs (Cu, Ni, and Cr) occurred. However, the irrigation at site A did not result in obvious acute toxicity or genotoxicity in the soil. The soil properties changed greatly, and HMs (Cu, Ni, and Cr) accumulated in site B. There were significant increases in the acute toxic and genotoxic effects in the soils from site B. The ecotoxicity in site B came primarily from organic-extractable pollutants.

Common problems in engineering projects that involve artificial ground freezing of soil or rock include inadequate thickness, strength and continuity of artificial frozen walls. It is difficult to evaluate the freezing state using only a few thermometer holes at fixed positions or with other existing approaches. Here we report a novel experimental design that investigates changes in ultrasonic properties (received waveform, wave velocity Vp, wave amplitude, frequency spectrum, centroid frequency fc, kurtosis of the frequency spectrum KFS, and quality factor Q) measured during upward freezing, compared with those during uniform freezing, in order to determine the freezing state in 150 mm cubic blocks of Ardingly sandstone. Water content, porosity and density were estimated during upward freezing to ascertain water migration and changes of porosity and density at different stages. The period of receiving the wave increased substantially and coda waves changed from loose to compact during both upward and uniform freezing. The trend of increasing Vpcan be divided into three stages during uniform freezing. During upward freezing, Vpincreased more or less uniformly. The frequency spectrum could be used as a convenient and rapid method to identify different freezing states of sandstone (unfrozen, upward frozen, and uniformly frozen). The continuous changes in reflection coefficient rφ, refraction coefficient tφand acoustic impedance field are the major reason for larger reflection and refraction during upward freezing compared with uniform freezing. Wave velocity Vp, wave amplitude Ah, centroid frequency fcand quality factor Qwere adopted as ultrasonic parameters to evaluate quantitatively the temperature Tof uniformly frozen sandstone, and their application within a radar chart is recommended. Determination of Vpprovides a convenient method to evaluate the freezing state and calculate the cryofront height and frozen section thickness of upward frozen sandstone, with accuracies of 73.37%–99.23%. © 2022 Institute of Rock and Soil Mechanics, Chinese Academy of Sciences. Production and hosting by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

A novel membrane receptor of immunoglobulin gene superfamily (IgSF) has been identified from mouse dendritic cells (DC) and designated as DC-derived Ig-like receptor 1 (DIgR1). It encodes a 228-amino-acid (aa) residue polypeptide with a 21-aa signal peptide, a 20-aa transmembrane region, a 189-aa extracellular region, and a 19 aa intracellular region. Its extracellular region contains a single V domain of Ig. So it is a novel type I transmembrane glycoprotein of IgSF. DIgR1 shows significant homologies to human CMRF-35 antigens and polymeric immunoglobulin receptors (pIgR). The mRNA expression of DIgR1 was highly abundant in mouse spleen. The preferential expression of DIgR1 mRNA is observed in the known antigen-presenting cells (APC) including DC, monocytes/macrophages, and B lymphocytes. A 40 kDa of protein in NIH/3T3 cells transfected with the DIgR1 cDNA was detected by Western blot analysis using anti-DIgR1 polyclonal antibodies. The expression of DIgR1 protein on DC is not regulated by LPS stimulation. Further study should be conducted to investigate what were biological functions of DIgR1 in the immunobiology of APC.

The C2H2 zinc finger protein family is one of the largest families of transcription factors. We identified a novel BTB/POZ zinc finger gene from human dendritic cells (DC), which encodes a 733-residue protein with a BTB/POZ domain at the N-terminal and 4 C2H2 zinc fingers at C-terminal. It was designated dendritic cell-derived BTB/POZ zinc finger (DPZF). DPZF protein shares closest homology to BCL-6, with the highest homology present in the BTB/POZ and zinc finger domains. Like BCL-6, DPZF gene is localized on chromosome 3. It is widely expressed in hematopoietic tissues, including DC, monocytes, B cells, and T cells. DPZF protein expression is detectable in lymphoid neoplasm with a molecular mass of 100 kD, especially in B lymphoma. These indicate that DPZF may be a transcription factor closely related to BCL-6, and may be involved in hematopoiesis, oncogenesis, and immune responses.