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The electrolyte supported cells satisfy the requirements for the application in the solid oxide fuel cell such as mechanical stability, long-term stability during operation at temperatures <1000{degree sign}C, thermal cycling and very low degradation during repeated anode reduction/oxidation cycles. Nevertheless an enhancement of the power density at T=800-850{degree sign}C should be achieved to increase the power density level towards anode supported cells. The electrolyte supported solid oxide fuel cells on dense 8YSZ or 10Sc1CeSZ tapes (50x50x0.150 mm) with screen printed nickel oxide and yttria stabilized zirconia cermet anode (NiO/YSZ) and lanthanum strontium manganite and yttria stabilized zirconia composite cathode (uLSM/YSZ) were sintered in co-firing. The long-term tests (over 1000 hours) were carried out at 850{degree sign}C at constant load of 550 mA/cm2 (H2:H2O:N2=40:5:55, fuel utilization uf=50%) for 8YSZ based MEA and 650 mA/cm2 (H2:H2O=50:50, uf=23%) for 10Sc1CeSZ based MEA. During the redox cycle the cells were unloaded and fully oxidized by air for 120-180 min. Up to 10 redox cycles were performed. The field emission scanning electron microscopy (FESEM) was used to characterize the microstructural changes that occurred after long-term and redox cycles experiments. Changes of polarization resistance of the cells during the experiments were analyzed by impedance spectroscopy.

Nickel oxide and yttria stabilised zirconia (NiO/YSZ) cermets have been prepared using a chemical co-precipitation of hydroxides. The influence of different factors on the microstructure, mechanical and electrochemical properties of the anode were investigated. The electrochemical tests were carried out on dense 8YSZ and 10Sc1CeSZ tapes (50x50x0.150 mm, Kerafol GmbH) with symmetrically screen-printed cathodes and anodes with a lateral dimension of 40x40 mm. The cells were sintered in co-firing. The anodes were characterized by impedance spectroscopy at open circuit potential and under current load at temperatures of 850-950{degree sign}C in hydrogen/steam atmosphere (H2:H2O=1:1). The electrode polarization resistance (Rp) of the spectra was identified and the influences of operating temperature (850{degree sign}C, 900{degree sign}C and 950{degree sign}C), current load and pH2O on impedance spectra of anode were discussed. The long-term stability of the cell with an anode prepared by co-precipitation was carried out over 1000 hours under current density of 430-450 mA/cm2@0.7V at temperature 850{degree sign}C.

Nickel oxide and yttria stabilised zirconia (NiO/YSZ) cermets have been prepared using a chemical co-precipitation of hydroxides. The influence of different factors on the microstructure, mechanical and electrochemical properties of the anode were investigated. The electrochemical tests were carried out on dense 8YSZ and 10Sc1CeSZ tapes (50x50x0.150 mm, Kerafol GmbH) with symmetrically screen-printed cathodes and anodes with a lateral dimension of 40x40 mm. The cells were sintered in co-firing. The anodes were characterized by impedance spectroscopy at open circuit potential and under current load at temperatures of 850-950{degree sign}C in hydrogen/steam atmosphere (H2:H2O=1:1). The electrode polarization resistance (Rp) of the spectra was identified and the influences of operating temperature (850{degree sign}C, 900{degree sign}C and 950{degree sign}C), current load and pH2O on impedance spectra of anode were discussed. The long-term stability of the cell with an anode prepared by co-precipitation was carried out over 1000 hours under current density of 430-450 mA/cm2@0.7V at temperature 850{degree sign}C.

The electrolyte supported cells satisfy the requirements for the application in the solid oxide fuel cell such as mechanical stability, long-term stability during operation at temperatures <1000{degree sign}C, thermal cycling and very low degradation during repeated anode reduction/oxidation cycles. Nevertheless an enhancement of the power density at T=800-850{degree sign}C should be achieved to increase the power density level towards anode supported cells. The electrolyte supported solid oxide fuel cells on dense 8YSZ or 10Sc1CeSZ tapes (50x50x0.150 mm) with screen printed nickel oxide and yttria stabilized zirconia cermet anode (NiO/YSZ) and lanthanum strontium manganite and yttria stabilized zirconia composite cathode (uLSM/YSZ) were sintered in co-firing. The long-term tests (over 1000 hours) were carried out at 850{degree sign}C at constant load of 550 mA/cm2 (H2:H2O:N2=40:5:55, fuel utilization uf=50%) for 8YSZ based MEA and 650 mA/cm2 (H2:H2O=50:50, uf=23%) for 10Sc1CeSZ based MEA. During the redox cycle the cells were unloaded and fully oxidized by air for 120-180 min. Up to 10 redox cycles were performed. The field emission scanning electron microscopy (FESEM) was used to characterize the microstructural changes that occurred after long-term and redox cycles experiments. Changes of polarization resistance of the cells during the experiments were analyzed by impedance spectroscopy.