55 results on '"Peijs, Ton"'
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2. Self-reinforced biodegradable thermoplastic composites
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Colwell, John, Halley, Peter, Varley, Russell, Heidarian, Pejman, McNally, Tony, Peijs, Ton, and Vandi, Luigi
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Improvements in the mechanical performance of biodegradable plastics are required to facilitate replacement of commodity plastics as part of a global push for the use of more sustainable materials. Reinforcing biodegradable plastics with fillers or fibres to create composite materials is an obvious choice for increasing mechanical properties but may affect recyclability and biodegradability. To avoid these issues, self-reinforced polymer composites (SRPCs), where the polymer matrix is reinforced with highly oriented films, fibres, or particles of the same polymer may be used. However, the use of biodegradable thermoplastics in SRPCs is currently limited to a few polymers, mostly focusing on poly(lactic acid) (PLA). Here, we have assessed the potential for a broader range of biodegradable thermoplastics to replace commercially available commodity-plastic-based SRPCs. This assessment was done using literature data for the oriented and isotropic bulk mechanical properties of commercially relevant biodegradable thermoplastics, along with properties for their SRPCs where available. It was found that despite polycaprolactone (PCL), poly(butylene succinate) (PBS), poly(butylene succinate adipate) (PBSA), and poly(butylene adipate terephthalate) (PBAT) not being suitable replacements for current commercially available SRPCs, they nonetheless exhibit increased modulus and strength after orientation. PLA, polyhydroxyalkanoates (PHAs), and poly(glycolic acid) (PGA) have more potential, with PGA being the most promising, although PLA and PHAs appear to offer potentially more sustainable alternatives to commercially available SRPCs and a wider range of end-of-life disposal options.
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- 2024
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3. Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) Self-Reinforced Composites via Solvent-Induced Interfiber Welding of Nanofibers
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Heidarian, Pejman, Aziz, Shazed, Halley, Peter J., McNally, Tony, Peijs, Ton, Vandi, Luigi-Jules, and Varley, Russell J.
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In this study, we explore an approach to enhance the mechanical performance of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) by utilizing the self-reinforcing effect of β-phase-induced PHBV electrospun nanofiber mats. This involves electrospinning combined with low-temperature postspun vapor solvent interfiber welding. Scanning electron microscopy imaging confirmed fiber alignment, while XRD diffraction revealed the presence of both α and β crystalline phases under optimized electrospinning conditions. The resulting composite exhibited significant improvements in mechanical properties attributed to the formation of more perfectly structured α and β polymorphs and enhanced interfacial adhesion of electrospun nanofibers after vapor solvent treatment. This approach offers entirely recyclable and biodegradable materials, presenting the potential for a new family of sustainable bioplastics.
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- 2024
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4. Ultra-High Actuation Stress Polymer Actuators as Light-Driven Artificial Muscles.
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Asghar Bhatti, Muhammad Rehan, Bilotti, Emiliano, Han Zhang, Varghese, Shaji, Verpaalen, Rob C. P., Schenning, Albert P. H. J., Bastiaansen, Cees W. M., and Peijs, Ton
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- 2020
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5. High-Performance Transparent Laminates Based on Highly Oriented Polyethylene Films.
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Lin, Yunyin, Cao, Jun, Zhu, Meifang, Bilotti, Emiliano, Zhang, Han, Bastiaansen, Cees W. M., and Peijs, Ton
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- 2020
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6. Nanoengineered electrospun fibers and their biomedical applications: a review
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Zhang, Xi, Shi, Xuetao, Gautrot, Julien E., and Peijs, Ton
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AbstractElectrospun fibers have received significant interests for various application areas such as filtration, composites and biomedical products due to their large surface area, good continuity, high porosity and many other unique properties. In bio-related applications, electrospun fibers have been used for in-situ drug delivery, tissue engineering scaffolds and wound dressing. In more recent years, there has been a drive toward novel electrospun fibers with added functionalities. Nanoengineering of electrospun fibers has introduced many of such novel properties. Through this review, researchers are provided with a state of the art overview of nanoenhanced electrospun fibers with added functionalities. Examples of some nanoengineered fibers include; surface functionalization, multi-component fibers, porous nanofibers, the creation of surface nano-topographies, and the incorporation of nanoparticles to create hierarchical fibrous structures for tailoring of physicochemical properties with a special focus on biomedical applications.
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- 2021
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7. On the low reinforcing efficiency of carbon nanotubes in high-performance polymer fibres
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Goutianos, Stergios and Peijs, Ton
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AbstractDriven by the exceptionally high mechanical properties of carbon nanotubes (CNTs), over the years an extensive research effort has been devoted to the reinforcement of high-performance polymer fibres with CNTs. However, to date, improvements in the strength of these fibres have been rather modest even for relatively high CNT contents. After a brief review of CNT reinforced polymer fibres, here, analytical and numerical finite element models will be used to show that these experimental findings are to be expected based on the intrinsic mechanical properties of these polymer fibres and CNTs, their aspect ratio and interfacial characteristics. Results show that for realistic CNT contents and aspect ratios, the extraordinary strength of CNTs cannot be easily fully exploited in high-performance polymer fibres like Dyneema®or Kevlar®. Even if CNTs are perfectly aligned, bonded and dispersed, the low intrinsic shear strength of these highly anisotropic polymer fibres limits effective stress transfer and nanotube reinforcement.
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- 2021
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8. Functionalization of electrospun PLA fibers using amphiphilic block copolymers for use in carboxy-methyl-cellulose hydrogel composites
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Zhang, Xi, Megone, William, Peijs, Ton, and Gautrot, Julien E.
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AbstractCarboxy-methyl-cellulose (CMC) hydrogels, prepared in the presence of a crosslinker and photoinitiator, were reinforced with 3.7 wt% electrospun PLA fibers to create CMC hydrogel composites. To improve fiber-matrix adhesion, electrospun fiber mats based on hybrids of PLA and amphiphilic block copolymer (BCP) poly(D,L-lactide)-block-poly[2-(dimethylamino)ethyl methacrylate] (PLA-b-PDMAEMA) were produced. The presence of PDMAEMA at the fiber surface induced hydrophilic surface properties, which could be controlled by varying the PDMAEMA chain length. PDMAEMA was quaternized and co-electrospun with PLA fibers, which further enhanced the interaction between fibers and hydrogel matrix viaionic interactions. Physicochemical properties of the electrospun fiber mats and their CMC hydrogel based composites were assessed and revealed a nearly two orders of magnitude increase in modulus. Continuous electrospun fiber mats were chopped into discontinuous fibers to create short fiber reinforced CMC hydrogels. Rheological properties of these reinforced hydrogels incorporating 0.5 wt% discontinuous fibers were evaluated and showed potential as injectable composite systems for biomedical applications.
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- 2020
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9. Ultra-High Actuation Stress Polymer Actuators as Light-Driven Artificial Muscles
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Bhatti, Muhammad Rehan Asghar, Bilotti, Emiliano, Zhang, Han, Varghese, Shaji, Verpaalen, Rob C. P., Schenning, Albert P. H. J., Bastiaansen, Cees W. M., and Peijs, Ton
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Remotely addressable actuators are of great interest in fields like microrobotics and smart textiles because of their simplicity, integrity, flexibility, and lightweight. However, most of the existing actuator systems are composed of complex assemblies and/or offer a low response rate. Here, the actuation performance of a light-driven, highly oriented film based on ultra-high molecular weight polyethylene (UHMW-PE), containing a photo-responsive additive, 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (BZT), is reported. The material exhibits a fast (<1 s) and reversible photo-induced thermal response upon exposure to UV light, which results in an exceptionally high actuation stress (∼70 MPa) at a low strain (<0.1%). The proposed actuation mechanism originates from light absorption by BZT and energy transfer into heat, in combination with the intrinsic high stiffness (∼80 GPa) and a negative thermal expansion (NTE) of the oriented polymer films. This unique set of properties of this actuator, in particular the very high specific actuation stress, compared to existing organic and inorganic actuators, and the remote optical actuation, promises impact in fields related to soft robotics, composites, medical devices, optics, prosthetics, and smart textiles.
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- 2020
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10. Fast, Light-Responsive, Metal-Like Polymer Actuators Generating High Stresses at Low Strain
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Verpaalen, Rob C.P., Varghese, Shaji, Froyen, Arne, Pilz da Cunha, Marina, Pouderoijen, Maarten J., Severn, John R., Bhatti, Muhammad R., Peijs, Ton, Bastiaansen, Cees W.M., Debije, Michael G., Engels, Tom A.P., and Schenning, Albertus P.H.J.
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Producing lightweight polymeric actuators able to generate high stresses typical of hard metals and/or ceramics remains challenging. The photo-mechanical responses of ultra-drawn ultra-high molecular weight polyethylene (UHMWPE) actuators containing azobenzene photo-switches with symmetrically attached polyethylene (PE) side chains are reported. Long PE side chains promote dispersion within the apolar UHMWPE matrix, and the ultra-drawn films are highly aligned. The ultra-drawn azobenzene-doped UHMWPE films have high Young's moduli (∼100 GPa) and are viscoelastic at room temperature at strains below 1%. The photo-mechanical response of the films is fast (<1 s), showing a high specific actuation stress response (>6 × 104Pa (kg m−3)−1) to UV or visible light at a low strain (∼0.06%). The actuator responds to rotating linearly polarized light, causing a photo-induced stress wave response. Such rapid, high-stress, low-strain, photo-mechanical responses are unique in soft polymer systems with physical values approaching hard metals/ceramics.
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- 2020
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11. High-modulus rotary jet spun co-polyimide nanofibers and their composites
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Rogalski, James J., Zhang, Han, Yao, Jian, Bastiaansen, Cees W. M., and Peijs, Ton
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AbstractThe production of high-modulus and high-strength polymer nanofibers using centrifugal or rotary jet spinning (RJS) was explored. Co-polyimide nanofibers based on 3,3′,4,4′-biphenyl-tetracarboxylic dianhydride (BPDA)/p-phenylenediamine (PDA)/4,4′-oxydianiline (ODA) (BPO) were successfully spun by RJS from a polyamic acid precursor solution before conversion into highly oriented and chain extended BPO co-polyimide fibers via an imidization step. Fourier transform infrared (FTIR) characterization was used to evaluate the chemical conversion of the fibers. Nanocomposite laminates based on co-polyimide nonwoven fiber mats in epoxy were manufactured for mechanical testing. Analysis using the generalized rule of mixtures resulted in a back-calculated fiber modulus and strength of around 50 and 2 GPa, approaching that of high-performance fibers like Kevlar®29, and equaling those of co-polyimide fibers obtained via electrospinning, making them the strongest centrifugal spun fibers ever reported.
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- 2020
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12. Turning low-cost recycled paper into high-value binder-free all-cellulose panel products
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Arévalo, Raquel, Soykeabkaew, Nattakan, and Peijs, Ton
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In this work, the feasibility of producing low-cost, recyclable and biodegradable binderless all-cellulose fibreboards was demonstrated through the successful manufacturing of self-binding composites based on recycled paper and kraft fibres. These all-cellulose composites were made by a simple and environmentally friendly solvent-free mechanical fibrillation method using water as a processing aid. Kraft fibres and recycled paper pulp were mixed in a 30/70 w/w ratio and refined simultaneously in a Valley beater for different periods of time. The mechanical properties of the composites, consisting of a ‘matrix’ of recycled paper reinforced with kraft fibres, were highly dependent on the level of fibrillation of the kraft fibres. Optimal levels of fibrillation resulted in a good balance of self-binding properties and reinforcing efficiency. The hot-pressed all-cellulose panels exhibited a flexural strength of 75 MPa and a modulus of 5·9 GPa, which are impressive values compared with those of conventional fibreboard materials. In addition, these panels showed better water resistance than some existing wood panel products. These binder-free all-cellulose composites have potential as cost-effective sustainable alternatives to existing panel board products, as they are entirely made from renewable and recycled materials, which at the end of life can potentially be recycled or composted, making them perfectly fit for a circular economy.
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- 2019
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13. Nanoclay assisted ultra-drawing of polypropylene tapes
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van Erp, Tim B., Reynolds, Christopher T., Bilotti, Emiliano, and Peijs, Ton
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AbstractIsotactic polypropylene (i-PP) – montmorillonite (MMT) nanocomposite films were prepared by melt-compounding and hot-pressing. The influence of organoclays on the mechanical properties and drawability of these isotropic composite films was investigated. Ultimate properties of solid-state drawn PP tapes incorporating 2.5 wt% MMT outperformed those of pure PP tapes. Interestingly, these improvements were found not to be the result of a mechanical reinforcement effect of the nanoclay platelets but merely the result of a more efficient ultra-drawing mechanism with MMT acting as a processing additive that altered initial polymer morphology and drawing behaviour. Hence, the introduction of MMT resulted in higher ultimate draw ratios and subsequently higher ultimate mechanical properties of the oriented nanocomposite tapes.
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- 2019
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14. Tissue-Engineered Trachea Consisting of Electrospun Patterned sc-PLA/GO-g-IL Fibrous Membranes with Antibacterial Property and 3D-Printed Skeletons with Elasticity
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Kang, Yuan, Wang, Chaoli, Qiao, Youbei, Gu, Junwei, Zhang, Han, Peijs, Ton, Kong, Jie, Zhang, Guangcheng, and Shi, Xuetao
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In this study, a tissue-engineered trachea, consisting of multilevel structural electrospun polylactide (PLA) membranes enveloping 3D-printed thermoplastic polyurethane (TPU) skeletons, was developed to create a mechanically robust, antibacterial and bioresorbable graft for the tracheal reconstruction. The study design incorporated two distinct uses of stereocomplex PLA: patterned electrospun fibers to enhance tissue integration compared to the random layered fibers, meanwhile possessing good antibacterial property; and 3D-printed TPU scaffold with elasticity to provide external support and protection. Herein, ionic liquid (IL)-functioned graphene oxide (GO) was synthesized and presented enhanced mechanical and hydrophilicity properties. More interesting, antibacterial activity of the GO-g-IL modified PLA membranes were proved by Escherichia coliand Staphylococcus aureus, showing superior antibacterial effect compared to single GO or IL. The synergistic antibacterial effect could be related to that GO break cytomembrane of bacteria by its extremely sharp edges, while IL works by electrostatic interaction between its cationic structures and electronegative phosphate groups of bacteria membranes, leading to the loss of cell electrolyte and cell death. Hence, after L929 fibroblast cells were seeded on patterned fibrous membranes with phenotypic shape, further effective cell infiltration, cell proliferation and attachment were observed. In addition, the tissue-engineered trachea scaffolds were implanted into rabbit models. The in vivoresult confirmed that the scaffolds with patterned membranes manifested favorable biocompatibility and promoted tissue regeneration.
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- 2019
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15. Nonlinear creep response of oriented polypropylene tapes
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Barkoula, Nektaria M, Alcock, Ben, van Erp, Tim B, Govaert, Leon E, and Peijs, Ton
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The creep response of a highly oriented polypropylene tape used for the manufacture of self-reinforced polypropylene or all-polypropylene composites was studied over a range of stresses and temperatures. Similar to oriented polyethylene, the creep compliance is linear viscoelastic at short loading times, whereas pronounced stress dependence is observed at longer loading times. A mathematical model is proposed, where the total deformation of the fibre is regarded as being composed of a stress-linear delayed elastic component and a nonlinear plastic flow contribution. Model predictions are in good agreement with the experimental data.
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- 2018
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16. Long-term performance and durability of polycarbonate/carbon nanotube nanocomposites
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Pastukhov, Leonid V., Mercx, Frans P. M., Peijs, Ton, and Govaert, Leon E.
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AbstractDue to their good mechanical properties, low density, and ease of processing polymer nanocomposites are of interest for a multitude of applications in the automotive, electronics, and leisure industry. Besides having an impact on short-term mechanical performance of polymers, the addition of nanoreinforcements can have also a significant effect on long-term properties such as the resistance to static (creep) and cyclic (fatigue) loadings. However, despite its significance there is a shortage of long-term mechanical performance data for thermoplastic-based polymer nanocomposites. Reason being that existing characterization methods for long-term performance and durability are time consuming and limited in their applicability. Here, an engineering approach to predict long-term time-to-failure of polycarbonate/carbon nanotube (PC/CNT) nanocomposites is presented based on short-term experimentation with an application to both creep and fatigue. Results showed that the addition of CNTs had an opposite effect on two important long-term failure mechanisms. Addition of CNTs lead to improvements in durability in the plasticity-controlled failure regime, whereas it had an adverse effect in the slow crack growth-controlled regime, meaning that in the latter regime nanocomposite performance was significantly less than that of the neat polymer matrix.
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- 2018
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17. Breaking the Nanoparticle Loading–Dispersion Dichotomy in Polymer Nanocomposites with the Art of Croissant-Making
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Santagiuliana, Giovanni, Picot, Olivier T., Crespo, Maria, Porwal, Harshit, Zhang, Han, Li, Yan, Rubini, Luca, Colonna, Samuele, Fina, Alberto, Barbieri, Ettore, Spoelstra, Anne B., Mirabello, Giulia, Patterson, Joseph P., Botto, Lorenzo, Pugno, Nicola M., Peijs, Ton, and Bilotti, Emiliano
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The intrinsic properties of nanomaterials offer promise for technological revolutions in many fields, including transportation, soft robotics, and energy. Unfortunately, the exploitation of such properties in polymer nanocomposites is extremely challenging due to the lack of viable dispersion routes when the filler content is high. We usually face a dichotomy between the degree of nanofiller loading and the degree of dispersion (and, thus, performance) because dispersion quality decreases with loading. Here, we demonstrate a potentially scalable pressing-and-folding method (P & F), inspired by the art of croissant-making, to efficiently disperse ultrahigh loadings of nanofillers in polymer matrices. A desired nanofiller dispersion can be achieved simply by selecting a sufficient number of P & F cycles. Because of the fine microstructural control enabled by P & F, mechanical reinforcements close to the theoretical maximum and independent of nanofiller loading (up to 74 vol %) were obtained. We propose a universal model for the P & F dispersion process that is parametrized on an experimentally quantifiable “Dfactor”. The model represents a general guideline for the optimization of nanocomposites with enhanced functionalities including sensing, heat management, and energy storage.
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- 2018
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18. The effect of polymer molar mass and silica nanoparticles on the rheological and mechanical properties of poly(Ε-caprolactone) nanocomposites
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Eriksson, Maria, Peijs, Ton, and Goossens, Han
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AbstractThe influence of nanosilica on the crystallization behavior, rheology and mechanical properties of poly(ε-caprolactone) (PCL) nanocomposites was investigated. It was found that the effect of nanofiller addition is dependent on the molar mass of the polymer matrix. For the higher molar mass matrix, a modest nucleation effect was observed, while in the lower molar mass matrices, this effect was absent. For the investigated range of filler contents, a modest increase in both modulus and ultimate tensile properties of the composites was observed. Lower molar mass matrices revealed voiding during deformation, which could be partly suppressed by the addition of nanofiller. The higher molar mass matrix showed no voiding in either the neat polymer or nanocomposite.
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- 2018
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19. Self-reinforced poly(lactic acid) nanocomposites with integrated bacterial cellulose and its surface modification
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Somord, Kedmanee, Somord, Kamonchanok, Suwantong, Orawan, Thanomsilp, Chuleeporn, Peijs, Ton, and Soykeabkaew, Nattakan
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AbstractBacterial cellulose (BC) nanofibers, with and without silane surface modification, were incorporated into self-reinforced poly(lactic acid) (SR-PLA) nanocomposites at 1 and 10 wt%. Disintegrated BC was combined with electrospun PLA fiber mats by film stacking and compression molding at 165 °C for 40 sec to obtain SR-PLA/BC hybrid films. The effect of nanocellulose addition and its surface modification on the structure, morphology, and properties of the resulting composites were investigated. It was found that BC was a highly effective reinforcement for SR-PLA nanocomposites, providing a noticeable increase in the film’s strength and modulus. Moreover, surface modification of BC was shown to further enhance the film performances due to an improved PLA/BC interfacial interaction. At an optimum BC content, these hybrid films also exhibited outstanding ductility and toughness. Water vapor barrier properties were also enhanced, especially when modified BC was integrated in the SR-PLA films.
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- 2018
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20. The influence of grafting on flow-induced crystallization and rheological properties of poly(ε-caprolactone)/cellulose nanocrystal nanocomposites
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Eriksson, Maria, Goffin, Anne-Lise, Dubois, Philippe, Peijs, Ton, and Goossens, Han
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AbstractThe influence of poly(ε-caprolactone) (PCL) grafts on the rheology and crystallization behavior of nanocomposites based on PCL and cellulose nanocrystals (CNC) both under quiescent and shear conditions is investigated. Under quiescent conditions, the grafted nanocrystals have high nucleation efficiencies. Under the influence of shear, the non-grafted nanocrystals were, however, more efficient in orienting the polymer chains and accelerating the flow-induced crystallization. The addition of large amounts of grafted material decreases the viscosity of the composites and thereby also the efficiency of shear-induced orientation.
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- 2018
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21. The fracture toughness of natural fibre- and glass fibre-reinforced SMC
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Patel, Harish K., Balasubramanian, Vimalan, and Peijs, Ton
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The fracture toughness properties, in terms of stress intensity factor KIcand strain energy release rate GIc, of hemp fibre mat-reinforced sheet moulding compound (H-SMC) are measured using the compact tension (CT) method and compared with those of glass fibre-reinforced SMC (G-SMC). Three material parameters were considered for composite optimisation: fibre volume fraction, CaCO3filler content and hemp fibre surface treatments using either alkaline, silane or a combination of these two treatments. The highest fracture toughness for H-SMC composites was obtained at a fibre loading of around 30 vol.-%, while it was also shown that the fracture toughness properties of H-SMC are sensitive to mineral filler content. Surface treatment of the hemp fibres using a combined alkaline-silane treatment resulted in a significant improvement in fracture toughness of H-SMC composites. Optimised H-SMC composites exhibited fracture toughness properties similar to those of G-SMC at fibre contents of 20 vol.-%, with KIcvalues of around 6 MPa.m-1/2.
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- 2017
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22. Rotary jet spinning review – a potential high yield future for polymer nanofibers
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Rogalski, James J., Bastiaansen, Cees W. M., and Peijs, Ton
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AbstractPolymeric nanofibers have been the focus of much research due to their continually evolving applications in fields such as biomedicine, tissue engineering, composites, filtration, battery separators, and energy storage. Although several methods of producing nanofibers have shown promise for large scale production, none have yet produced large enough volumes at a low cost to be the front runner in the field, and therefore the preferred choice for industrialization. Rotary jet spinning (RJS) could be the answer to high throughput, low cost, and environmentally friendly nanofiber production. Being exploited in only the last decade, it is a technology that has seen relatively little research, but one which could potentially be the answer to large scale manufacturing of polymer nanofibers. In this review, we focus on fundamental processing characteristics and initial application driven research. A comparison between existing nanofiber production methods is drawn with the key differences noted. Two methods of utilizing RJS in nanofiber production are discussed, namely spinning from a polymer melt, and solution-based spinning as is typically used in more traditional methods such as electrospinning. Modeling of the process is introduced, in which material selection and processing parameters play an important role.
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- 2017
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23. The fracture toughness of natural fibre- and glass fibre-reinforced SMC
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Patel, Harish K., Balasubramanian, Vimalan, and Peijs, Ton
- Abstract
ABSTRACTThe fracture toughness properties, in terms of stress intensity factor KIcand strain energy release rate GIc, of hemp fibre mat-reinforced sheet moulding compound (H-SMC) are measured using the compact tension (CT) method and compared with those of glass fibre-reinforced SMC (G-SMC). Three material parameters were considered for composite optimisation: fibre volume fraction, CaCO3filler content and hemp fibre surface treatments using either alkaline, silane or a combination of these two treatments. The highest fracture toughness for H-SMC composites was obtained at a fibre loading of around 30 vol.-%, while it was also shown that the fracture toughness properties of H-SMC are sensitive to mineral filler content. Surface treatment of the hemp fibres using a combined alkaline-silane treatment resulted in a significant improvement in fracture toughness of H-SMC composites. Optimised H-SMC composites exhibited fracture toughness properties similar to those of G-SMC at fibre contents of 20 vol.-%, with KIcvalues of around 6 MPa.m−1/2.
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- 2017
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24. Synergistic effects of filler size on thermal annealing-induced percolation in polylactic acid (PLA)/graphite nanoplatelet (GNP) nanocomposites
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Gao, Yuqing, Picot, Olivier T., Zhang, Han, Bilotti, Emiliano, and Peijs, Ton
- Abstract
AbstractTwo graphene-based nanofillers of different sizes were melt mixed with polylactide acid (PLA). Composite films based on graphite nanoplatelets (GNPs) with the largest lateral size showed superior electrical conductivity and a lower percolation threshold after melt-compounding and hot-pressing at room temperature. However, upon annealing in the melt, composites based on GNPs with the smallest lateral size displayed significantly improved electrical conductivity and a decrease in percolation threshold as a result of dynamic percolation while composites based on large GNPs showed hardly any change in conductivity and percolation threshold. Hybrid filler systems based on 5 wt% GNP with variable small/large GNP filler ratios displayed synergistic effects in the formation of a conductive network during thermal annealing, and an optimum filler ratio of 50/50 was found to achieve the highest conductivity after annealing. This annealing-induced increase in particle connectivity for composites based on 5 wt.% hybrid small/large GNPs was also reflected in rheological measurements by the manifestation of a plateau in the storage modulus at low frequencies after annealing while such phenomenon was not observed for nanocomposites solely based on either small or large GNPs at similar loadings.
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- 2017
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25. In Situ Exfoliation of Graphene in Epoxy Resins: A Facile Strategy to Efficient and Large Scale Graphene Nanocomposites
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Li, Yan, Zhang, Han, Crespo, Maria, Porwal, Harshit, Picot, Olivier, Santagiuliana, Giovanni, Huang, Zhaohui, Barbieri, Ettore, Pugno, Nicola M., Peijs, Ton, and Bilotti, Emiliano
- Abstract
Any industrial application aiming at exploiting the exceptional properties of graphene in composites or coatings is currently limited by finding viable production methods for large volumes of good quality and high aspect ratio graphene, few layer graphene (FLG) or graphite nanoplatelets (GNP). Final properties of the resulting composites are inherently related to those of the initial graphitic nanoparticles, which typically depend on time-consuming, resource-demanding and/or low yield liquid exfoliation processes. In addition, efficient dispersion of these nanofillers in polymer matrices, and their interaction, is of paramount importance. Here we show that it is possible to produce graphene/epoxy nanocomposites in situ and with high conversion of graphite to FLG/GNP through the process of three-roll milling (TRM), without the need of any additives, solvents, compatibilisers or chemical treatments. This readily scalable production method allows for more than 5 wt % of natural graphite (NG) to be directly exfoliated into FLG/GNP and dispersed in an epoxy resin. The in situ exfoliated graphitic nanoplatelets, with average aspect ratios of 300–1000 and thicknesses of 5–17 nm, were demonstrated to conferee exceptional enhancements in mechanical and electrical properties to the epoxy resin. The above conclusions are discussed and interpreted in terms of simple analytical models.
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- 2016
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26. Effect of mixed fillers on positive temperature coefficient of conductive polymer composites
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Asare, Eric, Basir, Al, Tu, Wei, Porwal, Harshit, Zhang, Han, Liu, Yi, Evans, Jamie, Newton, Mark, Peijs, Ton, and Bilotti, Emiliano
- Abstract
AbstractThis paper investigates the trade-off between low percolation threshold and large positive temperature coefficient (PTC) intensity in conductive polymer composites (CPCs). Conductive particles with low aspect ratios and large dimensions have been demonstrated to induce large PTC intensity in CPCs. Conversely high aspect ratio conductive (nano)particles like carbon nanotubes (CNTs) are desirable because of their extremely low percolation threshold (typically well below 1 wt.%), providing benefits in terms of reduced density, brittleness, costs and improved processability. Herein we report on combinations of different conductive fillers to explore the possibility to obtain both low percolation threshold and high PTC intensity. For the first time we use model systems in which at least one of the two conductive fillers is of relatively homogenous size and shape to facilitate unraveling some of the complicated inter-relationships between (mixed) conductive fillers and the PTC effect.
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- 2016
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27. The use of carbon nanotubes for damage sensing and structural health monitoring in laminated composites: a review
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Zhang, Han, Bilotti, Emiliano, and Peijs, Ton
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AbstractThe increasing use of fiber-reinforced plastics (FRPs) in industries such as aerospace, marine, and automotive, has resulted in a necessity to monitor the structural integrity of composite structures and materials. Apart from development of traditional non-destructive testing methods which are performed off-line, there is a growing need to integrate structural health monitoring (SHM) systems within composite structures. An interesting route toward multifunctional composite materials with integrated SHM capabilities is through the introduction of carbon nanotubes (CNTs) in fiber-reinforced composites as this provides not only integrated damage sensing capability, but may, at the same time, also lead to some additional mechanical reinforcement. Since the first use of CNTs for damage sensing in composite laminates, a significant number of studies have dealt with this topic, but a systematic understanding on the use of CNTs in FRPs for SHM is still lacking. Furthermore, a significant gap remains between results obtained in the laboratory and industrial applications. This review reports on the progress of this topic so far. The reviewed work had been categorized from model studies on single fiber composites to laminated composites under different loading conditions, as well as the development of reliable damage-sensing systems which could be transferred to real applications.
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- 2015
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28. High mechanical reinforcing efficiency of layered poly(vinyl alcohol) – graphene oxide nanocomposites
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Sellam, Charline, Zhai, Zhi, Zahabi, Hediyeh, Picot, Olivier T., Deng, Hua, Fu, Qiang, Bilotti, Emiliano, and Peijs, Ton
- Abstract
AbstractA bottom-up approach for producing poly(vinyl alcohol) (PVA)/graphene oxide (GO) nanocomposites using a spray-assisted layer-by-layer (LbL) method is presented. Simple and versatile, the process allows to build up uniform multi-layered nanocomposite films with good morphological control of each layer. A total of 150 bilayers were deposited to create a transparent film with improved mechanical properties at a loading of 5.4 wt% GO. The Young's modulus and tensile strength of these films nearly doubled as a result of the high level of structural organization of the nanocomposite incorporating the two-dimensional (2D) nanofiller, in combination with good interfacial interactions resulting from hydrogen bonding between PVA and the GO sheets.
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- 2015
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29. The RAPIDOS project—European and Chinese collaborative research on biomaterials
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Eglin, David, Alini, Mauro, de Bruijn, Joost, Gautrot, Julien, Grijpma, Dirk W., Kamer, Lukas, Lai, Yuxiao, Lu, Shibi, Peijs, Ton, Peng, Jian, Tang, Ting Ting, Wang, Xianluan, Wang, Xinjiang, Richards, R. Geoff, and Qin, Ling
- Abstract
The research project entitled “rapid prototyping of custom-made bone-forming tissue engineering constructs” (RAPIDOS) is one of the three unique projects that are the result of the first coordinated call for research proposals in biomaterials launched by the European Union Commission and the National Natural Science Foundation of China in 2013 for facilitating bilateral translational research. We formed the RAPIDOS European and Chinese consortium with the aim of applying technologies creating custom-made tissue engineered constructs made of resorbable polymer and calcium phosphate ceramic composites specifically designed by integrating the following: (1) imaging and information technologies, (2) biomaterials and process engineering, and (3) biological and biomedical engineering for novel and truly translational bone repair solutions. Advanced solid free form fabrication technologies, precise stereolithography, and low-temperature rapid prototyping provide the necessary control to create innovative high-resolution medical implants. The use of Chinese medicine extracts, such as the bone anabolic factor icaritin, which has been shown to promote osteogenic differentiation of stem cells and enhance bone healing in vivo, is a safe and technologically relevant alternative to the intensely debated growth factors delivery strategies. This unique initiative driven by a global consortium is expected to accelerate scientific progress in the important field of biomaterials and to foster strong scientific cooperation between China and Europe.
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- 2015
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30. Influence of drying procedure on glass transition temperature of PMMA based nanocomposites
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Eriksson, Maria, Goossens, Han, and Peijs, Ton
- Abstract
AbstractA literature review of poly(methyl methacrylate) (PMMA) nanocomposites shows inconsistent results regarding the influence of the addition of nanofillers on the mobility of the system. In academic research, solvent based preparation methods are often used to prepare nanocomposites with the aim to obtain a good and controlled dispersion. However, little attention is paid to the influence of the used solvent on the properties of the nanocomposites. We show that in PMMA nanocomposites prepared via solution casting from different solvents, the apparent decrease in glass transition temperature is caused by insufficient drying and that when an adequate drying procedure is used, an increase in glass transition temperature is always observed.
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- 2015
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31. Piezoresistive polymer composites based on EPDM and MWNTs for strain sensing applications.
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Ciselli, Paola, Lan Lu, Busfield, James J. C., and Peijs, Ton
- Subjects
ELASTOMERS ,MONOMERS ,CARBON nanotubes ,MECHANICAL behavior of materials ,PRESSURE transducers ,ELECTRIC conductivity ,DEFORMATIONS (Mechanics) - Abstract
Elastomeric composites based on Ethylene-Propylene-Diene-Monomer (EPDM) filled with multi-wall carbon nanotubes (MWNTs) have been prepared, showing improved mechanical properties as compared to the pure EPDM matrix. The results have been discussed using the Guth model. The main focus of the study was on the electrical behavior of these conductive polymer composites (CPCs), in view of possible sensor applications. A linear relation has been found between conductivity and deformations up to 10% strain, which means that such materials could be used for applications such as strain or pressure sensors. Cyclic experiments were conducted to establish whether the linear relation was reversible, which is an important requirement for sensor materials. [ABSTRACT FROM AUTHOR]
- Published
- 2010
32. Composites turn green!
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Peijs, Ton
- Subjects
COMPOSITE materials ,GLASS fibers ,WOOD ,SYNTHETIC products - Abstract
Presents a paper that aims to provide a short review on developments in the area of eco-composites and their applications. Information on wood fibre plastics; Advantages of plant fibres over glass fibres; Application of eco-composites in various industries.
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- 2002
33. New Approach toward Reflective Films and Fibers Using Cholesteric Liquid-Crystal Coatings
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Picot, Olivier T., Dai, Mian, Broer, Dirk J., Peijs, Ton, and Bastiaansen, Cees W. M.
- Abstract
A new approach for the production of oriented films and fibers with angular-dependent reflective colors is presented. The process consists of spray coating a solution of cholesteric liquid-crystalline monomers onto a melt-processed and oriented polyamide-6 substrate followed by UV curing. Reflectivity measurements and optical microscopy show that a well-defined liquid-crystalline and planar alignment is obtained. It is further demonstrated that a reflection up to 80% is obtained by coating oriented films on both sides of the oriented substrate with a single-handedness cholesteric liquid-crystal coating. The high reflectivity is attributed to the close to half-wave retardation induced by the anisotropic polymer substrate. Also, polyamide-6 filaments are successfully coated and fibers are obtained with an angular-dependent color in a single dimension along the fiber direction, which originates from the planar cholesteric alignment on a curved surface.
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- 2013
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34. Humidity-Responsive Bilayer Actuators Based on a Liquid-Crystalline Polymer Network
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Dai, Mian, Picot, Olivier T., Verjans, Julien M. N., de Haan, Laurens T., Schenning, Albertus P. H. J., Peijs, Ton, and Bastiaansen, Cees W. M.
- Abstract
A humidity-responsive bilayer actuator has been developed that consists of an oriented polyamide-6 substrate and a liquid-crystalline polymer coating. The oriented substrate acts as an alignment layer for the liquid crystal. The liquid-crystalline polymer consists of a supramolecular network having hydrogen-bonded entities that, after activation with an alkaline solution, exhibit deformation in response to a change in humidity. The bending behavior of the bilayer actuator was analyzed, showing a large response to a change in the humidity.
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- 2013
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35. Manufacture of Void-Free Electrospun Polymer Nanofiber Composites with Optimized Mechanical Properties
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Stachewicz, Urszula, Modaresifar, Farid, Bailey, Russell J., Peijs, Ton, and Barber, Asa H.
- Abstract
Engineered fiber reinforced polymer composites require effective impregnation of polymer matrix within the fibers to form coherent interfaces. In this work, we investigated solution interactions with electrospun fiber mats for the manufacture of nanocomposites with optimized mechanical properties. Void free composites of electrospun nonwoven PA6 nanofibers were manufactured using a PVA matrix that is introduced into the nonwoven mat using a solution-based processing method. The highest failure stress of the composites was reported for an optimum 16 wt % of PVA in solution, indicating the removal of voids in the composite as the PVA solution both impregnates the nanofiber network and fills all the pores of the network with PVA matrix upon evaporation of the solvent. These processing methods are effective for achieving coherent nanofiber–matrix interfaces, with further functionality demonstrated for optically transparent electrospun nanofiber composites.
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- 2012
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36. Processing of PolypropyleneCarbon Nanotube Composites using scCO2Assisted Mixing
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Ma, Jia, Deng, Hua, and Peijs, Ton
- Abstract
scCO2was used to assist in the preparation of PPCNT composites. Two types of CNTs were used: MWNTs with and without HDPE coating cMWNTs. The morphology of the nanocomposites and their mechanical and thermal properties were investigated and compared with samples made by traditional melt compounding. The use of cMWNT leads to better dispersion and properties in meltcompounded nanocomposites. For systems prepared using scCO2assisted mixing, however, better properties were obtained using pristine MWNTs, avoiding the additional costs of nanotube modification. It was also shown that observed improvements in the mechanical properties for these materials were due to a combination of matrix modification and nanotube reinforcement, rather than a reinforcement effect caused solely by MWNTs.
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- 2010
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37. Preparation of High‐Performance Conductive Polymer Fibers through Morphological Control of Networks Formed by Nanofillers
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Deng, Hua, Skipa, Tetyana, Bilotti, Emiliano, Zhang, Rui, Lellinger, Dirk, Mezzo, Luca, Fu, Qiang, Alig, Ingo, and Peijs, Ton
- Abstract
A general method is described to prepare high‐performance conductive polymer fibers or tapes. In this method, bicomponent tapes/fibers containing two layers of conductive polymer composites (CPCs) filled with multiwall carbon nanotubes (MWNT) or carbon black (CB) based on a lower‐melting‐temperature polymer and an unfilled polymer core with higher melting temperature are fabricated by a melt‐based process. Morphological control of the conductive network formed by nanofillers is realized by solid‐state drawing and annealing. Information on the morphological and electrical change of the highly oriented conductive nanofiller network in CPC bicomponent tapes during relaxation, melting, and crystallization of the polymer matrix is reported for the first time. The conductivity of these polypropylene tapes can be as high as 275 S m−1with tensile strengths of around 500 MPa. To the best of the authors' knowledge, it is the most conductive, high‐strength polymer fiber produced by melt‐processing reported in literature, despite the fact that only ∼5 wt.% of MWNTs are used in the outer layers of the tape and the overall MWNT content in the bicomponent tape can be much lower (typically ∼0.5 wt.%). Their applications could include sensing, smart textiles, electrodes for flexible solar cells, and electromagnetic interference (EMI) shielding. Furthermore, a modeling approach was used to study the relaxation process of highly oriented conductive networks formed by carbon nanofillers.
- Published
- 2010
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38. All-Aramid Composites by Partial Fiber Dissolution
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Zhang, Jian Min, Mousavi, Zeinab, Soykeabkaew, Nattakan, Smith, Paul, Nishino, Takashi, and Peijs, Ton
- Abstract
The area of self-reinforced polymer composites is one of the fastest growing areas in engineering polymers, but until now these materials have been mainly developed on the basis of thermoplastic fibers of moderate performance. In this work, we report on a new type of self-reinforced composites based on high-performance aramid fibers to produce an “all-aramid” composite by applying a surface-dissolution method to fuse poly(p-phenylene terephthalamide) (PPTA) fibers together. After immersion in concentrated (95%) sulphuric acid (H2SO4) for a selected period of time, partially dissolved fiber surfaces were converted into a PPTA interphase or matrix phase. Following extraction of H2SO4and drying, a consolidated all-aramid composite was formed. The structure, mechanical- and thermal properties of these single-polymer composites were investigated. Optimum processing conditions resulted in unidirectional composites of high reinforcement content (∼75 vol %) and good interfacial bonding. The all-aramid composites featured a Young’s modulus of ∼65 GPa at room temperature, and a tensile strength of 1.4 GPa, which are comparable with or exceed the corresponding values of conventional aramid/epoxy composites. However, since fiber, matrix and interphase in all-aramid composites are based on the same high-temperature resistant PPTA polymer, a high modulus of ∼50 GPa was maintained up to 250 °C, demonstrating the potential of these materials for high-temperature applications.
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- 2010
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39. Synergistic Reinforcement of Highly Oriented Poly(propylene) Tapes by Sepiolite Nanoclay
- Author
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Bilotti, Emiliano, Deng, Hua, Zhang, Rui, Lu, Dun, Bras, Wim, Fischer, Hartmut R., and Peijs, Ton
- Abstract
This paper reports the properties of highly oriented nanocomposite tapes based on isotactic PP and needlelike sepiolite nanoclay, obtained by a solid state drawing process. The intrinsic 1D character of sepiolite allows its exploitation in 1D objects, such as oriented polymer fibres and tapes, where it can be uniaxially oriented upon drawing. A synergistic increase in mechanical properties is presented for highly drawn tapes λ ≤ 20 and low filler loadings ≤2.5 wt., which can not be simply explained by micromechanical composite models. Instead, mechanical properties are intimately related to the dispersion state of the nanoclays in PP, the rheological properties of the nanocomposites and the polymer morphology.
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- 2010
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40. A Novel Concept for Highly Oriented Carbon Nanotube Composite Tapes or Fibres with High Strength and Electrical Conductivity
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Deng, Hua, Zhang, Rui, Reynolds, Christopher T., Bilotti, Emiliano, and Peijs, Ton
- Abstract
A new concept is described for the creation of multifunctional polymer nanocomposite tapes or fibres that combines high stiffness and strength with good electrical properties and a low percolation threshold of carbon nanotubes CNTs. The concept is based on a bicomponent tape or fibre construction consisting of a highly oriented polymer core and a conductive polymer composite CPC skin based on a polymer with a lower melting temperature than the core, enabling thermal annealing of these skins to improve conductivity through a dynamic percolation process while retaining the properties of the core and hence those of the tape or fibre. The percolation threshold in the CPC skins of the highly drawn conductive bicomponent tapes could be decreased from 5.3 to 1.1 wt. after annealing.
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- 2009
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41. Recyclable PP/Polyamide Composite*
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Abraham, Thomas N, George, K.E., and Peijs, Ton.
- Abstract
A commercial grade of polypropylene matrix reinforced with waste polyamide (nylon 6) fibres of two diameters at levels up to 40wt% (100 polypropylene + 40 polyamide) was studied.Smaller diameter fibres showed better mechanical properties than larger diameter ones. Attempts were made to improve the interfacial adhesion between the fibres and the matrix by grafting with maleic anhydride and with also styrene maleic anhydride. The mechanical properties showed significant improvements as a result of these modifications. Thermal stability was also marginally improved. These composites could be easily recycled by processing them above the melting point of the reinforcing fibres.
- Published
- 2005
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42. Influence of Matrix Ductility and Fibre Architecture on the Repeated Impact Response of Glass-Fibre-Reinforced Laminated Composites
- Author
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Schrauwen, Bernard and Peijs, Ton
- Abstract
This paper describes the results of falling weight impact tests on glass-fibre-reinforced laminates. The test program consisted of (i) falling weight impact tests for the determination of the penetration energy and the influence of laminate construction on damage development and (ii) repeated falling weight impact tests for the determination of the impact fatigue lifetime and damage development under repeated impact conditions at sub-penetration energy levels. The objective of this work is to compare the impact behaviour of cross-ply laminates based on a brittle unsaturated polyester resin and a more ductile vinyl ester resin system and two types of glass reinforcement, i.e. woven- and multiaxial non-crimp fabric. The penetration energy of the various composite laminates appeared to be mainly influenced by the type of reinforcement, whereas damage development during (repeated) impact is strongly influenced by both fibre architecture and resin. No significant effect of the different material parameters investigated on the number of impacts to penetration (impact fatigue lifetime) is observed. Especially when the repeated impact energy is normalised with respect to the penetration energy, all laminates showed similar behaviour.
- Published
- 2002
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43. Influence of Hybridisation and Test Geometry on the Impact Response of Glass-Fibre-Reinforced Laminated Composites
- Author
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Schrauwen, Bernard, Bertens, Pascal, and Peijs, Ton
- Abstract
This paper describes the results of falling weight impact tests (FWITs) on glass-fibre-reinforced (GRP) laminates and E-glass/Dyneema®hybrid laminates. The test programme consisted of (i) falling weight impact tests to determine the penetration energy and (ii) experiments to determine the influence of hybrid construction on damage development and impact fatigue lifetime under repeated impact conditions at sub-penetration energy levels. The objective of this work was to investigate the effect of hybridisation on the impact behaviour of GRP laminates as well as to find optimal conditions for hybridisation. It was shown that in the case of a rigid test set-up - and hence small deflections - the influence of the Dyneema®on the impact behaviour of hybrid laminates is rather small because damage processes are the result of local contact stresses in the vicinity of the impact body, whereas in the case of a compliant test set-up and large deflections the high energy storage capacity of the ductile Dyneema®fibres is used far more effectively for the protection of hybrid composite laminates. Therefore, it was concluded that in order to fully utilise the potential of high-performance polyethylene fibres it is essential that these fibres are located on the (non-impacted) tensile side of an impacted laminate and that the geometrical test conditions are such that large (bending) deformations are allowed.
- Published
- 2002
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44. Micromechanical Modeling of Time-Dependent Transverse Failure in Composite Systems
- Author
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Govaert, Leon and Peijs, Ton
- Abstract
The time-dependent failure behaviour of transversely loadedcomposites is investigated, assuming that fracture is matrix dominated.Since the stress and strain state of the matrix in composite structuresis complex, the yield and fracture behaviour of a neat epoxy system isinvestigated under various multi-axial loading conditions. A gooddescription of the multi-axial yielding behaviour of the matrix materialis obtained with the three-dimensional pressure modified Eyringequation. The parameters of this three-dimensional yield expression areimplemented into a constitutive model, which has been shown to correctly describe the deformation behaviour of polymers under complex loadings.By means of a micromechanical approach, the matrix dominated transversestrength of a unidirectional composite material was investigated.Numerical simulations show that a failure criterion based on maximumstrain provides a good description for the rate-dependent transversestrength of unidirectional glass/epoxy composites. Furthermore, such astrain criterion is also able to describe the durability (creep) oftransversely loaded unidirectional composites.
- Published
- 2000
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45. Natural Fiber Based Composites
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Peijs, Ton
- Published
- 2000
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46. Thermoplastic composites based on flax fibres and polypropylene: Influence of fibre length and fibre volume fraction on mechanical properties
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Peijs, Ton, Garkhail, Sanjeev, Heijenrath, Rob, van Den Oever, Martien, and Bos, Harriëtte
- Abstract
Natural‐fibre‐mat‐reinforced thermoplastic (NMT) composites based on flax fibre mats and a Polypropylene (PP) matrix were manufactured using (i) a film‐stacking method and (ii) a paper making process. The influence of fibre length and fibre content on stiffness and strength is reported and compared with data for glass‐mat‐reinforced thermoplastic (GMT) composites, including the influence of using maleic‐anhydride grafted PP. The data is also compared with existing micromechanical models like Kelly‐Tyson and Cox‐Krenchel for strength and stiffness, respectively. A good agreement was found between theory and experiment in case of stiffness while in case of strength the experimental values fall well below the theoretical predictions. Results indicated that NMTs are of interest for low‐cost engineering applications and can compete with commercial GMTs, especially when a high stiffness per unit weight is desirable. Results also indicated that the key area for future development lies not only in improved adhesion but mainly in improving the fibre strength.
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- 1998
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47. Post-impact damage tolerance of natural fibre-reinforced sheet moulding compound
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Patel, Harish K and Peijs, Ton
- Abstract
Natural fibre composites are of interest for a wide range of semi-structural applications in the building, construction and automotive sector. For a number of these applications, the evaluation of performance degradation after impact is of some relevance. The present work focused on the influence of fibre volume fraction and fibre surface treatment on the residual load-bearing capability of hemp fibre-reinforced sheet moulding compound (H-SMC) after non-penetrating impacts. Post-impact flexural strength and stiffness of H-SMC decreased linearly with increasing impact energy. At higher impact energy levels, the residual flexural strength of H-SMC improved with increasing fibre volume fraction. However, for the same amount of absorbed energy, the residual strength or damage tolerance capability of glass fibre-reinforced sheet moulding compound was about twice that of H-SMC. Composites based on surface treated hemp fibres showed a slight improvement in residual flexural strength, particularly for systems based on hemp fibres treated with a combined alkaline and silane surface treatment. Surface treated systems showed improved levels of adhesion and increased levels of energy absorption through potential mechanisms such as debonding, pull-out or fibre fibrillation.
- Published
- 2020
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48. First International Conference On Eco-Composites (ECOCOMP)
- Author
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Peijs, Ton
- Published
- 2001
- Full Text
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49. Electrospinning of High-performance Co-polyimide Nanofibers.
- Author
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Jian Yao, Bastiaansen, Cees W. M., and Peijs, Ton
- Abstract
Co-polyimide nanofibers based on BPDA (3, 3', 4, 4'- Biphenyltetracarboxylic dianhydride)/PDA (p-Phenylenediamine)/ ODA (4, 4'-Oxydianiline) are fabricated through electrospinning and imidization from its precursor polyamic acid (PAA). The resulting nanofiber bundles show high Young's moduli and tensile strengths of 38±0.3 GPa and 1630±15 MPa, respectively. [ABSTRACT FROM AUTHOR]
- Published
- 2013
50. Editorial
- Author
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Peijs, Ton
- Published
- 2015
- Full Text
- View/download PDF
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