1. Sensitive detection of nitrogen dioxide gas at room temperature using poly(3,4-ethylenedioxythiophene) nanotubes.
- Author
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Shaik, Mahabul, Rao, V.K., Sinha, A.K., Murthy, K.S.R.C., and Jain, Rajeev
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ISOTHERMAL processes ,CHEMICALS - Abstract
In the present work, we report on room temperature sensing of nitrogen dioxide (NO 2 ) gas using nanotubes made of intrinsically conducting poly(3,4-ethylenedioxythiophene) (PEDOT). The nanotubes of PEDOT (PEDOT-NT) were prepared by reverse emulsion polymerization method and characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS) and Fourier transformation infrared spectroscopy (FTIR). The thin film of PEDOT-NT on prefabricated gold interdigitated electrodes (IDEs) was obtained by drop drying the suspension of PEDOT-NT in N , N ′-dimethylformamide. The PEDOT-NT coated IDE sensor showed good response towards sensing NO 2 at room temperature. The recovery of the sensor was accelerated by ultra-violet light illumination. The proposed sensor showed excellent characteristics such as high sensitivity (1.316%/ppm), low detection limit of 80 ppb (at S/N = 3) and linear concentration range of 0.2–20 ppm for sensing NO 2 gas. The proposed sensor also showed excellent selectivity in respect of interfering gases such as H 2 S, NH 3, SO 2, CO, ethanol, acetone and benzene. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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