1. A new split-ring protoilludane-type sesquiterpenoid and prenylated aromatic compounds from Coriolopsis trogii.
- Author
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Zhai, Xin-Meng, Wang, Lu-Lu, Li, Ning, and Ren, Fu-Cai
- Abstract
One hitherto unknown protoilludane-type sesquiterpene, 8 β -hydroxyepicoterpene D (1), along with two novel prenylated aromatic compounds, namely coriolopsisins A and B (2 – 3), were isolated from the ethanol extract of Coriolopsis trogii fruit body. Their structures were determined through extensive spectroscopic data analysis and comparison of experimental and calculated electronic circular dichroism data. Compounds 2 and 3 are rare examples in which the isopentenyl group is attached to the side chain of the aromatic ring rather than directly to the aromatic ring, containing succinimide and alkynyl segments, respectively. Plausible biosynthetic pathways of compounds 2 and 3 are proposed and unique aromatic prenyltransferases may exist. [Display omitted] • One protoilludane-type sesquiterpene and two prenylated aromatic compounds were isolated from Coriolopsis trogii. • 8 β -Hydroxyepicoterpene D (1) was a novel a split-ring protoilludane-type sesquiterpenoid. • Coriolopsisins A and B (2 and 3) were rare examples containing succinimide and alkynyl segments, respectively. • The structures were established via extensive analyses of the spectroscopic data and ECD data. • Plausible biosynthetic pathways of coriolopsisins A and B (2 and 3) are proposed. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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