32 results on '"Ghasemian, Mohammad B."'
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2. Mechanism behind the Controlled Generation of Liquid Metal Nanoparticles by Mechanical Agitation
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Nor-Azman, Nur-Adania, Ghasemian, Mohammad B., Fuchs, Richard, Liu, Li, Widjajana, Moonika S., Yu, Ruohan, Chiu, Shih-Hao, Idrus-Saidi, Shuhada A., Flores, Nieves, Chi, Yuan, Tang, Jianbo, and Kalantar-Zadeh, Kourosh
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The size-controlled synthesis of liquid metal nanoparticles is necessary in a variety of applications. Sonication is a common method for breaking down bulk liquid metals into small particles, yet the influence of critical factors such as liquid metal composition has remained elusive. Our study employs high-speed imaging to unravel the mechanism of liquid metal particle formation during mechanical agitation. Gallium-based liquid metals, with and without secondary metals of bismuth, indium, and tin, are analyzed to observe the effect of cavitation and surface eruption during sonication and particle release. The impact of the secondary metal inclusion is investigated on liquid metals’ surface tension, solution turbidity, and size distribution of the generated particles. Our work evidences that there is an inverse relationship between the surface tension and the ability of liquid metals to be broken down by sonication. We show that even for 0.22 at. % of bismuth in gallium, the surface tension is significantly decreased from 558 to 417 mN/m (measured in Milli-Q water), resulting in an enhanced particle generation rate: 3.6 times increase in turbidity and ~43% reduction in the size of particles for bismuth in gallium liquid alloy compared to liquid gallium for the same sonication duration. The effect of particles’ size on the photocatalysis of the annealed particles is also presented to show the applicability of the process in a proof-of-concept demonstration. This work contributes to a broader understanding of the synthesis of nanoparticles, with controlled size and characteristics, via mechanical agitation of liquid metals for diverse applications.
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- 2024
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3. Polarity Control of the Schottky Barrier in Wurtzite Ferroelectrics.
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Zhang, Haoze, Ayana, Alanthattil, Webster, Richard F., Ghasemian, Mohammad B., Rajendra, Bharathipura V., Seidel, Jan, and Sharma, Pankaj
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- 2024
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4. Liquid Metal Interface for Two-Precursor Autogenous Deposition of Metal Telluride–Tellurium Networks.
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Mousavi, Maedehsadat, Ghasemian, Mohammad B., Baharfar, Mahroo, Tajik, Mohammad, Chi, Yuan, Mao, Guangzhao, Kalantar-Zadeh, Kourosh, and Tang, Jianbo
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- 2023
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5. Liquid Metal Interface for Two-Precursor Autogenous Deposition of Metal Telluride–Tellurium Networks
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Mousavi, Maedehsadat, Ghasemian, Mohammad B., Baharfar, Mahroo, Tajik, Mohammad, Chi, Yuan, Mao, Guangzhao, Kalantar-Zadeh, Kourosh, and Tang, Jianbo
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Liquid metal–electrolyte can offer electrochemically reducing interfaces for the self-deposition of low-dimensional nanomaterials. We show that implementing such interfaces from multiprecursors is a promising pathway for achieving nanostructured films with combinatory properties and functionalities. Here, we explored the liquid metal-driven interfacial growth of metal tellurides using eutectic gallium–indium (EGaIn) as the liquid metal and the cation pairs Ag+-HTeO2+and Cu2+-HTeO2+as the precursors. At the EGaIn–electrolyte interface, the precursors were reduced and self-deposited autogenously to form interconnected nanoparticle networks. The deposited materials consisted of metal telluride and tellurium with their relative abundance depending on the metal ion type (Ag+and Cu2+) and the metal-to-tellurium ion ratios. When used as electrode modifiers, the synthesized materials increased the electroactive surface area of unmodified electrodes by over 10 times and demonstrated remarkable activity for model electrochemical reactions, including HexRu(III) responses and dopamine sensing. Our work reveals the promising potential of the liquid metal-templated deposition method for synthesizing complex material systems for electrochemical applications.
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- 2023
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6. Robust Switchable Polarization and Coupled Electronic Characteristics of Magnesium-Doped Zinc Oxide.
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Zhang, Haoze, Alanthattil, Ayana, Webster, Richard F., Zhang, Dawei, Ghasemian, Mohammad B., Venkataramana, Rajendra B., Seidel, Jan, and Sharma, Pankaj
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- 2023
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7. Liquid-Metal Solvents for Designing Hierarchical Nanoporous Metals at Low Temperatures.
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Chi, Yuan, Kumar, Priyank V., Zheng, Jiewei, Kong, Charlie, Yu, Ruohan, Johnston, Lucy, Ghasemian, Mohammad B., Rahim, Md. Arifur, Kumeria, Tushar, Chu, Dewei, Lu, Xunyu, Mao, Guangzhao, Kalantar-Zadeh, Kourosh, and Tang, Jianbo
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- 2023
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8. Robust Switchable Polarization and Coupled Electronic Characteristics of Magnesium-Doped Zinc Oxide
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Zhang, Haoze, Alanthattil, Ayana, Webster, Richard F., Zhang, Dawei, Ghasemian, Mohammad B., Venkataramana, Rajendra B., Seidel, Jan, and Sharma, Pankaj
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Ferroelectrics possess a spontaneous polarization that is switchable by an electric field and is critical for the development of low-energy nanoelectronics and neuromorphic applications. However, apart from a few recent developments, the realization of switchable polarization in metal oxides with simpler structures has been a major challenge. Here, we demonstrate the presence of robust switchable polarization at the level of a single nanocrystallite in magnesium-doped zinc oxide thin films with polar wurtzite crystal structures. Using a combination of high-resolution scanning probe microscopy and spectroscopic techniques, voltage control of the polarization and the coupled electronic transport behavior revealing a giant resistance change of approximately 10000% is unveiled. Time- and frequency-resolved nanoscale measurements provide key insights into the polarization phenomenon and a 9-fold increase in the effective longitudinal piezoelectric coefficient. Our work thus constitutes a crucial step toward validating nanoscale ferroelectricity in polar wurtzites for use in advanced nanoelectronics and memory applications.
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- 2023
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9. Liquid Metal-Templated Tin-Doped Tellurium Films for Flexible Asymmetric Pseudocapacitors.
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Mousavi, Maedehsadat, Mittal, Uttam, Ghasemian, Mohammad B., Baharfar, Mahroo, Tang, Jianbo, Yao, Yin, Merhebi, Salma, Zhang, Chengchen, Sharma, Neeraj, Kalantar-Zadeh, Kourosh, and Mayyas, Mohannad
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- 2022
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10. Characteristics of Epitaxial Graphene on SiC/Si Substrates in the Radio Frequency Spectrum
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Katzmarek, David A., Yang, Yang, Ghasemian, Mohammad B., Kalantar-Zadeh, Kourosh, Ziolkowski, Richard W., and Iacopi, Francesca
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Graphene is expected to bring substantial benefits for high-frequency applications, however, most of the studies in this area are based on theory. Here, the properties of epitaxial graphene grown on intrinsic silicon carbide on silicon substrates are investigated for potential radio frequency (RF) applications. Metal coplanar waveguides (CPWs) are fabricated that employ graphene as a shunt between the signal and ground planes. The CPWs are used for characterizing the frequency-dependent behavior of the sheet resistance of the graphene shunt from 10 MHz to 10 GHz. The process involves evaluating the CPW’s RLCG transmission line parameters and comparing them to a reference un-shunted CPW to extract the sheet resistance. We find that the quality of the metal contact with graphene is one key parameter to observe adequate current injection in the 2D material in the RF spectrum. A mild argon plasma treatment was applied to reach an adequate contact quality. Furthermore, we observe a monotonic decrease of the sheet resistance of the epitaxial graphene for frequencies roughly above 100 MHz. We attribute this behavior to the progressively smaller influence of small-scale discontinuities, such as grain sizes, at those higher frequencies.
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- 2023
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11. Electrical Response of Poly(N‑[3-(dimethylamino)Propyl] Methacrylamide) to CO2 at a Long Exposure Period.
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Shahrbabaki, Zahra, Oveissi, Farshad, Farajikhah, Syamak, Ghasemian, Mohammad B., Jansen-van Vuuren, Ross D., Jessop, Philip G., Yun, Jimmy, Dehghani, Fariba, and Naficy, Sina
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- 2022
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12. Insights into the Interfacial Contact and Charge Transport of Gas-Sensing Liquid Metal Marbles.
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Chi, Yuan, Han, Jialuo, Zheng, Jiewei, Yang, Jiong, Cao, Zhenbang, Ghasemian, Mohammad B., Rahim, Md. Arifur, Kalantar-Zadeh, Kourosh, Kumar, Priyank, and Tang, Jianbo
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- 2022
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13. Liquid Metal-Templated Tin-Doped Tellurium Films for Flexible Asymmetric Pseudocapacitors
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Mousavi, Maedehsadat, Mittal, Uttam, Ghasemian, Mohammad B., Baharfar, Mahroo, Tang, Jianbo, Yao, Yin, Merhebi, Salma, Zhang, Chengchen, Sharma, Neeraj, Kalantar-Zadeh, Kourosh, and Mayyas, Mohannad
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Liquid metals can be surface activated to generate a controlled galvanic potential by immersing them in aqueous solutions. This creates energized liquid–liquid interfaces that can promote interfacial chemical reactions. Here we utilize this interfacial phenomenon of liquid metals to deposit thin films of tin-doped tellurium onto rigid and flexible substrates. This is accomplished by exposing liquid metals to a precursor solution of Sn2+and HTeO2+ions. The ability to paint liquid metals onto substrates enables us to fabricate supercapacitor electrodes of liquid metal films with an intimately connected surface layer of tin-doped tellurium. The tin-doped tellurium exhibits a pseudocapacitive behavior in 1.0 M Na2SO4electrolyte and records a specific capacitance of 184.06 F·g–1(5.74 mF·cm–2) at a scan rate of 10 mV·s–1. Flexible supercapacitor electrodes are also fabricated by painting liquid metals onto polypropylene sheets and subsequently depositing tin-doped tellurium thin films. These flexible electrodes show outstanding mechanical stability even when experiencing a complete 180° bend as well as exhibit high power and energy densities of 160 W·cm–3and 31 mWh·cm–3, respectively. Overall, this study demonstrates the attractive features of liquid metals in creating energy storage devices and exemplifies their use as media for synthesizing electrochemically active materials.
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- 2022
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14. Low Temperature Nano Mechano-electrocatalytic CH4 Conversion.
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Tang, Junma, Kumar, Priyank V., Scott, Jason A., Tang, Jianbo, Ghasemian, Mohammad B., Mousavi, Maedehsadat, Han, Jialuo, Esrafilzadeh, Dorna, Khoshmanesh, Khashayar, Daeneke, Torben, O'Mullane, Anthony P., Kaner, Richard B., Rahim, Md. Arifur, and Kalantar-Zadeh, Kourosh
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- 2022
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15. Insights into the Interfacial Contact and Charge Transport of Gas-Sensing Liquid Metal Marbles
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Chi, Yuan, Han, Jialuo, Zheng, Jiewei, Yang, Jiong, Cao, Zhenbang, Ghasemian, Mohammad B., Rahim, Md. Arifur, Kalantar-Zadeh, Kourosh, Kumar, Priyank, and Tang, Jianbo
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Understanding the interfacial contacts between liquid metals and substrate materials is becoming increasingly important for the fast-rising liquid metal-enabled technologies. However, for such technologies, probing the contact behavior and interfacial charge transport has remained challenging due to the deformable nature of liquid metals and the presence of the surface oxide layer. Here, we encapsulate eutectic gallium indium (EGaIn) micro-/nanodroplets with tungsten trioxide (WO3) nanoparticles to form a WO3/EGaIn liquid metal marble network, in which the interfacial contact of the intrinsically semiconducting WO3governs the charge transport. We investigate the interfacial structures and charge transport characteristics under different contact conditions and various gaseous environments. The results suggest that establishing a WO3/EGaIn heterostructure leads to near-ohmic contact behaviors and also the emergence of localized surface plasmon resonance. Density functional theory calculations of the WO3/EGaIn interface support the experiments by revealing atomistic attractions between EGaIn alloy and the O atoms from WO3, resulting in a Fermi level shift. We also show that the efficient interfacial charge transport of the liquid metal marble network results in an enhanced gas-sensing response. This work paves the way for the possibility of studying other liquid metal/semiconductor contacts for applications in soft electronics and optics.
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- 2022
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16. High-Q Phonon-polaritons in Spatially Confined Freestanding a-MoO3.
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Jiong Yang, Jianbo Tang, Ghasemian, Mohammad B., Mayyas, Mohannad, Yu, Qiuhui V., Lu Hua Li, and Kalantar-Zadeh, Kourosh
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- 2022
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17. Liquid-Metal-Assisted Deposition and Patterning of Molybdenum Dioxide at Low Temperature.
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Wang, Yifang, Mayyas, Mohannad, Yang, Jiong, Ghasemian, Mohammad B., Tang, Jianbo, Mousavi, Maedehsadat, Han, Jialuo, Ahmed, Mostak, Baharfar, Mahroo, Mao, Guangzhao, Yao, Yin, Esrafilzadeh, Dorna, Cortie, David, and Kalantar-Zadeh, Kourosh
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- 2021
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18. Polydopamine Shell as a Ga3+ Reservoir for Triggering Gallium-Indium Phase Separation in Eutectic Gallium-Indium Nanoalloys.
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Xie, Wanjie, Allioux, Francois-Marie, Namivandi-Zangeneh, Rashin, Ghasemian, Mohammad B., Han, Jialuo, Rahim, Md. Arifur, Tang, Jianbo, Yang, Jiong, Mousavi, Maedehsadat, Mayyas, Mohannad, Cao, Zhenbang, Centurion, Franco, Christoe, Michael J., Zhang, Chengchen, Wang, Yifang, Merhebi, Salma, Baharfar, Mahroo, Ng, Gervase, Esrafilzadeh, Dorna, and Boyer, Cyrille
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- 2021
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19. Low Temperature Nano Mechano-electrocatalytic CH4Conversion
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Tang, Junma, Kumar, Priyank V., Scott, Jason A., Tang, Jianbo, Ghasemian, Mohammad B., Mousavi, Maedehsadat, Han, Jialuo, Esrafilzadeh, Dorna, Khoshmanesh, Khashayar, Daeneke, Torben, O’Mullane, Anthony P., Kaner, Richard B., Rahim, Md. Arifur, and Kalantar-Zadeh, Kourosh
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Transforming natural resources to energy sources, such as converting CH4to H2and carbon, at high efficiency and low cost is crucial for many industries and environmental sustainability. The high temperature requirement of CH4conversion regarding many of the current methods remains a critical bottleneck for their practical uptake. Here we report an approach based on gallium (Ga) liquid metal droplets, Ni(OH)2cocatalysts, and mechanical energy input that offers low-temperature and scalable CH4conversion into H2and carbon. Mainly driven by the triboelectric voltage, originating from the joint contributions of the cocatalysts during agitation, CH4is converted at the Ga and Ni(OH)2interface through nanotribo-electrochemical reaction pathways. The efficiency of the system is enhanced when the reaction is performed at an increased pressure. The dehydrogenation of other nongaseous hydrocarbons using this approach is also demonstrated. This technology presents a possible low energy route for CH4conversion without involving high temperature and harsh operating conditions.
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- 2022
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20. Nanotip Formation from Liquid Metals for Soft Electronic Junctions.
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Allioux, Francois-Marie, Han, Jialuo, Tang, Jianbo, Merhebi, Salma, Cai, Shengxiang, Tang, Junma, Abbasi, Roozbeh, Centurion, Franco, Mousavi, Maedehsadat, Zhang, Chengchen, Xie, Wanjie, Mayyas, Mohannad, Rahim, Md. Arifur, Ghasemian, Mohammad B., and Kalantar-Zadeh, Kourosh
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- 2021
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21. Applications of liquid metals in nanotechnology
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Allioux, Francois-Marie, Ghasemian, Mohammad B., Xie, Wanjie, O'Mullane, Anthony P., Daeneke, Torben, Dickey, Michael D., and Kalantar-Zadeh, Kourosh
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Post-transition liquid metals (LMs) offer new opportunities for accessing exciting dynamics for nanomaterials. As entities with free electrons and ions as well as fluidity, LM-based nanomaterials are fundamentally different from their solid counterparts. The low melting points of most post-transition metals (less than 330 °C) allow for the formation of nanodroplets from bulk metal melts under mild mechanical and chemical conditions. At the nanoscale, these liquid state nanodroplets simultaneously offer high electrical and thermal conductivities, tunable reactivities and useful physicochemical properties. They also offer specific alloying and dealloying conditions for the formation of multi-elemental liquid based nanoalloys or the synthesis of engineered solid nanomaterials. To date, while only a few nanosized LM materials have been investigated, extraordinary properties have been observed for such systems. Multi-elemental nanoalloys have shown controllable homogeneous or heterogeneous core and surface compositions with interfacial ordering at the nanoscale. The interactions and synergies of nanosized LMs with polymeric, inorganic and bio-materials have also resulted in new compounds. This review highlights recent progress and future directions for the synthesis and applications of post-transition LMs and their alloys. The review presents the unique properties of these LM nanodroplets for developing functional materials for electronics, sensors, catalysts, energy systems, and nanomedicine and biomedical applications, as well as other functional systems engineered at the nanoscale.
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- 2022
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22. Liquid-Metal-Assisted Deposition and Patterning of Molybdenum Dioxide at Low Temperature
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Wang, Yifang, Mayyas, Mohannad, Yang, Jiong, Ghasemian, Mohammad B., Tang, Jianbo, Mousavi, Maedehsadat, Han, Jialuo, Ahmed, Mostak, Baharfar, Mahroo, Mao, Guangzhao, Yao, Yin, Esrafilzadeh, Dorna, Cortie, David, and Kalantar-Zadeh, Kourosh
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Molybdenum dioxide (MoO2), considering its near-metallic conductivity and surface plasmonic properties, is a great material for electronics, energy storage devices and biosensing. Yet to this day, room-temperature synthesis of large area MoO2, which allows deposition on arbitrary substrates, has remained a challenge. Due to their reactive interfaces and specific solubility conditions, gallium-based liquid metal alloys offer unique opportunities for synthesizing materials that can meet these challenges. Herein, a substrate-independent liquid metal-based method for the room temperature deposition and patterning of MoO2is presented. By introducing a molybdate precursor to the surrounding of a eutectic gallium-indium alloy droplet, a uniform layer of hydrated molybdenum oxide (H2MoO3) is formed at the interface. This layer is then exfoliated and transferred onto a desired substrate. Utilizing the transferred H2MoO3layer, a laser-writing technique is developed which selectively transforms this H2MoO3into crystalline MoO2and produces electrically conductive MoO2patterns at room temperature. The electrical conductivity and plasmonic properties of the MoO2are analyzed and demonstrated. The presented metal oxide room-temperature deposition and patterning method can find many applications in optoelectronics, sensing, and energy industries.
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- 2021
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23. Nanotip Formation from Liquid Metals for Soft Electronic Junctions
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Allioux, Francois-Marie, Han, Jialuo, Tang, Jianbo, Merhebi, Salma, Cai, Shengxiang, Tang, Junma, Abbasi, Roozbeh, Centurion, Franco, Mousavi, Maedehsadat, Zhang, Chengchen, Xie, Wanjie, Mayyas, Mohannad, Rahim, Md. Arifur, Ghasemian, Mohammad B., and Kalantar-Zadeh, Kourosh
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Liquid metals and alloys with high-aspect-ratio nanodimensional features are highly sought-after for emerging electronic applications. However, high surface tension, water-like fluidity, and the existence of self-limiting oxides confer specific peculiarities to their characteristics. Here, we introduce a high accuracy nanometric three-dimensional pulling and stretching method to fabricate liquid-metal-based nanotips from room- or near-room-temperature gallium-based alloys. The pulling rate and step size were controlled with a resolution of up to 10 nm and yielded different nanotip morphologies and lengths as a function of the base liquid metal alloy composition and the pulling parameters. The obtained nanotips presented high aspect ratios over lengths of a few microns and apexes between 10 and 100 nm. The liquid metal alloys were found confined within nanotips with about 10 nm apexes when vertically pulled at 100 nm/s. An amorphous gallium oxide skin was shown to cover the surface of the nanotips, while the liquid core was composed of the initial liquid metal alloys. The electrical contact established at the nanotips was characterized under dynamic conditions. The liquid metal nanotips showed an Ohmic resistance when a continuous liquid metal channel was formed, and a controllable semiconductor state corresponding to a heterojunction formed at the junction between the liquid metal phase and the gallium oxide semiconductor skin. The variable threshold voltages of the heterojunction were controlled via stretching of the nanotips with a 10 nm step resolution. The liquid metal nanotips were also used for establishing soft electronic junctions. This novel method of liquid metal nanotip fabrication with Ohmic and semiconducting behaviors will lead to exciting avenues for developing electronic and sensing devices.
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- 2021
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24. Pulsing Liquid Alloys for Nanomaterials Synthesis.
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Mayyas, Mohannad, Mousavi, Maedehsadat, Ghasemian, Mohammad B., Abbasi, Roozbeh, Li, Hongzhe, Christoe, Michael J., Han, Jialuo, Wang, Yifang, Zhang, Chengchen, Rahim, Md. Arifur, Tang, Jianbo, Yang, Jiong, Esrafilzadeh, Dorna, Jalili, Rouhollah, Allioux, Francois-Marie, O'Mullane, Anthony P., and Kalantar-Zadeh, Kourosh
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- 2020
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25. Unique surface patterns emerging during solidification of liquid metal alloys
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Tang, Jianbo, Lambie, Stephanie, Meftahi, Nastaran, Christofferson, Andrew J., Yang, Jiong, Ghasemian, Mohammad B., Han, Jialuo, Allioux, Francois-Marie, Rahim, Md. Arifur, Mayyas, Mohannad, Daeneke, Torben, McConville, Chris F., Steenbergen, Krista G., Kaner, Richard B., Russo, Salvy P., Gaston, Nicola, and Kalantar-Zadeh, Kourosh
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It is well-understood that during the liquid-to-solid phase transition of alloys, elements segregate in the bulk phase with the formation of microstructures. In contrast, we show here that in a Bi–Ga alloy system, highly ordered nanopatterns emerge preferentially at the alloy surfaces during solidification. We observed a variety of transition, hybrid and crystal-defect-like patterns, in addition to lamellar and rod-like structures. Combining experiments and molecular dynamics simulations, we investigated the influence of the superficial Bi and Ga2O3layers during surface solidification and elucidated the pattern-formation mechanisms, which involve surface-catalysed heterogeneous nucleation. We further demonstrated the dynamic nature and robustness of the phenomenon under different solidification conditions and for various alloy systems. The surface patterns we observed enable high-spatial-resolution nanoscale-infrared and surface-enhanced Raman mapping, which reveal promising potential for surface- and nanoscale-based applications.
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- 2021
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26. Pulsing Liquid Alloys for Nanomaterials Synthesis
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Mayyas, Mohannad, Mousavi, Maedehsadat, Ghasemian, Mohammad B., Abbasi, Roozbeh, Li, Hongzhe, Christoe, Michael J., Han, Jialuo, Wang, Yifang, Zhang, Chengchen, Rahim, Md. Arifur, Tang, Jianbo, Yang, Jiong, Esrafilzadeh, Dorna, Jalili, Rouhollah, Allioux, Francois-Marie, O’Mullane, Anthony P., and Kalantar-Zadeh, Kourosh
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Although it remains unexplored, the direct synthesis and expulsion of metals from alloys can offer many opportunities. Here, such a phenomenon is realized electrochemically by applying a polarizing voltage signal to liquid alloys. The signal induces an abrupt interfacial perturbation at the Ga-based liquid alloy surface and results in an unrestrained discharge of minority elements, such as Sn, In, and Zn, from the liquid alloy. We show that this can occur by either changing the surface tension or inducing a reversible redox reaction at the alloys’ interface. The expelled metals exhibit nanosized and porous morphologies, and depending on the cell electrochemistry, these metals can be passivated with oxide layers or fully oxidized into distinct nanostructures. The proposed concept of metal expulsion from liquid alloys can be extended to a wide variety of molten metals for producing metallic and metallic compound nanostructures for advanced applications.
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- 2020
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27. Nucleation and Growth of Polyaniline Nanofibers onto Liquid Metal Nanoparticles
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Zhang, Chengchen, Allioux, Francois-Marie, Rahim, Md. Arifur, Han, Jialuo, Tang, Jianbo, Ghasemian, Mohammad B., Tang, Shi-Yang, Mayyas, Mohannad, Daeneke, Torben, Le-Clech, Pierre, Kaner, Richard B., Esrafilzadeh, Dorna, and Kalantar-Zadeh, Kourosh
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Liquid metals can play an essential role in the generation of electrically conductive composites for electronic devices and environmental sensing and remediation applications. Here, a method for growing a polyaniline nanofibrous network at liquid metal nanoparticle interfaces is demonstrated for generating hybrid liquid metal–polymer nanocomposites. The investigation shows that an initial functionalization step of the liquid metal nanoparticles with a polymerization enhancer is essential for providing stable and specific nucleation points for the formation of the polyaniline nanofibrous network. The acidity and mechanical agitation conditions are carefully adjusted to control the fibrous polyaniline. The embedded gallium elements form an initial seeding layer around the liquid metal nanoparticles. The novel nanocomposites offer synergistic properties for environmental sensing and molecular separation applications. This study provides a road map for the direct synthesis of long organic molecular chains at the dynamic interfaces of liquid metals.
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- 2020
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28. Bi–Sn Catalytic Foam Governed by Nanometallurgy of Liquid Metals
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Allioux, Francois-Marie, Merhebi, Salma, Ghasemian, Mohammad B., Tang, Jianbo, Merenda, Andrea, Abbasi, Roozbeh, Mayyas, Mohannad, Daeneke, Torben, O’Mullane, Anthony P., Daiyan, Rahman, Amal, Rose, and Kalantar-Zadeh, Kourosh
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Metallic foams, with intrinsic catalytic properties, are critical for heterogeneous catalysis reactions and reactor designs. Market ready catalytic foams are costly and made of multimaterial coatings with large sub-millimeter open cells providing insufficient active surface area. Here we use the principle of nanometallurgy within liquid metals to prepare nanostructured catalytic metal foams using a low-cost alloy of bismuth and tin with sub-micrometer open cells. The eutectic bismuth and tin liquid metal alloy was processed into nanoparticles and blown into a tin and bismuth nanophase separated heterostructure in aqueous media at room temperature and using an indium brazing agent. The CO2electroconversion efficiency of the catalytic foam is presented with an impressive 82% conversion efficiency toward formates at high current density of −25 mA cm–2(−1.2 V vs RHE). Nanometallurgical process applied to liquid metals will lead to exciting possibilities for expanding industrial and research accessibility of catalytic foams.
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- 2020
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29. Boundary-Induced Auxiliary Features in Scattering-Type Near-Field Fourier Transform Infrared Spectroscopy
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Yang, Jiong, Mayyas, Mohannad, Tang, Jianbo, Ghasemian, Mohammad B., Yang, Honghua, Watanabe, Kenji, Taniguchi, Takashi, Ou, Qingdong, Li, Lu Hua, Bao, Qiaoliang, and Kalantar-Zadeh, Kourosh
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Phonon-polaritons (PhPs) in layered crystals, including hexagonal boron nitride (hBN), have been investigated by combined scattering-type scanning near-field optical microscopy (s-SNOM) and Fourier transform infrared (FTIR) spectroscopy. Nevertheless, many of such s-SNOM-based FTIR spectra features remain unexplored, especially those originated from the impact of boundaries. Here we observe real-space PhP propagations in thin-layer hBN sheets either supported or suspended by s-SNOM imaging. Then with a high-power broadband IR laser source, we identify two major peaks and multiple auxiliary peaks in the near-field amplitude spectra, obtained using scattering-type near-field FTIR spectroscopy, from both supported and suspended hBN. The major PhP propagation interference peak moves toward the major in-plane phonon peak when the IR illumination moves away from the hBN edge. Specific differences between the auxiliary peaks in the near-field amplitude spectra from supported and suspended hBN sheets are investigated regarding different boundary conditions, associated with edges and substrate interfaces. The outcomes may be explored in heterostructures for advanced nanophotonic applications.
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- 2020
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30. Advances in Liquid Metal Composites: Properties, Applications, and Future Prospects
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Ghasemian, Mohammad B., Tang, Junma, Rahim, Md. Arifur, Tang, Jianbo, and Kalantar-Zadeh, Kourosh
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•Post-transition LMs provide excellent opportunities for the construction of new composites with unprecedented properties. These LM-based composites take advantage of the low melting, fluidity, thermal, and conductive conductivity of LMs.•In general, two physical and chemical approaches are used for the fabrication of LM composites. While the former method mostly applies mechanical forces for mixing and downsizing LM particles, the latter method involves rapid chemical interactions between LMs and precursors.•Functionalized LM composites can be designed for desired applications through the modification of the surface or bulk of LMs with various materials, including metal particles, MXenes, ligands, graphene, 1D, and 2D materials.•Owing to their flexibility and conductivity, high reactivity, and biocompatibility, LM-based composites hold great potential to unlock numerous opportunities in soft electronics, sensing, and biotechnology.
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- 2023
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31. Liquid-Metal Solvents for Designing Hierarchical Nanoporous Metals at Low Temperatures
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Chi, Yuan, Kumar, Priyank V., Zheng, Jiewei, Kong, Charlie, Yu, Ruohan, Johnston, Lucy, Ghasemian, Mohammad B., Rahim, Md. Arifur, Kumeria, Tushar, Chu, Dewei, Lu, Xunyu, Mao, Guangzhao, Kalantar-Zadeh, Kourosh, and Tang, Jianbo
- Abstract
Metallic nanoarchitectures hold immense value as functional materials across diverse applications. However, major challenges lie in effectively engineering their hierarchical porosity while achieving scalable fabrication at low processing temperatures. Here we present a liquid-metal solvent-based method for the nanoarchitecting and transformation of solid metals. This was achieved by reacting liquid gallium with solid metals to form crystalline entities. Nanoporous features were then created by selectively removing the less noble and comparatively softer gallium from the intermetallic crystals. By controlling the crystal growth and dealloying conditions, we realized the effective tuning of the micro-/nanoscale porosities. Proof-of-concept examples were shown by applying liquid gallium to solid copper, silver, gold, palladium, and platinum, while the strategy can be extended to a wider range of metals. This metallic-solvent-based route enables low-temperature fabrication of metallic nanoarchitectures with tailored porosity. By demonstrating large-surface-area and scalable hierarchical nanoporous metals, our work addresses the pressing demand for these materials in various sectors.
- Published
- 2023
- Full Text
- View/download PDF
32. Polydopamine Shell as a Ga3+Reservoir for Triggering Gallium–Indium Phase Separation in Eutectic Gallium–Indium Nanoalloys
- Author
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Xie, Wanjie, Allioux, Francois-Marie, Namivandi-Zangeneh, Rashin, Ghasemian, Mohammad B., Han, Jialuo, Rahim, Md. Arifur, Tang, Jianbo, Yang, Jiong, Mousavi, Maedehsadat, Mayyas, Mohannad, Cao, Zhenbang, Centurion, Franco, Christoe, Michael J., Zhang, Chengchen, Wang, Yifang, Merhebi, Salma, Baharfar, Mahroo, Ng, Gervase, Esrafilzadeh, Dorna, Boyer, Cyrille, and Kalantar-Zadeh, Kourosh
- Abstract
Low melting point eutectic systems, such as the eutectic gallium–indium (EGaIn) alloy, offer great potential in the domain of nanometallurgy; however, many of their interfacial behaviors remain to be explored. Here, a compositional change of EGaIn nanoalloys triggered by polydopamine (PDA) coating is demonstrated. Incorporating PDA on the surface of EGaIn nanoalloys renders core–shell nanostructures that accompany Ga–In phase separation within the nanoalloys. The PDA shell keeps depleting the Ga3+from the EGaIn nanoalloys when the synthesis proceeds, leading to a Ga3+-coordinated PDA coating and a smaller nanoalloy. During this process, the eutectic nanoalloys turn into non-eutectic systems that ultimately result in the solidification of In when Ga is fully depleted. The reaction of Ga3+-coordinated PDA-coated nanoalloys with nitrogen dioxide gas is presented as an example for demonstrating the functionality of such hybrid composites. The concept of phase-separating systems, with polymeric reservoirs, may lead to tailored materials and can be explored on a variety of post-transition metals.
- Published
- 2021
- Full Text
- View/download PDF
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