Author: "Stefan Spirk" / Database: Supplemental Index - Searchworks@Jio Institute Digital Library Search Results

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Author: Tamilselvan Mohan, Raffael Rathner, David Reishofer, Martin Koller, Thomas Elschner, Stefan Spirk, Thomas Heinze, Karin Stana-Kleinschek, and Rupert Kargl
Published: 2015
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Author: Stefan Spirk, Ferdinand Belaj, JoÌrg H. Albering, and Rudolf Pietschnig
Published: 2010
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Author: Stefan, Spirk, Belaj, Ferdinand, Madl, Tobias, and Pietschnig, Rudolf
Abstract: The reaction of the nitroxy radical 2,2,6,6tetramethylpiperidineNoxyl TEMPO with SiCl4has been investigated in detail. One siliconcontaining product, TEMPOSiCl31, could be isolated in crystalline form, and its crystal structure was determined. The structural parameters have been compared with the related hydroxylaminotrichlorosilane known from the literature and with DFT calculations. According to the calculations, the formation of 1follows an SN2 mechanism, which is thermodynamically favored over an SN1 pathway. Upon hydrolysis, 1decomposes and yields several TEMPOcontaining species. These were all characterized crystallographically.
Published: 2010
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