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Pyrite is the most common among the group of sulfide minerals in the Earth and abundant in most geological settings. This gangue mineral in association with garnet, hematite, magnetite, and other sulfide minerals acts as an indicator mineral in the Kubi concession of the Asante Gold corporation in Ghana. X-ray diffraction (XRD), air annealing in a furnace, energy-dispersive x-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) were applied to investigate the crystal structure, identify individual elements, permanence, transformation, and chemical/electronic properties of such pyrite. The study aims to identify individual elements and to gain an understanding of the surface reaction mechanisms, as well as the properties of precipitated pyrite particles observed during the hydrothermal formation of the ore deposit. XRD shows that pristine and annealed samples contain some hematite and quartz besides pyrite. Results from air annealing indicate that the relationship between pyrite and hematite-magnetite is controlled by temperature. EDX reveals that the sample has O and C as contaminants, while XPS in addition reveals Ba, Au, P, Al, and N. These elements are attributed to pyrite that bonds metallically or covalently to neighboring ligands/impurity minerals such as oxides, chalcogenide sulfides, as well as the gangue alteration minerals of magnetite and hematite in the pyrite sample.

ABSTRACTThe Wa-Lawra Belt which is situated in the northern part of Ghana consists of Paleoproterozoic Birimian fine metasedimentary rocks metamorphosed to greenschist facies, particularly, in the western part. A whole-rock geochemical study of these metasedimentary rocks was undertaken to unravel their source area weathering, provenance and tectonic setting. Geochemical characteristics of the studied shales show that they are immature in nature and first cycle in origin, with little or no recycled component. Compared to Post-Archaean Australian Shales (PAAS), the studied shales indicate reduction in Zr, Hf, La, Nb, Th and Ta being the high field strength elements and evidences of transition metal enrichments in V, Ni, Sc, Co, and Cr. Major element geochemistry indicates that the shales were subjected to slight potassium metasomatism after deposition. Pre-metasomatized Chemical Index of Alteration calculations indicates that weak to moderate degree of chemical weathering took place at the sediment source area. Co-Th-La-Sc systematics reveals a combination of mafic and felsic provenances for the shales. Eu/Eu* together with values of Th/U and some abundances of trace elements show that the shales were mainly derived from juvenile rocks. Average REE model calculations suggest that the source materials are composed of about 49% basalt, 16% TTG and 35% granite.