860 results on '"Kinnunen P."'
Search Results
2. Influence of additives, temperature, and pressure on the morphology of nesquehonite– results from three synthesis routes
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Back, Jens, Ismailov, Arnold, Sreenivasan, Harisankar, Smått, Jan-Henrik, Santos, Hellen Silva, Nguyen, Hoang, Levänen, Erkki, Zevenhoven, Ron, and Kinnunen, Paivo
- Abstract
Carbon mineralization is expected to play a key role in the mitigation of climate change, as viable and efficient carbon capture and utilization (CCU) pathway. Indeed, the process has the advantage of enabling the recycling of waste-streams such as mine tailings or desalination brine, as well as the prospect of large-scale uptake of carbon dioxide emissions. However, the applications of the produced carbonates still hinder the commercial feasibility of the existing CCU routes, especially when hydrated Mg carbonates (HMCs) are obtained. HMCs are thermodynamically unstable, which poses potential risks in long-term stability. Nesquehonite (NQ, MgCO3·3H2O) is the major product of Mg carbonation in most aqueous reaction settings at moderate temperatures (15–50 °C), which has demonstrated suitable properties for producing construction materials. At somewhat higher temperatures (50–100 °C) hydromagnesite is obtained (4MgCO3·Mg(OH)2·4H2O). Yet, the final applications are not feasible as NQ often converts to hydromagnesite or other HMCs over time causing liberation of CO2and volume instability. A key scientific gap remains on the relationship between the morphology of NQ with the operational settings of the carbonation reaction. In turn, such understanding is needed to enable tuning NQ applications in construction materials. Therefore, the current work reports the observed features of NQ via three different synthetic routes, showing the effect of two additives (Mg acetate, and sodium dodecyl sulphate), and overpressure CO2on the physico-chemical features of NQ formed from magnesium chloride or sulphate solutions and from brucite-water system and sCO2conditions.
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- 2025
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3. Endorsing organisations towards international business: insights from Finland
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Sauvola, Jaakko, Hyysalo, Jarkko, Kinnunen, Matti, Kosonen, Paavo, Jokitalo, Pekka, Jurmu, Marko, and Riekki, Jukka
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Growth and internationalisation are challenges for SMEs that may lack the necessary resources and networks. For example, in Finland, the scope of the companies is often too limited, or the companies are too small to compete for large business with international clients. We propose a solution to this challenge; a systematic way to build research to business networks and agile working models to endorse growth and internationalisation. We present a case study on how Allied ICT Finland (AIF) helps Finnish companies in building projects and capabilities towards internationalisation. AIF supports companies in creating new solutions by combining usually separate areas of special knowledge and expertise, R&D platforms and resources, and using these to create globally attractive products and services. AIF increases Finnish competitive edge by combining business development, shared RDI environments, funding expertise, research and ecosystems. We believe that the experiences can also be adapted and utilised elsewhere.
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- 2025
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4. Comorbidity and Medication Trends in Chronic Kidney Disease and Incident Atrial Fibrillation: A Nationwide Cohort Study
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Jyrkilä, Heini, Kaartinen, Kati, Martola, Leena, Halminen, Olli, Haukka, Jari, Linna, Miika, Mustonen, Pirjo, Putaala, Jukka, Teppo, Konsta, Kinnunen, Janne, Hartikainen, Juha, Airaksinen, K.E. Juhani, and Lehto, Mika
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Introduction:Chronic kidney disease (CKD) is associated with an increased incidence of atrial fibrillation (AF). Also, patients with AF are prone to adverse kidney outcomes. We examined comorbidities and medication use in patients with CKD and incident AF. Methods:The Finnish AntiCoagulation in Atrial Fibrillation (FinACAF) is a nationwide retrospective register-linkage study including data from 168,233 patients with incident AF from 2007 to 2018, with laboratory data from 2010 onwards. Estimated glomerular filtration rate (eGFR) was available for 124,936 patients. The cohort was divided into 5 CKD stages with separate groups for dialysis and kidney transplantation. Results:At AF diagnosis eGFR <60 mL/min/1.73 m2was found in 27%, while 318 (0.3%) patients were on dialysis, and 188 (0.2%) had a functioning kidney transplant. Lowering eGFR yielded more comorbidities and medications. During 2010–2018 in patients with eGFR <60 mL/min/1.73 m2prevalence of hypertension, dyslipidaemia, and diabetes increased from 82 to 88%, from 50 to 66% and from 25 to 33%, respectively (<0.001). Throughout the observation period, lipid-lowering medication was underused. Conclusion:More than one-fourth of patients with incident AF also had CKD stage 3–5 (eGFR <60 mL/min/1.73 m2). Both comorbidities and medication use increased with worsening kidney function. Prevalence of major cardiovascular (CV) risk factors increased during 2010–2018, but the use of survival-affecting medications, such as lipid-lowering medication, was suboptimal at all stages of CKD. More attention should be given to the optimal treatment of risk factors in this high CV risk population.
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- 2024
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5. Effect of Ammonium Sulfate on the Precipitation Mechanism of Mg Carbonates.
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Santos, Hellen S., Nguyen, Hoang, Illikainen, Sofia, Alzeer, Mohammad I. M., Cunha, Sílvio, and Kinnunen, Paivo
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- 2024
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6. Effect of Ammonium Sulfate on the Precipitation Mechanism of Mg Carbonates
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Santos, Hellen S., Nguyen, Hoang, Illikainen, Sofia, Alzeer, Mohammad I. M., Cunha, Sílvio, and Kinnunen, Paivo
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The carbonation of Magnesium feedstocks is a promising route for carbon capture and utilization since it has the potential to minimize carbon footprints in the construction sector while addressing the criticality of Mg raw materials in the EU. However, the high energy requirements involved in the extraction and carbonation of Mg from Mg-rich feedstocks hinder commercial carbon mineralization. Long-lasting knowledge gaps remain regarding Mg-carbonates precipitation mechanisms and kinetics, known as the geochemical problems related to magnesite and dolomite formation. Despite centuries of research on the topic, it is unknown why these anhydrous Mg carbonates are found in modern geological formations but cannot be synthesized under ambient conditions. This study investigates one of the topics related to this geochemical dilemma, namely, the effect of sulfate ions on Mg-carbonate precipitation, which has contradictory findings in the literature. Recent studies involving molecular dynamics simulations have predicted an acceleratory role of sulfate additives on the precipitation of Mg carbonates, while experimental and geochemical investigations show evidence of inhibitory as well as acceleratory roles. This study explores the effect of solution concentrations on the catalytic role of ammonium sulfate in the precipitation system. The findings demonstrate that ammonium sulfate additives hinder the precipitation of crystalline Mg carbonates under the investigated conditions, shifting the reaction toward the formation of amorphous Mg carbonates at high sulfate concentrations via a nonclassical crystallization pathway.
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- 2024
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7. The Structure and Purpose of Shared Festival Memories: A Storytelling Approach.
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Wood, Emma Harriet, Kinnunen, Maarit, and Coll, Patricia Frances
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STORYTELLING ,FESTIVALS ,MEMORY ,RESONANCE ,AFFECT (Psychology) - Abstract
There is a dearth of research that addresses postfestival experience and particularly the effect of memory sharing on the sharer and the listener. In this article, we gather the memory stories from 11 festival-goers focusing on those they share with others. Analyzing these using Aristotelian storytelling principles helps us understand how they are constructed, what makes them memorable and affective. It allows us to better understand the effects on others of sharing these and the purpose behind sharing. Our findings show that a storytelling analysis provides a rich understanding that has implications for festival design and postevent marketing. We found that emotional resonance in the plot coupled with a moral outcome is often present. More surprisingly, we discovered that each story is condensed to a short phrase or title to aid recall in the teller and the listener. Implications for narrative analysis, postevent marketing, and festival design are discussed. [ABSTRACT FROM AUTHOR]
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- 2024
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8. Inappropriate Behavior at Finnish Live Music Events.
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Kinnunen, Maarit and Honkanen, Antti
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MUSICAL performance ,SPECIAL events ,NONBINARY people ,INTERNET surveys ,AT-risk behavior - Abstract
In this study, we concentrated on Finnish live music events, aiming to study audiences' experiences of inappropriate behavior, particularly the effect of being a member of a minority in the risk of facing such behavior. The research data comprised 19,452 answers to two web surveys; 22% of males, 33% of females, and 64% of nonbinary persons had experienced some or several forms of inappropriate behavior at live music events. The large number of responses from minority group members allowed statistical analysis focusing on their experiences. Being a member of a minority significantly increases the risk of facing inappropriate behavior. The more minority groups a person belongs to, the more likely they are to become harassed or threatened. Event organizers should put more effort into ensuring the quality of experience of minority members, and they should be aware that the way they handle inappropriate behavior is reflected in their reputation. [ABSTRACT FROM AUTHOR]
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- 2024
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9. Experiences of Electronic Health Records' and Client Information Systems' Use on a Mobile Device and Factors Associated With Work Time Savings Among Practical Nurses: Cross-Sectional Study.
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Paatela, Satu, Kyytsönen, Maiju, Saranto, Kaija, Kinnunen, Ulla-Mari, and Vehko, Tuulikki
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PRACTICAL nurses ,HOME care services ,PRACTICAL nursing ,ELECTRONIC health records ,DIGITAL technology - Abstract
Background: The transmission of clinical information in nursing predominantly occurs through digital solutions, such as computers and mobile devices, in today's era. Various technological systems, including electronic health records (EHRs) and client information systems (CISs), can be seamlessly integrated with mobile devices. The use of mobile devices is anticipated to rise, particularly as long-term care is increasingly delivered in environments such as clients' homes, where computers are not readily accessible. However, there is a growing need for more user-centered data to ensure that mobile devices effectively support practical nurses in their daily activities. Objective: This study aims to analyze practical nurses' experiences of using EHRs or CISs on a mobile device in their daily practice. In addition, it aims to examine the factors associated with work time savings when using EHRs/CISs on a mobile device. Methods: A cross-sectional study using an electronic survey was conducted in spring 2022. A total of 3866 practical nurses participated in the survey based on self-assessment. The sample was limited to practical nurses who used EHRs or CISs on a mobile device and worked in home care or service housing within the social welfare or health care sector (n=1014). Logistic regression analysis was used to explore the factors associated with work time savings. Results: The likelihood of perceiving work time savings was higher among more experienced EHR/CIS users compared with those with less experience (odds ratio [OR] 1.59, 95% CI 1.30-1.94). Participants with 0-5 years of work experience were more likely to experience work time savings compared with those who had worked 21 years or more (OR 2.41, 95% CI 1.43-4.07). Practical nurses in home care were also more likely to experience work time savings compared with those working in service housing (OR 1.95, 95% CI 1.23-3.07). A lower grade given for EHRs/CISs was associated with a reduced likelihood of experiencing work time savings (OR 0.76, 95% CI 0.66-0.89). Participants who documented client data in a public area were more likely to experience work time savings compared with those who did so in the nurses' office (OR 2.33, 95% CI 1.27-4.25). Practical nurses who found documentation of client data on a mobile device easy (OR 3.05, 95% CI 2.14-4.34) were more likely to experience work time savings compared with those who did not. Similarly, participants who believed that documentation of client data on a mobile device reduced the need to memorize things (OR 4.10, 95% CI 2.80-6.00) were more likely to experience work time savings compared with those who did not. Conclusions: To enhance the proportion of practical nurses experiencing work time savings, we recommend that organizations offer comprehensive orientation and regular education sessions tailored for mobile device users who have less experience using EHRs or CISs and find mobile devices less intuitive to use. [ABSTRACT FROM AUTHOR]
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- 2024
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10. Ischemic Stroke Temporally Associated With New-Onset Atrial Fibrillation: A Population-Based Registry-Linkage Study.
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Putaala, Jukka, Teppo, Konsta, Halminen, Olli, Haukka, Jari, Tiili, Paula, Jaakkola, Jussi, Karlsson, Elin, Linna, Miika, Mustonen, Pirjo, Kinnunen, Janne, Kiviniemi, Tuomas, Aro, Aapo, Hartikainen, Juha, Airaksinen, Juhani K. E., and Lehto, Mika
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- 2024
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11. Kansalaisten käyttöopas (maa)ilmojen toisin tekemiseen.
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Kinnunen, Veera
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- 2024
12. Nurses' Informatics Competency Assessment of Health Information System Usage: A Cross-sectional Survey.
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Kinnunen, Ulla-Mari, Kuusisto, Anne, Koponen, Samuli, Ahonen, Outi, Kaihlanen, Anu-Marja, Hassinen, Tiina, and Vehko, Tuulikki
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- 2023
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13. Instagram sukupuolittuneen politiikan alustana.
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YLÖSTALO, HANNA and KINNUNEN, HEINI
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DEPOLITICIZATION ,SOCIAL media ,GENDER - Abstract
Copyright of Politiikka is the property of Finnish Political Science Association and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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- 2023
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14. Neuroimaging to Facilitate Clinical Trials in Huntington’s Disease: Current Opinion from the EHDN Imaging Working Group
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Hobbs, Nicola Z., Papoutsi, Marina, Delva, Aline, Kinnunen, Kirsi M., Nakajima, Mitsuko, Van Laere, Koen, Vandenberghe, Wim, Herath, Priyantha, and Scahill, Rachael I.
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Neuroimaging is increasingly being included in clinical trials of Huntington’s disease (HD) for a wide range of purposes from participant selection and safety monitoring, through to demonstration of disease modification. Selection of the appropriate modality and associated analysis tools requires careful consideration. On behalf of the EHDN Imaging Working Group, we present current opinion on the utility and future prospects for inclusion of neuroimaging in HD trials. Covering the key imaging modalities of structural-, functional- and diffusion- MRI, perfusion imaging, positron emission tomography, magnetic resonance spectroscopy, and magnetoencephalography, we address how neuroimaging can be used in HD trials to: 1) Aid patient selection, enrichment, stratification, and safety monitoring; 2) Demonstrate biodistribution, target engagement, and pharmacodynamics; 3) Provide evidence for disease modification; and 4) Understand brain re-organization following therapy. We also present the challenges of translating research methodology into clinical trial settings, including equipment requirements and cost, standardization of acquisition and analysis, patient burden and invasiveness, and interpretation of results. We conclude, that with appropriate consideration of modality, study design and analysis, imaging has huge potential to facilitate effective clinical trials in HD.
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- 2024
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15. t-EER: Parameter-Free Tandem Evaluation of Countermeasures and Biometric Comparators
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Kinnunen, Tomi H., Lee, Kong Aik, Tak, Hemlata, Evans, Nicholas, and Nautsch, Andreas
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Presentation attack (spoofing) detection (PAD) typically operates alongside biometric verification to improve reliablity in the face of spoofing attacks. Even though the two sub-systems operate in tandem to solve the single task of reliable biometric verification, they address different detection tasks and are hence typically evaluated separately. Evidence shows that this approach is suboptimal. We introduce a new metric for the joint evaluation of PAD solutions operating in situ with biometric verification. In contrast to the tandem detection cost function proposed recently, the new tandem equal error rate (t-EER) is parameter free. The combination of two classifiers nonetheless leads to a set of operating points at which false alarm and miss rates are equal and also dependent upon the prevalence of attacks. We therefore introduce the concurrent t-EER, a unique operating point which is invariable to the prevalence of attacks. Using both modality (and even application) agnostic simulated scores, as well as real scores for a voice biometrics application, we demonstrate application of the t-EER to a wide range of biometric system evaluations under attack. The proposed approach is a strong candidate metric for the tandem evaluation of PAD systems and biometric comparators.
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- 2024
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16. Ischemic Stroke Temporally Associated With New-Onset Atrial Fibrillation: A Population-Based Registry-Linkage Study
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Putaala, Jukka, Teppo, Konsta, Halminen, Olli, Haukka, Jari, Tiili, Paula, Jaakkola, Jussi, Karlsson, Elin, Linna, Miika, Mustonen, Pirjo, Kinnunen, Janne, Kiviniemi, Tuomas, Aro, Aapo, Hartikainen, Juha, Airaksinen, Juhani K.E., and Lehto, Mika
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- 2024
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17. Technical Validation and Utility of an HLA Class II Tetramer Assay for Type 1 Diabetes: A Multicenter Study
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Ettinger, Ruth A, Buitinga, Mijke, Vandamme, Céline, Afonso, Georgia, Gomez, Rebecca, Arribas-Layton, David, Bissenova, Samal, Speake, Cate, Reijonen, Helena, Kinnunen, Tuure, Overbergh, Lut, Mallone, Roberto, Kwok, William W, and James, Eddie A
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- 2024
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18. Developmental Perspectives on Transitions at Age 60: Individuals Navigating Across the Lifespan (TRAILS) – latest data collection in a longitudinal JYLS study
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Kokko, Katja, Fadjukoff, Päivi, Reinilä, Emmi, Ahola, Johanna, Kinnunen, Marja-Liisa, Kroger, Jane, Laakkonen, Eija K., Pitkänen, Tuuli, Pulkkinen, Lea, Rantanen, Taina, Staudinger, Ursula M., Taipale, Sakari, Törmäkangas, Timo, Kekäläinen, Tiia, and Saajanaho, Milla
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- 2024
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19. Generalizing Speaker Verification for Spoof Awareness in the Embedding Space
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Liu, Xuechen, Sahidullah, Md, Lee, Kong Aik, and Kinnunen, Tomi
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It is now well-known that automatic speaker verification (ASV) systems can be spoofed using various types of adversaries. The usual approach to counteract ASV systems against such attacks is to develop a separate spoofing countermeasure (CM) module to classify speech input either as a bonafide, or a spoofed utterance. Nevertheless, such a design requires additional computation and utilization efforts at the authentication stage. An alternative strategy involves a single monolithic ASV system designed to handle both zero-effort imposter (non-targets) and spoofing attacks. Such spoof-aware ASV systems have the potential to provide stronger protections and more economic computations. To this end, we propose to generalize the standalone ASV (G-SASV) against spoofing attacks, where we leverage limited training data from CM to enhance a simple backend in the embedding space, without the involvement of a separate CM module during the test (authentication) phase. We propose a novel yet simple backend classifier based on deep neural networks and conduct the study via domain adaptation and multi-task integration of spoof embeddings at the training stage. Experiments are conducted on the ASVspoof 2019 logical access dataset, where we improve the performance of statistical ASV backends on the joint (bonafide and spoofed) and spoofed conditions by a maximum of 36.2% and 49.8% in terms of equal error rates, respectively.
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- 2024
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20. GAN-Aimbots: Using Machine Learning for Cheating in First Person Shooters
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Kanervisto, Anssi, Kinnunen, Tomi, and Hautamaki, Ville
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Playing games with cheaters is not fun, and in a multibillion-dollar video game industry with hundreds of millions of players, game developers aim to improve the security and, consequently, the user experience of their games by preventing cheating. Both traditional software-based methods and statistical systems have been successful in protecting against cheating, but recent advances in the automatic generation of content, such as images or speech, threaten the video game industry; they could be used to generate artificial gameplay indistinguishable from that of legitimate human players. To better understand this threat, we begin by reviewing the current state of multiplayer video game cheating, and then proceed to build a proof-of-concept method, GAN-Aimbot. By gathering data from various players in a first-person shooter game, we show that the method improves players’ performance while remaining hidden from the automatic and manual protection mechanisms. By sharing this article, we hope to raise awareness on this issue and encourage further research into protecting the gaming communities.
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- 2023
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21. Guest editorial: Sharing and belonging in festival and event space: introduction to special issue
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Quinn, Bernadette and Kinnunen, Maarit
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- 2023
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22. Reminiscence and wellbeing – reflecting on past festival experiences during Covid lockdowns
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Wood, Emma Harriet and Kinnunen, Maarit
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Purpose: To explore the value in reminiscing about past festivals as a potential way of improving wellbeing in socially isolated times. Design/methodology/approach: The paper uses previous research on reminiscence, nostalgia and wellbeing to underpin the analysis of self-recorded memory narratives. These were gathered from 13 pairs of festivalgoers during Covid-19 restrictions and included gathering their individual memories and their reminiscences together. The participant pairs were a mix of friends, family and couples who had visited festivals in the UK, Finland and Denmark. Findings: Four key areas that emerged through the analysis were the emotions of nostalgia and anticipation, and the processes of reliving emotions and bonding through memories. Research limitations/implications: Future studies could take a longitudinal approach to see how memory sharing evolves and the impact of this on wellbeing. The authors also recommend undertaking similar studies in other cultural settings. Practical implications: This study findings have implications for both post-festival marketing and for the further development of reminiscence therapy interventions. Originality/value: The method provides a window into memory sharing that has been little used in previous studies. The narratives confirm the value in sharing memories and the positive impact this has on wellbeing. They also illustrate that this happens through positive forms of nostalgia that centre on gratitude and lead to hope and optimism. Anticipation, not emphasised in other studies, was also found to be important in wellbeing and was triggered through looking back at happier times.
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- 2023
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23. Trends in treatment and outcomes of atrial fibrillation during 2007–17 in Finland
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Teppo, Konsta, Airaksinen, K E Juhani, Jaakkola, Jussi, Halminen, Olli, Linna, Miika, Haukka, Jari, Putaala, Jukka, Mustonen, Pirjo, Kinnunen, Janne, Hartikainen, Juha, Aro, Aapo L, and Lehto, Mika
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- 2023
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24. Nursing Informatics' Contribution to One Health
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Peltonen, Laura-Maria, O'Connor, Siobhan, Conway, Aaron, Cook, Robyn, Currie, Leanne M., Goossen, William, Hardiker, Nicholas R., Kinnunen, Ulla-Mari, Ronquillo, Charlene E., Topaz, Maxim, and Rotegård, Ann Kristin
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- 2023
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25. The Use of Digital Health Services Among Patients and Citizens Living at Home: Scoping Review.
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Rosenlund, Milla, Kinnunen, Ulla-Mari, and Saranto, Kaija
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DIGITAL health ,WEB portals ,MEDICAL care ,OLDER people ,PATIENT care - Abstract
Background: The development of digital health services reflects not only the technical development of services but also a change in attitude and the way of thinking. It has become a cornerstone for engaging and activating patients and citizens in health management while living at home. Digital health services are also aimed at enhancing the efficiency and quality of services, while simultaneously providing services more cost-effectively. In 2020, the COVID-19 pandemic accelerated worldwide the development and use of digital services in response to requirements for social distancing and other regulations. Objective: The aim of this review is to identify and summarize how digital health services are being used among patients and citizens while living at home. Methods: The Joanna Briggs Institute (JBI) methodology for scoping reviews was used as guidance. A search conducted in 3 databases (CINAHL, PubMed, Scopus) resulted in 419 papers. The reporting was conducted by the Preferred Reporting Items for Systematic Reviews and Meta-Analyses extension for scoping review (PRISMA-ScR), and the analysis of the included papers was performed using a framework consisting of 5 clusters describing the use of digital health services. After screening and excluding papers that did not match the inclusion criteria, 88 (21%) papers from 2010 to 2022 were included in the final analysis. Results: Results indicated that digital health services are used in different situations and among different kinds of populations. In most studies, digital health services were used in the form of video visits or consultations. The telephone was also used regularly for consultations. Other services, such as remote monitoring and transmitting of recorded information and the use the of internet or portals for searching information, were observed as well. Alerts, emergency systems, and reminders were observed to offer possibilities of use, for example, among older people. The digital health services also showed to have potential for use in patient education. Conclusions: The development of digital services reflects a shift toward the provision of care regardless of time and place. It also reflects a shift toward emphasis on patient-centered care, meaning activating and engaging patients in their own care as they use digital services for various health-related purposes. Despite the development of digital services, many challenges (eg, adequate infrastructure) still prevail worldwide. [ABSTRACT FROM AUTHOR]
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- 2023
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26. Survey of Toxoplasma gondii in Urban and Rural Squirrels (Sciuridae) in Manitoba, Canada.
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Kinnunen, Riikka P., Schmidt, Chloé, Hernández-Ortiz, Adrián, Rahim, Md Niaz, and Garroway, Colin J.
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The coccidian parasite Toxoplasma gondii is found worldwide infecting warm-blooded vertebrates. Felids are the definitive hosts; other species act as intermediate hosts. Squirrels (Sciuridae) generally have high population densities in cities and forage and cache food on the ground, where they may come into contact with T. gondii oocysts or be preyed upon by cats and other carnivores. This environment might make squirrels important intermediate hosts of T. gondii in cities, and infection rates could indicate environmental levels of oocysts in soil. We investigated whether urban squirrels would be more exposed to T. gondii infection than rural squirrels with samples collected from American red squirrels (Tamiasciurus hudsonicus), eastern grey squirrels (Sciurus carolinensis), northern flying squirrels (Glaucomys sabrinus), and least chipmunks (Tamias minimus) in and around Winnipeg, Manitoba, Canada. We tested 230 tissue samples from 46 squirrels for T. gondii DNA by quantitative PCR and 13 serum samples from grey squirrels for T. gondii antibodies by competitive ELISA. We found no evidence of infection in any squirrel, indicating that squirrels are probably not important intermediate hosts of T. gondii in cities and that consumption of oocysts in the soil in general may not be an important contributor to transmission in colder environments. [ABSTRACT FROM AUTHOR]
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- 2023
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27. Hybrid Inorganic–Organic Complexes of Zn, Cd, and Pb with a Cationic Phenanthro-diimine Ligand.
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Temerova, Diana, Chou, Tai-Che, Kisel, Kristina S., Eskelinen, Toni, Kinnunen, Niko, Jänis, Janne, Karttunen, Antti J., Chou, Pi-Tai, and Koshevoy, Igor O.
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- 2022
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28. Are U.S. consumers willing to pay more by the lake? An analysis of preferences for Great Lakes region fish.
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Athnos, April, de Souza, Simone Valle, Quagrainie, Kwamena, Etumnu, Chinonso, Knudson, William, Kinnunen, Ronald E., and Hitchens, Paul
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- 2022
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29. Bringing clarity to the leadership of teaching and learning in higher education: a systematic review
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Kinnunen, Päivi, Ripatti-Torniainen, Leena, Mickwitz, Åsa, and Haarala-Muhonen, Anne
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Purpose: The study aims to investigate the state of higher education (HE) leadership research after the intensified focus on teaching and learning (TL) in academia. Design/methodology/approach: The authors clarify the use of key concepts in English-medium empirical journal articles published between 2017 and 2021 by analysing 64 publications through qualitative content analysis. Findings: The analysed papers on leadership of TL in HE activate a number of concepts, the commonest concepts being academic leadership, distributed leadership, educational leadership, transformational leadership, leadership and transformative leadership. Even if the papers highlight partly overlapping aspects of leadership, the study finds a rationale for the use of several concepts in the HE context. Contrary to the expectation raised in earlier scholarship, no holistic framework evolves from within the recent research to reveal the contribution that leadership of TL makes to leadership in HE generally. Research limitations/implications: Limitations: Nearly 40 per cent of the analysed articles are from the United States of America (USA), United Kingdom (UK), Australia and Canada, which leaves large areas of the world aside. Implications: The found geographical incoherence might be remediated and the research of leadership of TL in HE generally led forward by widening the cultural and situational diversity in the field. Originality/value: This research contributes to an enhanced understanding of the field of leadership in TL in HE in that it frames the concepts used in recent research and makes the differences, similarities and rationale between concepts visible.
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- 2023
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30. Dividends and tax avoidance as drivers of earnings management: Evidence from dividend-paying private SMEs in Finland
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Karjalainen, Jussi, Kasanen, Eero, Kinnunen, Juha, and Niskanen, Jyrki
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ABSTRACTUsing a sample covering practically all dividend-paying small and medium-sized private companies in Finland during 2006–2010, we document that earnings management in these companies is driven by two concurrent forces: the willingness to pay (tax-exempt) dividends and avoiding unnecessary company income tax. Moreover, we show that the need for income-increasing earnings management enabling current dividend distribution is mitigated by the amount of retained earnings from prior years. This article adds to the existing literature by providing empirical evidence for dividend and tax-driven earnings management in private SMEs facing neither political pressures nor capital market incentives for earnings disclosures.
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- 2023
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31. Portable Acceleration of CMS Computing Workflows with Coprocessors as a Service
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Hayrapetyan, A., Tumasyan, A., Adam, W., Andrejkovic, J. W., Bergauer, T., Chatterjee, S., Damanakis, K., Dragicevic, M., Hussain, P. S., Jeitler, M., Krammer, N., Li, A., Liko, D., Mikulec, I., Schieck, J., Schöfbeck, R., Schwarz, D., Sonawane, M., Templ, S., Waltenberger, W., Wulz, C.-E., Darwish, M. R., Janssen, T., Mechelen, P. Van, Bols, E. S., D’Hondt, J., Dansana, S., De Moor, A., Delcourt, M., Faham, H. El, Lowette, S., Makarenko, I., Müller, D., Sahasransu, A. R., Tavernier, S., Tytgat, M., Onsem, G. P. Van, Putte, S. Van, Vannerom, D., Clerbaux, B., Das, A. K., De Lentdecker, G., Favart, L., Gianneios, P., Hohov, D., Jaramillo, J., Khalilzadeh, A., Khan, F. A., Lee, K., Mahdavikhorrami, M., Malara, A., Paredes, S., Thomas, L., Bemden, M. Vanden, Velde, C. Vander, Vanlaer, P., De Coen, M., Dobur, D., Hong, Y., Knolle, J., Lambrecht, L., Mestdach, G., Amarilo, K. Mota, Rendón, C., Samalan, A., Skovpen, K., Bossche, N. Van Den, Linden, J. van der, Wezenbeek, L., Benecke, A., Bethani, A., Bruno, G., Caputo, C., Delaere, C., Donertas, I. S., Giammanco, A., Jaffel, K., Jain, Sa., Lemaitre, V., Lidrych, J., Mastrapasqua, P., Mondal, K., Tran, T. T., Wertz, S., Alves, G. A., Coelho, E., Hensel, C., De Oliveira, T. Menezes, Moraes, A., Teles, P. Rebello, Soeiro, M., Júnior, W. L. Aldá, Pereira, M. Alves Gallo, Filho, M. Barroso Ferreira, Malbouisson, H. Brandao, Carvalho, W., Chinellato, J., Da Costa, E. M., Da Silveira, G. G., De Jesus Damiao, D., De Souza, S. Fonseca, De Souza, R. Gomes, Martins, J., Herrera, C. Mora, Mundim, L., Nogima, H., Pinheiro, J. P., Santoro, A., Sznajder, A., Thiel, M., Pereira, A. Vilela, Bernardes, C. A., Calligaris, L., Tomei, T. R. Fernandez Perez, Gregores, E. M., Mercadante, P. G., Novaes, S. F., Orzari, B., Padula, Sandra S., Aleksandrov, A., Antchev, G., Hadjiiska, R., Iaydjiev, P., Misheva, M., Shopova, M., Sultanov, G., Dimitrov, A., Litov, L., Pavlov, B., Petkov, P., Petrov, A., Shumka, E., Keshri, S., Thakur, S., Cheng, T., Javaid, T., Yuan, L., Hu, Z., Liu, J., Yi, K., Chen, G. M., Chen, H. S., Chen, M., Iemmi, F., Jiang, C. H., Kapoor, A., Liao, H., Liu, Z.-A., Sharma, R., Song, J. N., Tao, J., Wang, C., Wang, J., Wang, Z., Zhang, H., Agapitos, A., Ban, Y., Levin, A., Li, C., Li, Q., Mao, Y., Qian, S. J., Sun, X., Wang, D., Yang, H., Zhang, L., Zhou, C., You, Z., Lu, N., Bauer, G., Gao, X., Leggat, D., Okawa, H., Lin, Z., Lu, C., Xiao, M., Avila, C., Trujillo, D. A. Barbosa, Cabrera, A., Florez, C., Fraga, J., Vega, J. A. Reyes, Guisao, J. Mejia, Ramirez, F., Rodriguez, M., Alvarez, J. D. Ruiz, Giljanovic, D., Godinovic, N., Lelas, D., Sculac, A., Kovac, M., Sculac, T., Bargassa, P., Brigljevic, V., Chitroda, B. K., Ferencek, D., Mishra, S., Starodumov, A., Susa, T., Attikis, A., Christoforou, K., Konstantinou, S., Mousa, J., Nicolaou, C., Ptochos, F., Razis, P. A., Rykaczewski, H., Saka, H., Stepennov, A., Finger, M., Finger, M., Kveton, A., Ayala, E., Jarrin, E. Carrera, Abdelalim, A. A., Salama, E., Mahmoud, M. A., Mohammed, Y., Ehataht, K., Kadastik, M., Lange, T., Nandan, S., Nielsen, C., Pata, J., Raidal, M., Tani, L., Veelken, C., Kirschenmann, H., Osterberg, K., Voutilainen, M., Bharthuar, S., Brücken, E., Garcia, F., Kallonen, K. T. S., Kinnunen, R., Lampén, T., Lassila-Perini, K., Lehti, S., Lindén, T., Martikainen, L., Myllymäki, M., Rantanen, M.m., Siikonen, H., Tuominen, E., Tuominiemi, J., Luukka, P., Petrow, H., Besancon, M., Couderc, F., Dejardin, M., Denegri, D., Faure, J. L., Ferri, F., Ganjour, S., Gras, P., de Monchenault, G. Hamel, Lohezic, V., Malcles, J., Rander, J., Rosowsky, A., Sahin, M. Ö., Savoy-Navarro, A., Simkina, P., Titov, M., Tornago, M., Barrera, C. Baldenegro, Beaudette, F., Perraguin, A. Buchot, Busson, P., Cappati, A., Charlot, C., Chiusi, M., Damas, F., Davignon, O., De Wit, A., Alves, B. A. Fontana Santos, Ghosh, S., Gilbert, A., de Cassagnac, R. Granier, Hakimi, A., Harikrishnan, B., Kalipoliti, L., Liu, G., Motta, J., Nguyen, M., Ochando, C., Portales, L., Salerno, R., Sauvan, J. B., Sirois, Y., Tarabini, A., Vernazza, E., Zabi, A., Zghiche, A., Agram, J.-L., Andrea, J., Apparu, D., Bloch, D., Brom, J.-M., Chabert, E. C., Collard, C., Falke, S., Goerlach, U., Grimault, C., Haeberle, R., Bihan, A.-C. Le, Meena, M., Saha, G., Sessini, M. A., Hove, P. Van, Beauceron, S., Blancon, B., Boudoul, G., Chanon, N., Choi, J., Contardo, D., Depasse, P., Dozen, C., Mamouni, H. El, Fay, J., Gascon, S., Gouzevitch, M., Greenberg, C., Grenier, G., Ille, B., Laktineh, I. B., Lethuillier, M., Mirabito, L., Perries, S., Purohit, A., Donckt, M. Vander, Verdier, P., Xiao, J., Bagaturia, I., Lomidze, I., Tsamalaidze, Z., Botta, V., Feld, L., Klein, K., Lipinski, M., Meuser, D., Pauls, A., Röwert, N., Teroerde, M., Diekmann, S., Dodonova, A., Eich, N., Eliseev, D., Engelke, F., Erdmann, J., Erdmann, M., Fackeldey, P., Fischer, B., Hebbeker, T., Hoepfner, K., Ivone, F., Jung, A., Lee, M.y., Mausolf, F., Merschmeyer, M., Meyer, A., Mukherjee, S., Noll, D., Nowotny, F., Pozdnyakov, A., Rath, Y., Redjeb, W., Rehm, F., Reithler, H., Sarkar, U., Sarkisovi, V., Schmidt, A., Sharma, A., Spah, J. L., Stein, A., Da Silva De Araujo, F. Torres, Vigilante, L., Wiedenbeck, S., Zaleski, S., Dziwok, C., Flügge, G., Ahmad, W. Haj, Kress, T., Nowack, A., Pooth, O., Stahl, A., Ziemons, T., Zotz, A., Petersen, H. Aarup, Martin, M. Aldaya, Alimena, J., Amoroso, S., An, Y., Baxter, S., Bayatmakou, M., Gonzalez, H. Becerril, Behnke, O., Belvedere, A., Bhattacharya, S., Blekman, F., Borras, K., Campbell, A., Cardini, A., Cheng, C., Colombina, F., Rodríguez, S. Consuegra, Silva, G. Correia, De Silva, M., Eckerlin, G., Eckstein, D., Banos, L. I. Estevez, Filatov, O., Gallo, E., Geiser, A., Giraldi, A., Guglielmi, V., Guthoff, M., Hinzmann, A., Jafari, A., Jeppe, L., Jomhari, N. Z., Kaech, B., Kasemann, M., Kleinwort, C., Kogler, R., Komm, M., Krücker, D., Lange, W., Pernia, D. Leyva, Lipka, K., Lohmann, W., Mankel, R., Melzer-Pellmann, I.-A., Morentin, M. Mendizabal, Meyer, A. B., Milella, G., Mussgiller, A., Nair, L. P., Nürnberg, A., Otarid, Y., Park, J., Adán, D. Pérez, Ranken, E., Raspereza, A., Lopes, B. Ribeiro, Rübenach, J., Saggio, A., Scham, M., Schnake, S., Schütze, P., Schwanenberger, C., Selivanova, D., Sharko, K., Shchedrolosiev, M., Ricardo, R. E. Sosa, Stafford, D., Vazzoler, F., Barroso, A. Ventura, Walsh, R., Wang, Q., Wen, Y., Wichmann, K., Wiens, L., Wissing, C., Yang, Y., Santos, A. Zimermmane Castro, Albrecht, A., Albrecht, S., Antonello, M., Bein, S., Benato, L., Bollweg, S., Bonanomi, M., Connor, P., Eich, M., Morabit, K. El, Fischer, Y., Garbers, C., Garutti, E., Grohsjean, A., Haller, J., Jabusch, H. R., Kasieczka, G., Keicher, P., Klanner, R., Korcari, W., Kramer, T., Kutzner, V., Labe, F., Lange, J., Lobanov, A., Matthies, C., Mehta, A., Moureaux, L., Mrowietz, M., Nigamova, A., Nissan, Y., Paasch, A., Rodriguez, K. J. Pena, Quadfasel, T., Raciti, B., Rieger, M., Savoiu, D., Schindler, J., Schleper, P., Schröder, M., Schwandt, J., Sommerhalder, M., Stadie, H., Steinbrück, G., Tews, A., Wolf, M., Brommer, S., Burkart, M., Butz, E., Chwalek, T., Dierlamm, A., Droll, A., Faltermann, N., Giffels, M., Gottmann, A., Hartmann, F., Hofsaess, R., Horzela, M., Husemann, U., Kieseler, J., Klute, M., Koppenhöfer, R., Lawhorn, J. M., Link, M., Lintuluoto, A., Maier, S., Mitra, S., Mormile, M., Müller, Th., Neukum, M., Oh, M., Presilla, M., Quast, G., Rabbertz, K., Regnery, B., Shadskiy, N., Shvetsov, I., Simonis, H. J., Toms, M., Trevisani, N., Cube, R. F. Von, Wassmer, M., Wieland, S., Wittig, F., Wolf, R., Zuo, X., Anagnostou, G., Daskalakis, G., Kyriakis, A., Papadopoulos, A., Stakia, A., Kontaxakis, P., Melachroinos, G., Panagiotou, A., Papavergou, I., Paraskevas, I., Saoulidou, N., Theofilatos, K., Tziaferi, E., Vellidis, K., Zisopoulos, I., Bakas, G., Chatzistavrou, T., Karapostoli, G., Kousouris, K., Papakrivopoulos, I., Siamarkou, E., Tsipolitis, G., Zacharopoulou, A., Adamidis, K., Bestintzanos, I., Evangelou, I., Foudas, C., Kamtsikis, C., Katsoulis, P., Kokkas, P., Kioseoglou, P. G. Kosmoglou, Manthos, N., Papadopoulos, I., Strologas, J., Bartók, M., Hajdu, C., Horvath, D., Márton, K., Sikler, F., Veszpremi, V., Csanád, M., Farkas, K., Gadallah, M. M. A., Kadlecsik, Á., Major, P., Mandal, K., Pásztor, G., Rádl, A. J., Veres, G. I., Raics, P., Ujvari, B., Zilizi, G., Bencze, G., Czellar, S., Molnar, J., Szillasi, Z., Csorgo, T., Nemes, F., Novak, T., Babbar, J., Bansal, S., Beri, S. B., Bhatnagar, V., Chaudhary, G., Chauhan, S., Dhingra, N., Kaur, A., Kaur, A., Kaur, H., Kaur, M., Kumar, S., Sandeep, K., Sheokand, T., Singh, J. B., Singla, A., Ahmed, A., Bhardwaj, A., Chhetri, A., Choudhary, B. C., Kumar, A., Kumar, A., Naimuddin, M., Ranjan, K., Saumya, S., Baradia, S., Barman, S., Bhattacharya, S., Dutta, S., Dutta, S., Sarkar, S., Ameen, M. M., Behera, P. K., Behera, S. C., Chatterjee, S., Jana, P., Kalbhor, P., Komaragiri, J. R., Kumar, D., Pujahari, P. R., Saha, N. R., Sharma, A., Sikdar, A. K., Verma, S., Dugad, S., Kumar, M., Mohanty, G. B., Suryadevara, P., Bala, A., Banerjee, S., Chatterjee, R. M., Dewanjee, R. K., Guchait, M., Jain, Sh., Jaiswal, A., Karmakar, S., Kumar, S., Majumder, G., Mazumdar, K., Parolia, S., Thachayath, A., Bahinipati, S., Kar, C., Maity, D., Mal, P., Mishra, T., Bindhu, V. K. Muraleedharan Nair, Naskar, K., Nayak, A., Sadangi, P., Saha, P., Swain, S. K., Varghese, S., Vats, D., Acharya, S., Alpana, A., Dube, S., Gomber, B., Kansal, B., Laha, A., Sahu, B., Sharma, S., Vaish, K. Y., Bakhshiansohi, H., Khazaie, E., Zeinali, M., Chenarani, S., Etesami, S. M., Khakzad, M., Najafabadi, M. Mohammadi, Grunewald, M., Abbrescia, M., Aly, R., Colaleo, A., Creanza, D., D’Anzi, B., De Filippis, N., De Palma, M., Florio, A. Di, Elmetenawee, W., Fiore, L., Iaselli, G., Louka, M., Maggi, G., Maggi, M., Margjeka, I., Mastrapasqua, V., My, S., Nuzzo, S., Pellecchia, A., Pompili, A., Pugliese, G., Radogna, R., Ramirez-Sanchez, G., Ramos, D., Ranieri, A., Silvestris, L., Simone, F. M., Sözbilir, Ü., Stamerra, A., Venditti, R., Verwilligen, P., Zaza, A., Abbiendi, G., Battilana, C., Bonacorsi, D., Borgonovi, L., Campanini, R., Capiluppi, P., Castro, A., Cavallo, F. R., Cuffiani, M., Dallavalle, G. M., Diotalevi, T., Fanfani, A., Fasanella, D., Giacomelli, P., Giommi, L., Grandi, C., Guiducci, L., Meo, S. Lo, Lunerti, L., Marcellini, S., Masetti, G., Navarria, F. L., Perrotta, A., Primavera, F., Rossi, A. M., Rovelli, T., Siroli, G. P., Costa, S., Mattia, A. Di, Potenza, R., Tricomi, A., Tuve, C., Assiouras, P., Barbagli, G., Bardelli, G., Camaiani, B., Cassese, A., Ceccarelli, R., Ciulli, V., Civinini, C., D’Alessandro, R., Focardi, E., Kello, T., Latino, G., Lenzi, P., Lizzo, M., Meschini, M., Paoletti, S., Papanastassiou, A., Sguazzoni, G., Viliani, L., Benussi, L., Bianco, S., Meola, S., Piccolo, D., Chatagnon, P., Ferro, F., Robutti, E., Tosi, S., Benaglia, A., Boldrini, G., Brivio, F., Cetorelli, F., De Guio, F., Dinardo, M. E., Dini, P., Gennai, S., Gerosa, R., Ghezzi, A., Govoni, P., Guzzi, L., Lucchini, M. T., Malberti, M., Malvezzi, S., Massironi, A., Menasce, D., Moroni, L., Paganoni, M., Pedrini, D., Pinolini, B. S., Ragazzi, S., de Fatis, T. Tabarelli, Zuolo, D., Buontempo, S., Cagnotta, A., Carnevali, F., Cavallo, N., Fabozzi, F., Iorio, A. O. M., Lista, L., Paolucci, P., Rossi, B., Sciacca, C., Ardino, R., Azzi, P., Bacchetta, N., Bisello, D., Bortignon, P., Bragagnolo, A., Checchia, P., Dorigo, T., Gasparini, U., Lusiani, E., Margoni, M., Marini, F., Meneguzzo, A. T., Migliorini, M., Passaseo, M., Pazzini, J., Ronchese, P., Rossin, R., Sgaravatto, M., Simonetto, F., Strong, G., Tosi, M., Triossi, A., Ventura, S., Yarar, H., Zanetti, M., Zotto, P., Zucchetta, A., Zumerle, G., Zeid, S. Abu, Aimè, C., Braghieri, A., Calzaferri, S., Fiorina, D., Montagna, P., Re, V., Riccardi, C., Salvini, P., Vai, I., Vitulo, P., Ajmal, S., Bilei, G. M., Ciangottini, D., Fanò, L., Magherini, M., Mantovani, G., Mariani, V., Menichelli, M., Moscatelli, F., Rossi, A., Santocchia, A., Spiga, D., Tedeschi, T., Asenov, P., Azzurri, P., Bagliesi, G., Bhattacharya, R., Bianchini, L., Boccali, T., Bossini, E., Bruschini, D., Castaldi, R., Ciocci, M. A., Cipriani, M., D’Amante, V., Dell’Orso, R., Donato, S., Giassi, A., Ligabue, F., Figueiredo, D. Matos, Messineo, A., Musich, M., Palla, F., Rizzi, A., Rolandi, G., Chowdhury, S. Roy, Sarkar, T., Scribano, A., Spagnolo, P., Tenchini, R., Tonelli, G., Turini, N., Venturi, A., Verdini, P. G., Barria, P., Basile, C., Campana, M., Cavallari, F., Mendez, L. Cunqueiro, Re, D. Del, Marco, E. Di, Diemoz, M., Errico, F., Longo, E., Meridiani, P., Mijuskovic, J., Organtini, G., Pandolfi, F., Paramatti, R., Quaranta, C., Rahatlou, S., Rovelli, C., Santanastasio, F., Soffi, L., Amapane, N., Arcidiacono, R., Argiro, S., Arneodo, M., Bartosik, N., Bellan, R., Bellora, A., Biino, C., Borca, C., Cartiglia, N., Costa, M., Covarelli, R., Demaria, N., Finco, L., Grippo, M., Kiani, B., Legger, F., Luongo, F., Mariotti, C., Markovic, L., Maselli, S., Mecca, A., Migliore, E., Monteno, M., Mulargia, R., Obertino, M. M., Ortona, G., Pacher, L., Pastrone, N., Pelliccioni, M., Ruspa, M., Siviero, F., Sola, V., Solano, A., Staiano, A., Tarricone, C., Trocino, D., Umoret, G., Vlasov, E., Belforte, S., Candelise, V., Casarsa, M., Cossutti, F., De Leo, K., Ricca, G. Della, Dogra, S., Hong, J., Huh, C., Kim, B., Kim, D. H., Kim, J., Lee, H., Lee, S. W., Moon, C. S., Oh, Y. D., Ryu, M. S., Sekmen, S., Yang, Y. C., Kim, M. S., Bak, G., Gwak, P., Kim, H., Moon, D. H., Asilar, E., Kim, D., Kim, T. J., Merlin, J. A., Choi, S., Han, S., Hong, B., Lee, K., Lee, K. S., Lee, S., Park, J., Park, S. K., Yoo, J., Goh, J., Yang, S., Kim, H. S., Kim, Y., Lee, S., Almond, J., Bhyun, J. H., Choi, J., Jun, W., Kim, J., Ko, S., Kwon, H., Lee, H., Lee, J., Lee, J., Oh, B. H., Oh, S. B., Seo, H., Yang, U. K., Yoon, I., Jang, W., Kang, D. Y., Kang, Y., Kim, S., Ko, B., Lee, J. S. H., Lee, Y., Park, I. C., Roh, Y., Watson, I. J., Ha, S., Yoo, H. D., Choi, M., Kim, M. R., Lee, H., Lee, Y., Yu, I., Beyrouthy, T., Maghrbi, Y., Dreimanis, K., Gaile, A., Pikurs, G., Potrebko, A., Seidel, M., Veckalns, V., Strautnieks, N. R., Ambrozas, M., Juodagalvis, A., Rinkevicius, A., Tamulaitis, G., Norjoharuddeen, N. Bin, Yusuff, I., Zolkapli, Z., Benitez, J. F., Hernandez, A. Castaneda, Acosta, H. A. Encinas, Maríñez, L. G. Gallegos, Coello, M. León, Quijada, J. A. Murillo, Sehrawat, A., Palomo, L. Valencia, Ayala, G., Castilla-Valdez, H., Ledesma, H. Crotte, De La Cruz-Burelo, E., La Cruz, I. Heredia-De, Lopez-Fernandez, R., Herrera, C. A. Mondragon, Hernández, A. Sánchez, Barrera, C. Oropeza, García, M. Ramírez, Bautista, I., Pedraza, I., Ibarguen, H. A. Salazar, Estrada, C. Uribe, Bubanja, I., Raicevic, N., Butler, P. H., Ahmad, A., Asghar, M. I., Awais, A., Awan, M. I. M., Hoorani, H. R., Khan, W. A., Avati, V., Grzanka, L., Malawski, M., Bialkowska, H., Bluj, M., Boimska, B., Górski, M., Kazana, M., Szleper, M., Zalewski, P., Bunkowski, K., Doroba, K., Kalinowski, A., Konecki, M., Krolikowski, J., Muhammad, A., Pozniak, K., Zabolotny, W., Araujo, M., Bastos, D., Da Cruz E Silva, C. Beirão, Boletti, A., Bozzo, M., Camporesi, T., Da Molin, G., Faccioli, P., Gallinaro, M., Hollar, J., Leonardo, N., Niknejad, T., Petrilli, A., Pisano, M., Seixas, J., Varela, J., Wulff, J. W., Adzic, P., Milenovic, P., Dordevic, M., Milosevic, J., Rekovic, V., Aguilar-Benitez, M., Maestre, J. Alcaraz, Bedoya, Cristina F., Cepeda, M., Cerrada, M., Colino, N., De La Cruz, B., Peris, A. Delgado, Valle, A. Escalante Del, Val, D. Fernández Del, Ramos, J. P. Fernández, Flix, J., Fouz, M. C., Lopez, O. Gonzalez, Lopez, S. Goy, Hernandez, J. M., Josa, M. I., Moran, D., Perez, C. M. Morcillo, Tobar, Á. Navarro, Dengra, C. Perez, Yzquierdo, A. Pérez-Calero, Pelayo, J. Puerta, Redondo, I., Ferrero, D. D. Redondo, Romero, L., Navas, S. Sánchez, Gómez, L. Urda, Escobar, J. Vazquez, Willmott, C., de Trocóniz, J. F., Gonzalez, B. Alvarez, Cuevas, J., Menendez, J. Fernandez, Folgueras, S., Caballero, I. Gonzalez, Fernández, J. R. González, Cortezon, E. Palencia, Álvarez, C. Ramón, Bouza, V. Rodríguez, Rodríguez, A. Soto, Trapote, A., Villalba, C. Vico, Vischia, P., Bhowmik, S., Fernández, S. Blanco, Cifuentes, J. A. Brochero, Cabrillo, I. J., Calderon, A., Campderros, J. Duarte, Fernandez, M., Gomez, G., García, C. Lasaosa, Rivero, C. Martinez, Arbol, P. Martinez Ruiz del, Matorras, F., Cuevas, P. Matorras, Ramos, E. Navarrete, Gomez, J. Piedra, Scodellaro, L., Vila, I., Garcia, J. M. Vizan, Jayananda, M. K., Kailasapathy, B., Sonnadara, D. U. J., Wickramarathna, D. D. C., Dharmaratna, W. G. D., Liyanage, K., Perera, N., Wickramage, N., Abbaneo, D., Amendola, C., Auffray, E., Auzinger, G., Baechler, J., Barney, D., Martínez, A. Bermúdez, Bianco, M., Bilin, B., Anuar, A. A. Bin, Bocci, A., Botta, C., Brondolin, E., Caillol, C., Cerminara, G., Chernyavskaya, N., d’Enterria, D., Dabrowski, A., David, A., De Roeck, A., Defranchis, M. M., Deile, M., Dobson, M., Forthomme, L., Franzoni, G., Funk, W., Giani, S., Gigi, D., Gill, K., Glege, F., Gouskos, L., Haranko, M., Hegeman, J., Huber, B., Innocente, V., James, T., Janot, P., Laurila, S., Lecoq, P., Leutgeb, E., Lourenço, C., Maier, B., Malgeri, L., Mannelli, M., Marini, A. 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S., Zarubin, A., Zhizhin, I., and Zhokin, A.
- Abstract
Computing demands for large scientific experiments, such as the CMS experiment at the CERN LHC, will increase dramatically in the next decades. To complement the future performance increases of software running on central processing units (CPUs), explorations of coprocessor usage in data processing hold great potential and interest. Coprocessors are a class of computer processors that supplement CPUs, often improving the execution of certain functions due to architectural design choices. We explore the approach of Services for Optimized Network Inference on Coprocessors (SONIC) and study the deployment of this as-a-service approach in large-scale data processing. In the studies, we take a data processing workflow of the CMS experiment and run the main workflow on CPUs, while offloading several machine learning (ML) inference tasks onto either remote or local coprocessors, specifically graphics processing units (GPUs). With experiments performed at Google Cloud, the Purdue Tier-2 computing center, and combinations of the two, we demonstrate the acceleration of these ML algorithms individually on coprocessors and the corresponding throughput improvement for the entire workflow. This approach can be easily generalized to different types of coprocessors and deployed on local CPUs without decreasing the throughput performance. We emphasize that the SONIC approach enables high coprocessor usage and enables the portability to run workflows on different types of coprocessors.
- Published
- 2024
- Full Text
- View/download PDF
32. The couple norm in single men’s digital stories
- Author
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Kinnunen, Anu and Pietilä, Ilkka
- Published
- 2023
- Full Text
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33. Extending 5G to Narrow Spectrum Allocations
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Hooli, Kari, Kinnunen, Pasi, Tiirola, Esa, Hakola, Sami, Kiss, Zsombor, Kaikkonen, Jorma, Baker, Matthew, and Harjula, Ilkka
- Abstract
5G New Radio (NR) has been a great success story since its introduction. It offers high reliability, low communication latency, flexibility, and efficiency that further enable 5G networks to be used for mission critical applications. Currently, there are specialized networks serving industry verticals that would benefit from the NR properties. Key use cases include communications for critical infrastructure such as railways, public safety, and smart energy and infrastructure. These networks often use dedicated spectrum allocations that are narrower than the original minimum operating bandwidth of NR. In this paper, we describe how new flexibility is being introduced into the NR design to allow operation with bandwidths between about 3 and 5 MHz. As a use case study, we focus on railway communications, and study the co-existence of the Global System for Mobile Communications–Railway (GSM-R) and Future Railway Mobile Communication System (FRMCS) based on NR during the decade-long migration period. We discuss the changes required for the NR control channels and signaling and study the effect of the changes on the system performance.
- Published
- 2023
- Full Text
- View/download PDF
34. ASVspoof 2021: Towards Spoofed and Deepfake Speech Detection in the Wild
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Liu, Xuechen, Wang, Xin, Sahidullah, Md, Patino, Jose, Delgado, Hector, Kinnunen, Tomi, Todisco, Massimiliano, Yamagishi, Junichi, Evans, Nicholas, Nautsch, Andreas, and Lee, Kong Aik
- Abstract
Benchmarking initiatives support the meaningful comparison of competing solutions to prominent problems in speech and language processing. Successive benchmarking evaluations typically reflect a progressive evolution from ideal lab conditions towards to those encountered in the wild. ASVspoof, the spoofing and deepfake detection initiative and challenge series, has followed the same trend. This article provides a summary of the ASVspoof 2021 challenge and the results of 54 participating teams that submitted to the evaluation phase. For the logical access (LA) task, results indicate that countermeasures are robust to newly introduced encoding and transmission effects. Results for the physical access (PA) task indicate the potential to detect replay attacks in real, as opposed to simulated physical spaces, but a lack of robustness to variations between simulated and real acoustic environments. The Deepfake (DF) task, new to the 2021 edition, targets solutions to the detection of manipulated, compressed speech data posted online. While detection solutions offer some resilience to compression effects, they lack generalization across different source datasets. In addition to a summary of the top-performing systems for each task, new analyses of influential data factors and results for hidden data subsets, the article includes a review of post-challenge results, an outline of the principal challenge limitations and a road-map for the future of ASVspoof.
- Published
- 2023
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35. Hybrid Inorganic–Organic Complexes of Zn, Cd, and Pb with a Cationic Phenanthro-diimine Ligand
- Author
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Temerova, Diana, Chou, Tai-Che, Kisel, Kristina S., Eskelinen, Toni, Kinnunen, Niko, Jänis, Janne, Karttunen, Antti J., Chou, Pi-Tai, and Koshevoy, Igor O.
- Abstract
The phosphonium-decorated phenanthro-imidazolyl pyridine ligand, LP+Br, readily reacts with zinc(II) and cadmium(II) bromides to give inorganic–organic zero-dimensional compounds [LP+ZnBr2]2[ZnBr4] (1) and [(LP+)2Cd2Br4][CdBr4] (2), respectively, upon crystallization. These salts are moderately fluorescent in the solid state under ambient conditions (λem= 458 nm, Φem= 0.11 for 1; λem= 460 nm, Φem= 0.13 for 2). Their emission results from spin-allowed electronic transitions localized on the organic component with the negligible effect of [MBr4]2–and MBr2units. Contrary to ionic species 1and 2, lead(II) bromide affords a neutral and water-stable complex [(LP+)2Pb3Br8] (3), showing weak room-temperature phosphorescence arising from spin–orbit coupling due to the heavy atom effect. The emission, which is substantially enhanced for the amorphous sample of 3(λem= 575 nm, Φem= 0.06), is assigned to the intraligand triplet excited state, which is a rare phenomenon among Pb(II) molecular materials.
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- 2022
- Full Text
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36. Perioperative Bleeding Requiring Blood Transfusions is Associated With Increased Risk of Stroke After Transcatheter and Surgical Aortic Valve Replacement.
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Tauriainen, Tuomas, Juvonen, Tatu, Anttila, Vesa, Maaranen, Pasi, Niemelä, Matti, Eskola, Markku, Ahvenvaara, Tuomas, Husso, Annastiina, Virtanen, Marko P.O., Kinnunen, Eeva-Maija, Dahlbacka, Sebastian, Jalava, Maina, Laine, Mika, Valtola, Antti, Raivio, Peter, Vento, Antti, Airaksinen, Juhani, Mäkikallio, Timo, and Biancari, Fausto
- Abstract
The authors aimed to investigate the impact of severe bleeding and use of red blood cell (RBC) transfusion on the development of postoperative stroke after surgical (SAVR) and transcatheter aortic valve replacement (TAVR), taken from the FinnValve registry. Nationwide, retrospective observational study. Five Finnish university hospitals participated in the registry. A total of 6,463 patients who underwent SAVR (n = 4,333) or TAVR (n = 2,130). Patients who underwent TAVR or SAVR with a bioprosthesis with or without coronary revascularization. The incidence of postoperative stroke after SAVR was 3.8%. In multivariate analysis, the number of transfused RBC units (odds ratio [OR], 1.098; 95% confidence interval [CI], 1.064-1.133) was one of the independent predictors of postoperative stroke. The incidence of stroke increased, along with the severity of perioperative bleeding, according to the European Coronary Artery Bypass Grafting (E-CABG) bleeding grades were as follows: grade 0, 2.2% (reference group); grade 1, 3.4% (adjusted OR, 1.841; 95% CI, 1.105-3.066); grade 2, 5.5% (adjusted OR, 3.282; 95% CI, 1.948-5.529); and grade 3, 14.8% (adjusted OR, 7.103; 95% CI, 3.612-13.966). The incidence of postoperative stroke after TAVR was 2.5%. The number of transfused RBC units was an independent predictor of stroke after TAVR (adjusted OR, 1.155; 95% CI, 1.058-1.261). The incidence of postoperative stroke increased, along with the severity of perioperative bleeding, as stratified by the E-CABG bleeding grades: E-CABG grade 0, 1.7%; grade 1, 5.3% (adjusted OR, 1.270; 95% CI, 0.532-3.035); grade 2, 10.0% (adjusted OR, 2.898; 95% CI, 1.101-7.627); and grade 3, 30.0% (adjusted OR, 10.706; 95% CI, 2.389-47.987). Perioperative bleeding requiring RBC transfusion and/or reoperation for intrathoracic bleeding is associated with an increased risk of postoperative stroke after SAVR and TAVR. Patient blood management and meticulous preprocedural planning and operative technique aiming to avoid significant perioperative bleeding may reduce the risk of cerebrovascular complications. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
37. Perioperative Bleeding Requiring Blood Transfusions is Associated With Increased Risk of Stroke After Transcatheter and Surgical Aortic Valve Replacement.
- Author
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Tauriainen, Tuomas, Juvonen, Tatu, Anttila, Vesa, Maaranen, Pasi, Niemelä, Matti, Eskola, Markku, Ahvenvaara, Tuomas, Husso, Annastiina, Virtanen, Marko P.O., Kinnunen, Eeva-Maija, Dahlbacka, Sebastian, Jalava, Maina, Laine, Mika, Valtola, Antti, Raivio, Peter, Vento, Antti, Airaksinen, Juhani, Mäkikallio, Timo, and Biancari, Fausto
- Abstract
The authors aimed to investigate the impact of severe bleeding and use of red blood cell (RBC) transfusion on the development of postoperative stroke after surgical (SAVR) and transcatheter aortic valve replacement (TAVR), taken from the FinnValve registry. Nationwide, retrospective observational study. Five Finnish university hospitals participated in the registry. A total of 6,463 patients who underwent SAVR (n = 4,333) or TAVR (n = 2,130). Patients who underwent TAVR or SAVR with a bioprosthesis with or without coronary revascularization. The incidence of postoperative stroke after SAVR was 3.8%. In multivariate analysis, the number of transfused RBC units (odds ratio [OR], 1.098; 95% confidence interval [CI], 1.064-1.133) was one of the independent predictors of postoperative stroke. The incidence of stroke increased, along with the severity of perioperative bleeding, according to the European Coronary Artery Bypass Grafting (E-CABG) bleeding grades were as follows: grade 0, 2.2% (reference group); grade 1, 3.4% (adjusted OR, 1.841; 95% CI, 1.105-3.066); grade 2, 5.5% (adjusted OR, 3.282; 95% CI, 1.948-5.529); and grade 3, 14.8% (adjusted OR, 7.103; 95% CI, 3.612-13.966). The incidence of postoperative stroke after TAVR was 2.5%. The number of transfused RBC units was an independent predictor of stroke after TAVR (adjusted OR, 1.155; 95% CI, 1.058-1.261). The incidence of postoperative stroke increased, along with the severity of perioperative bleeding, as stratified by the E-CABG bleeding grades: E-CABG grade 0, 1.7%; grade 1, 5.3% (adjusted OR, 1.270; 95% CI, 0.532-3.035); grade 2, 10.0% (adjusted OR, 2.898; 95% CI, 1.101-7.627); and grade 3, 30.0% (adjusted OR, 10.706; 95% CI, 2.389-47.987). Perioperative bleeding requiring RBC transfusion and/or reoperation for intrathoracic bleeding is associated with an increased risk of postoperative stroke after SAVR and TAVR. Patient blood management and meticulous preprocedural planning and operative technique aiming to avoid significant perioperative bleeding may reduce the risk of cerebrovascular complications. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
38. Effects of technology-based interventions on dietary intake or anthropometrics among adolescents and adults in South Asia – A systematic review of intervention studies.
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Char, Arundhati, Gaudel, Pramila, Kulathinal, Sangita, and Kinnunen, Tarja I.
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ONLINE information services ,FOOD consumption ,ANTHROPOMETRY ,SYSTEMATIC reviews ,MEDICAL technology ,MEDLINE - Abstract
Mobile technology has been increasingly used as part of dietary interventions, but the effects of such interventions have not been systematically evaluated in the South Asian context. The systematic review aimed to determine the effects of technology-based interventions on dietary intake or anthropometrics among adolescents and adults in South Asia. Methods: Five electronic databases were searched (PubMed, Scopus, Web of Science, Global Health Library and Health Technology Assessment). Studies published in English between 1st January 2011 and 31st December 2021were included. Interventions that evaluated the effects of dietary interventions using technology on dietary outcomes and anthropometrics in adolescents or adults in the age group of 13–44 years (or a broader age group) from South Asia were eligible for inclusion. The risk of bias was assessed using the Cochrane Risk-of-bias 2 tool and ROBINS-I tool. A narrative synthesis was conducted. Twenty-one studies met the inclusion criteria (20,667 participants). Eleven of the 17 randomised controlled trials (RCTs) had a high overall risk of bias. The four non-randomised intervention studies had a serious or critical overall risk of bias. When including studies with low risk or some concern for bias, the interventions had a beneficial effect on at least one dietary outcome in four of the six RCTs that measured changes in diet, and no effect on the anthropometric outcomes in the six RCTs that measured changes in anthropometric outcomes. Technology-based dietary interventions have had some positive effects on dietary intake, but no effects on anthropometry in South Asia. More evidence is needed as the overall risk of bias was high in a majority of the studies. • This is the first systematic review on the topic focusing on South Asia. • Most of the included studies had a high risk of bias in this systematic review. • Technology-based interventions had some beneficial effects on diet in South Asia. • The interventions had no effect on anthropometrics. • More research is needed on the effects of mHealth interventions in South Asia. [ABSTRACT FROM AUTHOR]
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- 2022
- Full Text
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39. Exploring Mechanisms of Hydration and Carbonation of MgO and Mg(OH)2 in Reactive Magnesium Oxide-Based Cements.
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Gardeh, Mina Ghane, Kistanov, Andrey A., Nguyen, Hoang, Manzano, Hegoi, Cao, Wei, and Kinnunen, Paivo
- Published
- 2022
- Full Text
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40. A NEW ENTREPRENEURIAL MOTIVATIONS PROFILE FOR STARTING NEW BUSINESS BY USING A PANEL DATA ANALYSIS.
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ANDRONICEANU, Ane-Mari, GEORGESCU, Irina, and KINNUNEN, Jani
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PANEL analysis ,NEW business enterprises ,FIXED effects model ,RANDOM effects model ,FEAR of failure - Abstract
The paper is based on research that identified and analyzed the effects of the variable context of the period 2011-2019 on the entrepreneur's businesses from 16 states. The database used in this research has been selected from the Global Entrepreneurship Monitor. The data were obtained based on surveys involving adult entrepreneurs. The aim of the research was to identify the characteristics and motivations of entrepreneurs in selected states to start new businesses. The data set includes variables that reflect the entrepreneurial intentions of individuals, their abilities, opportunities, and risks depending on gender. The research was conducted using random and fixed effects models. Within the research methodology, the final analysis model selected explains 95% (R2) of the variation of TEA (total early-stage entrepreneurial activity). The research results show a high degree of heterogeneity in the profile of entrepreneurs. Research has shown that fear of failure has positive effects on TEA. During the research, we tested the predictive power of the fixed effects model, and the results showed that it is very accurate. The results of our research contribute to shaping a well-defined profile of the entrepreneur's behavior from different states. [ABSTRACT FROM AUTHOR]
- Published
- 2022
41. Syöminen on teorian tekemistä.
- Author
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Kinnunen, Veera and Loikkanen, Teemu
- Published
- 2022
42. Implementation of a protocol to increase the academic productivity of cardiothoracic surgery resident physicians.
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Coyan, Garrett N., Sultan, Ibrahim, Seese, Laura M., Chu, Danny, Schuchert, Matthew J., Kinnunen, Angela, and Kilic, Arman
- Abstract
Academic productivity during cardiothoracic surgery residency training is an important program metric, but is highly variable due to multiple factors. This study evaluated the influence of implementing a protocol to increase resident physicians' academic productivity in cardiac surgery. A comprehensive protocol for cardiac surgery was implemented at our institution that included active pairing of residents with academically productive faculty, regular research meetings, centralized data storage and analysis with a core team of biostatisticians, a formal peer-review protocol for analytic requests, and project prioritization and feedback. We compared cardiothoracic surgery residents' academic productivity before implementation (July 2015-June 2017) versus after implementation (July 2017-June 2019). Academic productivity was measured by peer-reviewed articles, abstract presentations (oral or poster) at national cardiothoracic surgery meetings, and textbook chapters. Thirty-four resident physicians (from traditional and integrated programs) trained at our institution during the study. A total of 122 peer-reviewed articles were produced over the course of the study: 74 (60.7%) cardiac- and 48 (39.3%) thoracic-focused. The number of cardiac-focused resident-produced articles increased from 10 preimplementation to 64 postimplementation (0.61 vs 2.03 articles per resident; P <.01). Abstract oral or poster presentations also increased, from 11 to 40 (0.61 vs 1.33 abstracts per resident; P =.01). Textbook chapters increased from 4 to 15 following the intervention (0.22 vs 0.5 chapters per resident; P =.01). Implementation of a dedicated protocol to facilitate faculty mentoring of resident research and streamline the data access, analysis, and publication process substantially improved cardiothoracic surgery residents' academic productivity. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
43. Serum biochemistry suggests a physiological response to environmental stress in a native urban Eastern Gray Squirrel (Sciurus carolinensis) population.
- Author
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SCHMIDT, CHLOÉ, TREBERG, JASON R., KINNUNEN, RIIKKA P., and GARROWAY, COLIN J.
- Abstract
Urban wildlife populations experience human-driven environmental changes that can be both beneficial and detrimental to individual health. We measured body condition and serum chemistry (electrolyte levels, markers of kidney and liver function, protein, glucose, and cholesterol) in a native urban and rural population of Eastern Gray Squirrel (Sciurus carolinensis) to assess whether we could detect physiological responses to environmental stressors or dietary differences. We found no differences in body condition between habitats and no evidence of malnutrition at either site. However, urban squirrels had higher blood glucose, lower potassium, phosphorus, chloride, and albumin:globulin ratios. These results align with previous findings of increased dietary sugar in cities and suggest that urban populations of gray squirrels are under greater environmental stress than rural populations, providing future directions for studying physiological responses to urbanization. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
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44. Nanostructured and Advanced Designs from Biomass and Mineral Residues: Multifunctional Biopolymer Hydrogels and Hybrid Films Reinforced with Exfoliated Mica Nanosheets.
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Niu, He, Zhang, Kaitao, Myllymäki, Sami, Ismail, Mostafa Y., Kinnunen, Paivo, Illikainen, Mirja, and Liimatainen, Henrikki
- Published
- 2021
- Full Text
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45. Impact of changing urban typologies on residential vegetation and its climate-effects – A case study from Helsinki, Finland.
- Author
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Leppänen, Paula-Kaisa, Kinnunen, Antti, Hautamäki, Ranja, Järvi, Leena, Havu, Minttu, Junnila, Seppo, and Tahvonen, Outi
- Subjects
URBAN plants ,RESIDENTIAL mobility ,CLIMATE change adaptation ,URBAN density ,URBAN planning ,CLIMATE change mitigation ,RESIDENTIAL areas - Abstract
Residential green spaces are an integral part of urban green infrastructure and its role in climate change adaptation and mitigation. Various urban typologies and changing planning practices affect the amount and structure of residential greenery, which has a direct impact on climate benefits. While urban green and its climate benefits have received increasing attention, there is still limited knowledge on how changing planning practices and related urban typologies impact residential vegetation and its capacity to deliver climate benefits. This paper aims to address this gap by determining the impact of planning practices on residential vegetation, focussing specifically on climate mitigation and adaptation. With the case study of Helsinki, characterized by a high share of green areas, the paper first examines how construction year and urban density affect the amount and structure of vegetation on residential properties. Second, it estimates the carbon sequestration and summer temperatures in the present-day climate. The paper applies spatial modelling and regression analysis to estimate the impact of construction year on the studied dependent variables, while controlling density via gross floor area of buildings. The study demonstrates that the average amount of residential vegetation, as measured using canopy and vegetation cover, has declined 15 percentage points from the 1970 s to early 2010 s and the canopy to low vegetation ratio has decreased constantly over the periods studied. The decline of the canopy cover in particular has reduced the climate benefits of residential vegetation. The paper highlights the significant impact of gross floor area and planning practices on urban vegetation cover and the climate benefits it provides. It also stresses the importance of ensuring sufficient tree cover and permeable surfaces in cities with progressive climate mitigation agenda throughout the chain of urban planning, construction, and subsequent property management stages. [Display omitted] • Residential areas are a vital but understudied part of urban green infrastructure. • The amount of residential vegetation has diminished since the late 1970 s • The decline in canopy cover has reduced the climate benefits of residential areas. • Density and spatial patterns affect the climate benefits of residential vegetation. • Climate-wise, residential areas require sufficient vegetated and permeable surfaces. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
46. Villiinnyttämisen politiikkaa?
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Kinnunen, Veera
- Published
- 2022
47. Gold Nanoparticles on 3D-Printed Filters: From Waste to Catalysts.
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Lahtinen, Elmeri, Kukkonen, Esa, Kinnunen, Virva, Lahtinen, Manu, Kinnunen, Kimmo, Suvanto, Sari, Väisänen, Ari, and Haukka, Matti
- Published
- 2019
- Full Text
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48. The effect of mental health conditions on the use of oral anticoagulation therapy in patients with atrial fibrillation: the FinACAF study
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Jaakkola, Jussi, Teppo, Konsta, Biancari, Fausto, Halminen, Olli, Putaala, Jukka, Mustonen, Pirjo, Haukka, Jari, Linna, Miika, Kinnunen, Janne, Tiili, Paula, Aro, Aapo L, Hartikainen, Juha, Airaksinen, K E Juhani, and Lehto, Mika
- Published
- 2022
- Full Text
- View/download PDF
49. Challenging Management of Plexiform Schwannoma and Plexiform Neurofibroma
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Nicoli, Taija K., Saat, Riste, Tarkkanen, Jussi, Kinnunen, Ilpo, Mäkitie, Antti A., and Jero, Jussi
- Published
- 2022
- Full Text
- View/download PDF
50. Exploring Mechanisms of Hydration and Carbonation of MgO and Mg(OH)2in Reactive Magnesium Oxide-Based Cements
- Author
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Gardeh, Mina Ghane, Kistanov, Andrey A., Nguyen, Hoang, Manzano, Hegoi, Cao, Wei, and Kinnunen, Paivo
- Abstract
Reactive magnesium oxide (MgO)-based cement (RMC) can play a key role in carbon capture processes. However, knowledge on the driving forces that control the degree of carbonation and hydration and rate of reactions in this system remains limited. In this work, density functional theory-based simulations are used to investigate the physical nature of the reactions taking place during the fabrication of RMCs under ambient conditions. Parametric indicators such as adsorption energies, charge transfer, electron localization function, adsorption/dissociation energy barriers, and the mechanisms of interaction of H2O and CO2molecules with MgO and brucite (Mg(OH)2) clusters are considered. The following hydration and carbonation interactions relevant to RMCs are evaluated: (i) carbonation of MgO, (ii) hydration of MgO, carbonation of hydrated MgO, (iii) carbonation of Mg(OH)2, (iv) hydration of Mg(OH)2, and (v) hydration of carbonated Mg(OH)2. A comparison of the energy barriers and reaction pathways of these mechanisms shows that the carbonation of MgO is hindered by the presence of H2O molecules, while the carbonation of Mg(OH)2is hindered by the formation of initial carbonate and hydrate layers as well as presence of excessed H2O molecules. To compare these finding to bulk mineral surfaces, the interactions of the CO2and H2O molecules with the MgO(001) and Mg(OH)2(001) surfaces are studied. Therefore, this work presents deep insights into the physical nature of the reactions and the mechanisms involved in hydrated magnesium carbonates production that can be beneficial for its development.
- Published
- 2022
- Full Text
- View/download PDF
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