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1. Solid-state Rotaxane Switch: Synthesis of Thermoresponsive Rotaxane Shuttle Utilizing a Thermally Decomposable Acid.

Author

Nan Zhu, Kazuko Nakazono, and Toshikazu Takata

Abstract

A thermoresponsive crown ether/amine-type rotaxane switch worked under solvent-free condition was developed. The wheel component moved to switch the local position on the axle by the solid-state acidbase reaction between tert-amine moiety of the rotaxane and trichloroacetic acid. The wheel shuttling on the axle proceeded via neutralization by heating and protonation with trichloroacetic acid, being confirmed by ¹NMR and TGA. [ABSTRACT FROM AUTHOR]

Published
2016
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