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We performed a multi-scale characterization of aqueous alteration of Mars analog basaltic rock from a Mauna Kea drill core using high-resolution visible and short-wave infrared (VIS-SWIR) spectral imaging, scanning electron microscopy, X‑ray diffraction, and point VIS-SWIR spectra. Several types of smectites, zeolites, and primary minerals were identified. Mineral classes were mapped in cut sections extracted from the drill core and used to represent the range of alteration products seen in field data collected over 1000 m depth (Calvin et al. 2020). Ten distinct spectral end-members identified in the cut sections were used to map the field point spectra. Trioctahedral Fe- and Mg-rich smectites were present toward the top of the zone of analysis (972 m below the surface) and increased in abundance toward the bottom of the drill core (1763 m depth). The mineralogy demonstrates a general trend of discontinuous alteration that increases in intensity with depth, with less pervasive phyllosilicate alteration at the top, several zones of different mixtures of zeolites toward the center, followed by more abundant phyllosilicates in the lowest sections. Distinctly absent are Fe-Mg phyllosilicates other than smectites, as well as carbonates, sulfates, and Al phyllosilicates such as kaolinite or illite. Furthermore, hematite was only detected in two of 24 samples. The suite of assemblages points to aqueous alteration at low-to-moderate temperatures at neutral to basic pH in low-oxygen conditions, with little evidence of extensive surface interaction, presenting a possible analog for an early Mars subsurface environment. We also present a library of VIS-SWIR spectra of the analyzed cut sections, including both spatial averages (i.e., unweighted linear mixtures) of spectral images of each cut section and single point spectra of the cut sections. This will allow for consideration of nonlinear mixing effects in point spectra of these assemblages from natural surfaces in future terrestrial or planetary work.

For the first time on Mars, the crystalline magnesium‐sulfate mineral starkeyite (MgSO4‧4H2O) was definitively identified using the CheMin X‐ray diffraction instrument at Gale crater. At the Canaima drill site, starkeyite along with amorphous MgSO4‧nH2O are among the “polyhydrated Mg‐sulfates” interpreted in orbital reflectance spectra. Mg‐sulfates are good climate indicators as they are very responsive to changes in temperature and relative humidity. We hypothesize that, through evaporation, Mg‐sulfates formed at the end of brine evolution when ion concentrations became saturated and precipitated on the surface or near sub‐surface as either epsomite or meridianiite. These minerals were subsequently dehydrated later to starkeyite and amorphous MgSO4‧nH2O in response to a drier Mars. At Canaima, starkeyite is stable and would form during the warmer Mars summers. Due to very slow kinetics at the low Mars winter temperatures, starkeyite and amorphous MgSO4‧nH2O would be resistant to recrystallize to more hydrous forms and thus likely persist year‐round. During the course of analyses, starkeyite transforms into amorphous MgSO4‧nH2O inside the rover body due to the elevated temperature and greatly reduced relative humidity compared to the martian surface at the Canaima drill site. It is possible that crystalline sulfate minerals existed in earlier samples measured by CheMin but altered inside the rover before they could be analyzed. Starkeyite is most likely prevalent in the subsurface, whereas both starkeyite and amorphous MgSO4‧nH2O are likely present on the surface as starkeyite could partially transform into amorphous MgSO4‧nH2O due to direct solar heating. For the first time on Mars, starkeyite (MgSO4‧4H2O), one of the many possible naturally occurring Mg‐sulfate minerals, has been identified using instruments that determine the mineralogy and chemistry of samples on the Curiosityrover in Gale crater. Minerals form in response to conditions they are subjected to and can be used to infer temperature, pressure, water availability, and other factors that will influence their formation. As such, their presence can be used to help define current and past climate conditions on Mars. When Mg‐sulfate minerals first precipitate from brine that is evaporating on the surface, they form more hydrous varieties. In response to drier conditions, they will recrystallize to Mg‐sulfate forms with less water in them. When Mg‐sulfate minerals are desiccated under extremely dry conditions, they will lose their crystal structure and form an amorphous phase. This occurred inside the rover body during the analysis of the Canaima sample. It is likely that earlier samples may also have contained crystalline Mg‐sulfates but altered to an amorphous phase while in the rover body before analyses could take place. Mg‐sulfate in the subsurface is likely starkeyite but could partially transform on the surface to amorphous MgSO4‧nH2O due to direct solar heating. For the first time on Mars, starkeyite (MgSO4‧4H2O) was positively identifiedStarkeyite along with amorphous MgSO4‧nH2O are the “polyhydrated Mg‐sulfates” interpreted in orbital reflectance spectraMg‐sulfate mineralogy serves as an indicator of transition to a drier climate and helps outline the climatic and depositional changes on Mars For the first time on Mars, starkeyite (MgSO4‧4H2O) was positively identified Starkeyite along with amorphous MgSO4‧nH2O are the “polyhydrated Mg‐sulfates” interpreted in orbital reflectance spectra Mg‐sulfate mineralogy serves as an indicator of transition to a drier climate and helps outline the climatic and depositional changes on Mars

As part of the Phase 2 Bagnold Dune campaign at Gale Crater, Mars, constraints on the geochemistry, mineralogy, and oxidation state of pristine and disturbed linear sand ripples were made using visible/near‐infrared spectral observations for comparison to Phase 1 spectra of the barchan dunes to the north. Spectra acquired by the ChemCam and Mastcam instruments (400–1,000 nm) at four Phase 2 locations revealed similar overall spectral trends between the two regions, but most Phase 2 sands were redder in the visible wavelengths. The majority of targets exhibited lower red/infrared ratios, higher ~530‐nm band depths, and higher red/blue ratios than Phase 1 samples, suggesting a greater proportion of redder, fine‐grained, ferric sands in Phase 2 samples. This is consistent with the slightly greater proportion of hematite in Phase 2 samples as determined from CheMin analyses of the Ogunquit sands, which may reflect contamination from the surrounding hematite‐bearing Murray formation bedrock. The Mars Science Laboratory Curiosity rover visited the southern portion of the Bagnold Dunes to look for differences in the types of sand grains that comprised the dunes and ripples. The rover's cameras and spectrometers provided information about the color of the sands, which was used to infer the composition and types of minerals. Overall, the sands in this part of the Bagnold Dunes were a bit redder than those further to the north that were studied previously. We interpreted this to mean that the southern sands contained more oxidized (rusted) iron particles. Because the rocks surrounding these dunes were known to contain a fair amount of red, iron‐rich minerals, it is probable that the sands were mixed with a small amount of broken fragments from these rocks. Bagnold Phase 2 sands exhibit higher 535‐nm band depths and red/blue ratios and lower 600‐/700‐nm ratios than Bagnold Phase 1 sandsPhase 2 sands contain a greater amount of redder, ferric materials, likely owing to minor hematite contamination from nearby bedrock

The Martian surface is cold, dry, exposed to biologically harmful radiation and apparently barren today. Nevertheless, there is clear geological evidence for warmer, wetter intervals in the past that could have supported life at or near the surface. This evidence has motivated National Aeronautics and Space Administration and European Space Agency to prioritize the search for any remains or traces of organisms from early Mars in forthcoming missions. Informed by (1) stratigraphic, mineralogical and geochemical data collected by previous and current missions, (2) Earth's fossil record, and (3) experimental studies of organic decay and preservation, we here consider whether, how, and where fossils and isotopic biosignatures could have been preserved in the depositional environments and mineralizing media thought to have been present in habitable settings on early Mars. We conclude that Noachian‐Hesperian Fe‐bearing clay‐rich fluvio‐lacustrine siliciclastic deposits, especially where enriched in silica, currently represent the most promising and best understood astropaleontological targets. Siliceous sinters would also be an excellent target, but their presence on Mars awaits confirmation. More work is needed to improve our understanding of fossil preservation in the context of other environments specific to Mars, particularly within evaporative salts and pore/fracture‐filling subsurface minerals. This paper reviews the rocks and minerals on Mars that could potentially host fossils or other signs of ancient life preserved since Mars was warmer and wetter billions of years ago. We apply recent results from the study of Earth's fossil record and fossilization processes, and from the geological exploration of Mars by rovers and orbiters, in order to select the most favoured targets for astrobiological missions to Mars. We conclude that mudstones rich in silica and iron‐bearing clays currently offer the best hope of finding fossils on Mars and should be prioritized, but that several other options warrant further research. We also recommend further experimental work on how fossilization processes operate under conditions analogous to early Mars. Noachian‐Hesperian Fe‐bearing clay‐rich fluvio‐lacustrine siliciclastic sediments are favored in the search for ancient Martian lifeThere is insufficient confidence in the nature of reported silica sinters on Mars or the possibility of preservation in the deep biosphereExperimental taphonomy approaches from paleontology should now be adapted to understand limits on preservation under Martian conditions

Mittlefehldt et al. (2018, https://doi.org/10.1002/2017JE005474) synthesize Alpha Particle X‐Ray Spectrometer chemical measurements along more than 4.5 km of Endeavour crater's rim. Their analyses clarify details of Endeavour's geologic history, including evidence for three to four distinct episodes of aqueous alteration. Fracture‐driven aqueous systems and Mn mobility are particularly important both here and at Curiosity's landing site on the opposite side of the planet. The detailed documentation of Alpha Particle X‐Ray Spectrometer data products within this paper will be a key reference for researchers who want to perform future work on questions related to Mars aqueous geochemistry, impact processes, and Martian crustal and atmospheric evolution. Mittlefehldt et al. (2018) synthesize APXS chemical measurements along Endeavour crater's rim to clarify Endeavour's geologic historyFracture driven aqueous systems and Mn mobility are important both here and at Curiosity's landing site on the opposite side of the planetThe detailed documentation of APXS data in this paper will be a key reference for future researchers

During its ascent up Mount Sharp, the Mars Science Laboratory Curiosity rover traversed the Bagnold Dune Field. We model sand modal mineralogy and grain size at four locations near the rover traverse, using orbital shortwave infrared single‐scattering albedo spectra and a Markov chain Monte Carlo implementation of Hapke's radiative transfer theory to fully constrain uncertainties and permitted solutions. These predictions, evaluated against in situ measurements at one site from the Curiosity rover, show that X‐ray diffraction‐measured mineralogy of the basaltic sands is within the 95% confidence interval of model predictions. However, predictions are relatively insensitive to grain size and are nonunique, especially when modeling the composition of minerals with solid solutions. We find an overall basaltic mineralogy and show subtle spatial variations in composition in and around the Bagnold Dunes, consistent with a mafic enrichment of sands with cumulative aeolian‐transport distance by sorting of olivine, pyroxene, and plagioclase grains. Furthermore, the large variations in Fe and Mg abundances (~20 wt %) at the Bagnold Dunes suggest that compositional variability may be enhanced by local mixing of well‐sorted sand with proximal sand sources. Our estimates demonstrate a method for orbital quantification of composition with rigorous uncertainty determination and provide key constraints for interpreting in situ measurements of compositional variability within Martian aeolian sandstones. Spectral variability in the dunes arises from spatially variable mineral composition and qualitatively correlates with local sand fluxMineral abundance estimates from orbit are within <13 wt % of in situ measurements from CheMin in average, although uncertainties are largeOrbital observations of dune field mineral variations may be explained by both aeolian sorting and mixing of multiple sand sources

The Mars Science Laboratory Curiosity rover performed coordinated measurements to examine the textures and compositions of aeolian sands in the active Bagnold dune field. The Bagnold sands are rounded to subrounded, very fine to medium sized (~45–500 μm) with ≥6 distinct grain colors. In contrast to sands examined by Curiosity in a dust‐covered, inactive bedform called Rocknest and soils at other landing sites, Bagnold sands are darker, less red, better sorted, have fewer silt‐sized or smaller grains, and show no evidence for cohesion. Nevertheless, Bagnold mineralogy and Rocknest mineralogy are similar with plagioclase, olivine, and pyroxenes in similar proportions comprising >90% of crystalline phases, along with a substantial amorphous component (35% ± 15%). Yet Bagnold and Rocknest bulk chemistry differ. Bagnold sands are Si enriched relative to other soils at Gale crater, and H2O, S, and Cl are lower relative to all previously measured Martian soils and most Gale crater rocks. Mg, Ni, Fe, and Mn are enriched in the coarse‐sieved fraction of Bagnold sands, corroborated by visible/near‐infrared spectra that suggest enrichment of olivine. Collectively, patterns in major element chemistry and volatile release data indicate two distinctive volatile reservoirs in Martian soils: (1) amorphous components in the sand‐sized fraction (represented by Bagnold) that are Si‐enriched, hydroxylated alteration products and/or H2O‐ or OH‐bearing impact or volcanic glasses and (2) amorphous components in the fine fraction (<40 μm; represented by Rocknest and other bright soils) that are Fe, S, and Cl enriched with low Si and adsorbed and structural H2O. The Bagnold dune field is an active sand field with moving dunes and sits between the landing site of the Curiosity rover and rocks of interest higher up on Mount Sharp. When passing through the dune field, we used all of Curiosity's instruments to measure the chemistry, mineralogy, and grain size of sands in the Bagnold dune field in order to figure out where they came from, how the sands are transported, and what volatile materials (like water) lie within Martian soils. We found that the Bagnold sand dunes are very well sorted; no dusty materials are found within them, in stark contrast to soils seen previously with Curiosity and with rovers at other landing sites. We found that the coarser sand grains are enriched in the volcanic minerals olivine and pyroxene, confirming a prediction from orbit that wind‐related activity seems to concentrate these phases. We also found that the dunes were much lower in water and other volatile elements like sulfur and chlorine versus all previous Mars soils. Using a combination of the rover's sieving system and chemical measurement tools, we figured out that two types of materials host water. In the first type of material, common in these sands, water is low in abundance (≤~1%), very tightly bound to the grains, and is not released until temperatures >200°C. In the second type of material, water is higher in abundance (2%) and more easily released by heating. Sieved water‐bearing fine materials may be a useful resource for human explorers. Because of ongoing aeolian activity, the Bagnold dunes consist of well‐sorted sands and lack the finer grains typical of Martian soilsDune sands are chemically distinct with elevated Si, Mg, and Ni and lower H2O, S, and Cl relative to all previously measured Martian finesTwo distinct, water‐/OH‐bearing amorphous components are identified: Fe‐, S‐, and Cl‐rich material in dust and Si‐rich material in the sands

As part of the Bagnold Dune campaign conducted by Mars Science Laboratory rover Curiosity, visible/near‐infrared reflectance spectra of dune sands were acquired using Mast Camera (Mastcam) multispectral imaging (445–1013 nm) and Chemistry and Camera (ChemCam) passive point spectroscopy (400–840 nm). By comparing spectra from pristine and rover‐disturbed ripple crests and troughs within the dune field, and through analysis of sieved grain size fractions, constraints on mineral segregation from grain sorting could be determined. In general, the dune areas exhibited low relative reflectance, a weak ~530 nm absorption band, an absorption band near 620 nm, and a spectral downturn after ~685 nm consistent with olivine‐bearing sands. The finest grain size fractions occurred within ripple troughs and in the subsurface and typically exhibited the strongest ~530 nm bands, highest relative reflectances, and weakest red/near‐infrared ratios, consistent with a combination of crystalline and amorphous ferric materials. Coarser‐grained samples were the darkest and bluest and exhibited weaker ~530 nm bands, lower relative reflectances, and stronger downturns in the near‐infrared, consistent with greater proportions of mafic minerals such as olivine and pyroxene. These grains were typically segregated along ripple crests and among the upper surfaces of grain flows in disturbed sands. Sieved dune sands exhibited progressive decreases in reflectance with increasing grain size, as observed in laboratory spectra of olivine size separates. The continuum of spectral features observed between the coarse‐ and fine‐grained dune sands suggests that mafic grains, ferric materials, and air fall dust mix in variable proportions depending on aeolian activity and grain sorting. Visible/near‐infrared spectra of Bagnold Dunes sands indicate variable mixtures of olivine and ferric materialsObserved spectral variations with grain size are consistent with laboratory spectra of olivineCoarse‐grained fractions enriched in mafic components compared to more ferric, fine fractions, likely related to aeolian/kinematic sorting

The Mastcam CCD cameras on the Mars Science Laboratory Curiosity Rover each use an 8-position filter wheel in acquiring up to 1600 × 1200 pixel images. The filter set includes a broadband near-infrared cutoff filter for RGB Bayer imaging on each camera and 12 narrow-band geology filters distributed between the two cameras, spanning the wavelength range 445–1013 nm. This wavelength region includes the relatively broad charge-transfer and crystal-field absorption bands that are most commonly due to the presence of iron-bearing minerals. To identify such spectral features, sequences of images taken with identical pointings through different filters have been calibrated to relative reflectance using pre-flight calibration coefficients and in-flight measurements of an onboard calibration target. Within the first 1000 sols of the mission, Mastcam observed a spectrally diverse set of materials displaying absorption features consistent with the presence of iron-bearing silicate, iron oxide, and iron sulfate minerals. Dust-coated surfaces as well as soils possess a strong positive reflectance slope in the visible, consistent with the presence of nanophase iron oxides, which have long been considered the dominant visible-wavelength pigmenting agent in weathered martian surface materials. Fresh surfaces, such as tailings produced by the drill tool and the interiors of rocks broken by the rover wheels, are grayer in visible wavelengths than their reddish, dust-coated surfaces but possess reflectance spectra that vary considerably between sites. To understand the mineralogical basis of observed Mastcam reflectance spectra, we focus on a subset of the multispectral data set for which additional constraints on the composition of surface materials are available from other rover instruments, with an emphasis on sample sites for which detailed mineralogy is provided by the results of CheMin X-ray diffraction analyses. We also discuss the results of coordinated observations with the ChemCam instrument, whose passive mode of operation is capable of acquiring reflectance spectra over wavelengths that considerably overlap the range spanned by the Mastcam filter set (Johnson et al. 2016). Materials that show a distinct 430 nm band in ChemCam data also are observed to have a strong near-infrared absorption band in Mastcam spectral data, consistent with the presence of a ferric sulfate mineral. Long-distance Mastcam observations targeted toward the flanks of the Gale crater central mound are in agreement with both ChemCam spectra and orbital results, and in particular exhibit the spectral features of a crystalline hematite layer identified in MRO/CRISM data. Variations observed in Mastcam multi-filter images acquired to date have shown that multispectral observations can discriminate between compositionally different materials within Gale Crater and are in qualitative agreement with mineralogies from measured samples and orbital data.

Diagenetic silica enrichment in fracture‐associated halos that crosscut lacustrine and unconformably overlying aeolian sedimentary bedrock is observed on the lower north slope of Aeolis Mons in Gale crater, Mars. The diagenetic silica enrichment is colocated with detrital silica enrichment observed in the lacustrine bedrock yet extends into a considerably younger, unconformably draping aeolian sandstone, implying that diagenetic silica enrichment postdates the detrital silica enrichment. A causal connection between the detrital and diagenetic silica enrichment implies that water was present in the subsurface of Gale crater long after deposition of the lacustrine sediments and that it mobilized detrital amorphous silica and precipitated it along fractures in the overlying bedrock. Although absolute timing is uncertain, the observed diagenesis likely represents some of the most recent groundwater activity in Gale crater and suggests that the timescale of potential habitability extended considerably beyond the time that the lacustrine sediments of Aeolis Mons were deposited. Silica‐rich diagenetic halos penetrate lacustrine and unconformably draping aeolian bedrock in Gale crater, MarsColocation of diagenetic and detrital silica suggests aqueous remobilization of detrital silicaPresence of diagenetic halos in the unconformably draping aeolian bedrock suggests late‐stage groundwater activity in Gale crater

During the first 2934 sols of the Curiosity rover's mission 33,468 passive visible/near‐infrared (NIR) reflectance spectra were taken of the surface by the mast‐mounted Chemistry and Camera (ChemCam) instrument on a range of target types. ChemCam spectra of bedrock targets from the Murray and Carolyn Shoemaker formations on Mt. Sharp were investigated using principal component analysis and various spectral parameters including the band depth at 535 nm and the slope between 840 and 750 nm. Four end‐member spectra were identified. Passive spectra were compared to Laser Induced Breakdown Spectroscopy (LIBS) data to search for correlations between spectral properties and elemental abundances. The correlation coefficient between FeOTreported by LIBS and BD535 from passive spectra was used to search for regions where iron may have been added to the bedrock through oxidation of ferrous‐bearing fluids but no correlations were found. Rocks in the Blunts Point‐Sutton Island transition that have unique spectral properties compared to surrounding rocks, that is flat NIR slopes and weak 535 nm absorptions, are associated with higher Mn and Mg in the LIBS spectra of bedrock. Additionally, calcium‐sulfate cements, previously identified by Ca and S enrichments in the LIBS spectra of bedrock, were also shown to be associated with spectral trends seen in Blunts Point. A shift toward a steeper NIR slope is seen in the Hutton interval, indicative of changing depositional conditions or increased diagenesis. The Chemistry and Camera (ChemCam) instrument on the Mars Science Laboratory Curiosity rover was built for use in “active” mode, in which a laser vaporizes a small amount of material from a targets' surface and the light emitted from the resulting plasma is used to quantify the relative amounts of various elements. ChemCam also collects “passive” spectra (without the use of the laser). These passive spectra use reflected sunlight to provide complementary mineralogical information. By looking at how passive and active spectral features relate and change, we can further our understanding of the composition of targets that the rover has encountered. Specifically, this methodology can help determine if Curiosity encountered rocks altered by fluids containing reduced iron. Comparison between passive spectral parameters and iron oxides reported by active spectroscopy identified two regions (Sutton Island to Blunts Point and Glasgow to Knockfarril Hill transitions) as areas of compositional interest and show evidence of variations in oxidation conditions. The passive spectra are also shown to be largely in agreement with data from Chemistry and Mineralogy, another instrument on Curiosity which provides mineralogical analysis of powdered samples. Principal component and spectral parameter analysis of Chemistry and Camera (ChemCam) passive spectra highlight four spectral end‐members in Mt. Sharp group rocksA decrease in the near‐infrared slope is seen in the Hutton interval, suggesting a changing depositional environment or enhanced diagenesisBedrock containing Mg‐sulfates and Ca‐sulfate cements are highlighted in a multivariate survey of ChemCam passive spectra Principal component and spectral parameter analysis of Chemistry and Camera (ChemCam) passive spectra highlight four spectral end‐members in Mt. Sharp group rocks A decrease in the near‐infrared slope is seen in the Hutton interval, suggesting a changing depositional environment or enhanced diagenesis Bedrock containing Mg‐sulfates and Ca‐sulfate cements are highlighted in a multivariate survey of ChemCam passive spectra

The Mars Science Laboratory rover, Curiosity, explored the clay mineral‐bearing Glen Torridon region for 1 Martian year between January 2019 and January 2021, including a short campaign onto the Greenheugh pediment. The Glen Torridon campaign sought to characterize the geology of the area, seek evidence of habitable environments, and document the onset of a potentially global climatic transition during the Hesperian era. Curiosityroved 5 km in total throughout Glen Torridon, from the Vera Rubin ridge to the northern margin of the Greenheugh pediment. Curiosityacquired samples from 11 drill holes during this campaign and conducted the first Martian thermochemolytic‐based organics detection experiment with the Sample Analysis at Mars instrument suite. The lowest elevations within Glen Torridon represent a continuation of lacustrine Murray formation deposits, but overlying widespread cross bedded sandstones indicate an interval of more energetic fluvial environments and prompted the definition of a new stratigraphic formation in the Mount Sharp group called the Carolyn Shoemaker formation. Glen Torridon hosts abundant phyllosilicates yet remains compositionally and mineralogically comparable to the rest of the Mount Sharp group. Glen Torridon samples have a great diversity and abundance of sulfur‐bearing organic molecules, which are consistent with the presence of ancient refractory organic matter. The Glen Torridon region experienced heterogeneous diagenesis, with the most striking alteration occurring just below the Siccar Point unconformity at the Greenheugh pediment. Results from the pediment campaign show that the capping sandstone formed within the Stimson Hesperian aeolian sand sea that experienced seasonal variations in wind direction. The Mars Science Laboratory rover, Curiosity, explored a valley called Glen Torridon on the lower slopes of a sedimentary mountain within Gale crater, Mars, between January 2019 and January 2021. The rocks within this shallow valley are part of a sequence of rock layers whose mineral composition could imply a transition from a wetter to drier environment more than 3 billion years ago. This paper reports on the exploration campaign designed to understand the local geology, document evidence of past climate change, and investigate if the ancient environments may have been amenable to biological activity. Curiosityfound that many rocks were deposited in the bottom of a lake, but also that river deposits occur frequently in this area, suggesting that the environmental conditions changed through time. Curiosityobserved evidence for multiple cycles of water interacting with the sediments that chemically changed the elemental and mineralogical compositions of the rock layers. Curiositycollected 11 drill holes over the course of the campaign and found abundant clay minerals, as predicted, as well as a wide variety of organic molecules, suggesting that the ancient environment contained many of the necessary conditions to support life. Sedimentary facies within Glen Torridon record a transition from low‐energy lacustrine mudstones to higher‐energy fluvial sandstonesGlen Torridon hosts the highest clay mineral abundances observed thus far by Mars Science Laboratory (MSL) while remaining in family with the Mount Sharp groupGlen Torridon drill samples contain the greatest diversity of organic compounds yet detected by the MSL mission Sedimentary facies within Glen Torridon record a transition from low‐energy lacustrine mudstones to higher‐energy fluvial sandstones Glen Torridon hosts the highest clay mineral abundances observed thus far by Mars Science Laboratory (MSL) while remaining in family with the Mount Sharp group Glen Torridon drill samples contain the greatest diversity of organic compounds yet detected by the MSL mission

What allows a planet to be both within a potentially habitable zone and sustain habitability over long geologic time? With the advent of exoplanetary astronomy and the ongoing discovery of terrestrial‐type planets around other stars, our own solar system becomes a key testing ground for ideas about what factors control planetary evolution. Mars provides the solar system's longest record of the interplay of the physical and chemical processes relevant to habitability on an accessible rocky planet with an atmosphere and hydrosphere. Here we review current understanding and update the timeline of key processes in early Mars history. We then draw on knowledge of exoplanets and the other solar system terrestrial planets to identify six broad questions of high importance to the development and sustaining of habitability (unprioritized): (1) Is small planetary size fatal? (2) How do magnetic fields influence atmospheric evolution? (3) To what extent does starting composition dictate subsequent evolution, including redox processes and the availability of water and organics? (4) Does early impact bombardment have a net deleterious or beneficial influence? (5) How do planetary climates respond to stellar evolution, e.g., sustaining early liquid water in spite of a faint young Sun? (6) How important are the timescales of climate forcing and their dynamical drivers? Finally, we suggest crucial types of Mars measurements (unprioritized) to address these questions: (1) in situ petrology at multiple units/sites; (2) continued quantification of volatile reservoirs and new isotopic measurements of H, C, N, O, S, Cl, and noble gases in rocks that sample multiple stratigraphic sections; (3) radiometric age dating of units in stratigraphic sections and from key volcanic and impact units; (4) higher‐resolution measurements of heat flux, subsurface structure, and magnetic field anomalies coupled with absolute age dating. Understanding the evolution of early Mars will feed forward to understanding the factors driving the divergent evolutionary paths of the Earth, Venus, and thousands of small rocky extrasolar planets yet to be discovered. As more rocky planets are found around other stars, a key question is which factors are most important to understanding whether they are habitable? Within our solar system Mars preserves the longest record of the history of terrestrial planets, even longer than Earth. Exploration of Mars' rock record provides to the ability to understand why its environment ‐‐ its habitability ‐‐ changed so profoundly, going from a watery world, to the cold, dry world of today. In this paper, we review what is known of Mars history after several decades of exploration. We then list 6 key questions for understanding terrestrial planets generally and what makes them Earth‐like, Mars‐like, Venus‐like or otherwise have different fates. We then make recommendations of measurements needed in our own solar system, on Mars, to better understand how Earth‐like worlds change over time, keeping the ability to sustain life (or not) over time. Understanding the solar system terrestrial planets is crucial for interpretation of the history and habitability of rocky exoplanetsMars' accessible geologic record extends back past 4 Ga and possibly to as long ago as 5 Myr after solar system formationMars is key for testing theories of planetary evolution and processes that sustain habitability (or not) on rocky planets with atmospheres

The Curiosityrover on the Mars Science Laboratory mission has found extensive evidence that Gale crater once hosted a habitable lacustrine environment; however, there are remaining questions about the chemistry and duration of the lake and the nature of the climate at the time. In this study, we use Mastcam multispectral data to investigate the mineralogy of the Sutton Island member of the Murray formation, a part of the basal layers of Mt. Sharp, which consists of heterolithic mudstone and sandstone that are distinct from the finely laminated mudstones that dominate much of the Murray. Sutton Island includes at least one instance of desiccation cracks, indicative of subaerial exposure, and uniquely irregular diagenetic features that may be related to local bedrock permeability. These features suggest that Sutton Island experienced a complex history of deposition and diagenesis which may be crucial for understanding changing water‐rock interactions within Gale. We find that most Mastcam bedrock spectra in this region lack the absorptions associated with hematite found throughout the Murray, and instead show deeper absorptions shifted toward longer wavelengths that are more consistent with Fe‐smectites such as nontronite. Elemental chemistry from ChemCam supports this interpretation, as SiO, MgO, Li, and the chemical index of alteration are elevated in this region. Combined with observations of bedrock sedimentology, this suggests that Sutton Island was deposited in a nearshore or low stand environment, and we hypothesize that the clay minerals were produced in this region due to sub‐aerial exposure and weathering in a semi‐arid climate. The Curiosityrover on the Mars Science Laboratory mission has found extensive evidence that Gale crater once hosted a habitable lake environment; however, there are remaining questions about the chemistry and timing of the lake and the nature of the climate at the time. In this study, we use Mastcam data to investigate the composition of the Sutton Island member of the Murray formation, which consists of mixed fine and coarse grained rocks that are distinct from the very fine‐grained rocks that dominate much of the Murray. Sutton Island includes mudcracks, indicative of surface exposure, and irregular alteration features that may be related to local bedrock differences. These features suggest that Sutton Island experienced a complex history of deposition and alteration which may be crucial for understanding changing water‐rock interactions within Gale. We find that most bedrock in this region lack features associated with hematite found throughout the Murray, and instead show features that are more consistent with clay minerals. Combined with observations of mudcracks and chemistry data, this suggests that Sutton Island was deposited in a nearshore environment, and we hypothesize that the clays were produced in this region due to surface exposure and weathering in a semi‐arid climate. Mastcam multispectral data in Sutton Island exhibit bands >900 nm consistent with Fe/Mg‐clay minerals like nontroniteSutton Island was deposited in a lowstand/nearshore environment and exposed to more subaerial weathering than the nearby MurrayThe presence of abundant clay minerals in Sutton Island significantly reduced fluid flow and alteration during later diagenesis Mastcam multispectral data in Sutton Island exhibit bands >900 nm consistent with Fe/Mg‐clay minerals like nontronite Sutton Island was deposited in a lowstand/nearshore environment and exposed to more subaerial weathering than the nearby Murray The presence of abundant clay minerals in Sutton Island significantly reduced fluid flow and alteration during later diagenesis

We have developed a refined geologic map and stratigraphy for lower Mount Sharp using coordinated analyses of new spectral, thermophysical, and morphologic orbital data products. The Mount Sharp group consists of seven relatively planar units delineated by differences in texture, mineralogy, and thermophysical properties. These units are (1–3) three spatially adjacent units in the Murray formation which contain a variety of secondary phases and are distinguishable by thermal inertia and albedo differences, (4) a phyllosilicate‐bearing unit, (5) a hematite‐capped ridge unit, (6) a unit associated with material having a strongly sloped spectral signature at visible near‐infrared wavelengths, and (7) a layered sulfate unit. The Siccar Point group consists of the Stimson formation and two additional units that unconformably overlie the Mount Sharp group. All Siccar Point group units are distinguished by higher thermal inertia values and record a period of substantial deposition and exhumation that followed the deposition and exhumation of the Mount Sharp group. Several spatially extensive silica deposits associated with veins and fractures show that late‐stage silica enrichment within lower Mount Sharp was pervasive. At least two laterally extensive hematitic deposits are present at different stratigraphic intervals, and both are geometrically conformable with lower Mount Sharp strata. The occurrence of hematite at multiple stratigraphic horizons suggests redox interfaces were widespread in space and/or in time, and future measurements by the Mars Science Laboratory Curiosity rover will provide further insights into the depositional settings of these and other mineral phases. We have developed a stratigraphy for lower Mount Sharp using analyses of new spectral, thermophysical, and morphologic orbital data productsSiccar Point group records a period of deposition and exhumation that followed the deposition and exhumation of the Mount Sharp groupLate state silica enrichment and redox interfaces within lower Mount Sharp were pervasive and widespread in space and/or in time

Relative reflectance point spectra (400–840 nm) were acquired by the Chemistry and Camera (ChemCam) instrument on the Mars Science Laboratory (MSL) rover Curiosity in passive mode (no laser) of drill tailings and broken rock fragments near the rover as it entered the lower reaches of Mt. Sharp and of landforms at distances of 2–8 km. Freshly disturbed surfaces are less subject to the spectral masking effects of dust, and revealed spectral features consistent with the presence of iron oxides and ferric sulfates. We present the first detection on Mars of a ~433 nm absorption band consistent with small abundances of ferric sulfates, corroborated by jarosite detections by the Chemistry and Mineralogy (CheMin) X-ray diffraction instrument in the Mojave, Telegraph Peak, and Confidence Hills drilled samples. Disturbed materials near the Bonanza King region also exhibited strong 433 nm bands and negative near-infrared spectral slopes consistent with jarosite. ChemCam passive spectra of the Confidence Hills and Mojave drill tailings showed features suggestive of the crystalline hematite identified by CheMin analyses. The Windjana drill sample tailings exhibited flat, low relative reflectance spectra, explained by the occurrence of magnetite detected by CheMin. Passive spectra of Bonanza King were similar, suggesting the presence of spectrally dark and neutral minerals such as magnetite. Long-distance spectra of the “Hematite Ridge” feature (3–5 km from the rover) exhibited features consistent with crystalline hematite. The Bagnold dune field north of the Hematite Ridge area exhibited low relative reflectance and near-infrared features indicative of basaltic materials (olivine, pyroxene). Light-toned layers south of Hematite Ridge lacked distinct spectral features in the 400–840 nm region, and may represent portions of nearby clay minerals and sulfates mapped with orbital near-infrared observations. The presence of ferric sulfates such as jarosite in the drill tailings suggests a relatively acidic environment, likely associated with flow of iron-bearing fluids, associated oxidation, and/or hydrothermal leaching of sedimentary rocks. Combined with other remote sensing data sets, mineralogical constraints from ChemCam passive spectra will continue to play an important role in interpreting the mineralogy and composition of materials encountered as Curiosity traverses further south within the basal layers of the Mt. Sharp complex.

Data are limited for mortality and comorbidities in patients with multiple sclerosis (MS).

The Glen Torridon (GT) region within Gale crater, Mars, occurs in contact with the southern side of Vera Rubin ridge (VRR), a well‐defined geomorphic feature that is comparatively resistant to erosion. Prior to detailed ground‐based investigation of GT, its geologic relationship with VRR was unknown. Distinct lithologic subunits within the Jura member (Murray formation), which forms the upper part of VRR, made it possible to be also identified within GT. This indicates that the strata pass across the geomorphic divide between regions. Furthermore, the cross‐bedded lower part of the overlying Knockfarril Hill member (Carolyn Shoemaker formation) also occurs within both VRR and GT. Correlation of both units demonstrates that the strata form a continuous stratigraphic succession regardless of large‐scale geomorphic expression. The lithologic change from mudstone (Jura member) to cross‐bedded sandstone (Knockfarril Hill member) heralds a significant shift in paleoenvironment from lacustrine to fluvial. The upper part of the Knockfarril Hill member consists of interbedded mudstone and sandstone that transitions to the overlying finely laminated mudstone of the Glasgow member, and a return to lacustrine deposition. In GT, the Stimson formation unconformably overlies the Glasgow member, where it demarks the southern boundary of GT. Contacts for each stratigraphic unit were defined and transferred to a high‐resolution image base to make a geologic map and cross sections perpendicular to the NE strike. Stratal dips cannot exceed 2° NW to retain the positions of stratigraphic units in the locations they are exposed throughout GT. The Mars Science Laboratory Curiosity rover explored a region called Glen Torridon (GT) that is located on the northwest side of a large sedimentary central mound (Mount Sharp) within Gale crater. This study analyzed the rocks within GT to (a) identify the sedimentary features, (b) determine if or how the sedimentary layers correlate between the Vera Rubin ridge (VRR) and GT regions, (c) interpret ancient environments, (d) generate a geologic map, and (e) discuss the relationship between topography and the exposure of sedimentary layers. Even though the VRR and GT regions are very different in present‐day geomorphology, sedimentary layers correlate across the two regions indicating that the layers belong to a continuous sedimentary succession. Cross‐bedded sandstones of the Knockfarril Hill member represent a change to fluvial from the underlying lake and lake‐margin deposits of the Jura member, which represents a major shift in depositional environment. Packages of layers have distinct characteristics, which allows their distribution to be represented on a map. A geologic cross section limits the tilt of the layers to less than two degrees. We find that caution must be taken when attempting to derive primary stratigraphy only using datasets acquired from orbital platforms. Cross‐bedded Knockfarril Hill member strata overlie mudstone of the Jura member indicating an environmental change from lake to fluvialA geologic map of Glen Torridon (GT) made using lithologically defined stratigraphic units shows that strata dip two degrees or less to the NNWStratigraphic units pass from Vera Rubin ridge into GT indicating that strata continue through a major geomorphic boundary Cross‐bedded Knockfarril Hill member strata overlie mudstone of the Jura member indicating an environmental change from lake to fluvial A geologic map of Glen Torridon (GT) made using lithologically defined stratigraphic units shows that strata dip two degrees or less to the NNW Stratigraphic units pass from Vera Rubin ridge into GT indicating that strata continue through a major geomorphic boundary

The Mars Science Laboratory Curiosity rover has explored over 400 m of vertical stratigraphy within Gale crater to date. These fluvio‐deltaic, lacustrine, and aeolian strata have been well‐documented by Curiosity's in situ and remote science instruments, including the Mast Camera (Mastcam) pair of multispectral imagers. Mastcam visible to near‐infrared spectra can broadly distinguish between iron phases and oxidation states, and in combination with chemical data from other instruments, Mastcam spectra can help constrain mineralogy, depositional origin, and diagenesis. However, no traverse‐scale analysis of Mastcam multispectral data has yet been performed. We compiled a database of Mastcam spectra from >600 multispectral observations and quantified spectral variations across Curiosity's traverse through Vera Rubin ridge (sols 0–2302). From principal component analysis and an examination of spectral parameters, we identified nine rock spectral classes and five soil spectral classes. Rock classes are dominated by spectral differences attributed to hematite and other oxides (due to variations in grain size, composition, and abundance) and are mostly confined to specific stratigraphic members. Soil classes fall along a mixing line between soil spectra dominated by fine‐grained Fe‐oxides and those dominated by olivine‐bearing sands. By comparing trends in soil versus rock spectra, we find that locally derived sediments are not significantly contributing to the spectra of soils. Rather, varying contributions of dark, mafic sands from the active Bagnold Dune field is the primary spectral characteristic of soils. These spectral classes and their trends with stratigraphy provide a basis for comparison in Curiosity's ongoing exploration of Gale crater. The Curiosity rover's Mastcam instrument is a pair of cameras that take images in visible and near‐infrared wavelengths. Mastcam spectra can distinguish between different types of iron‐bearing minerals. During Curiosity's traverse through a variety of sedimentary rock types in Gale crater, Mars, the rover has acquired more than 600 Mastcam multispectral observations, but no previous studies have analyzed the full data set. In this study, we compiled a database of Mastcam spectra from the first 2302 sols (Martian days) of Curisoity's mission and analyzed spectral trends across the traverse. We define nine classes of spectra for rocks and five classes of spectra for soils, and we observe that different classes occur in different locations. The major spectral differences are due to the mineral hematite and other iron oxides. By comparing the trends in rock spectra to nearby soils across the traverse, we find that the soils are not made of the same minerals as the local rocks, but are dominated by sands from the active Bagnold Dune field. These spectral classes and their trends will be a basis of comparison for Curiosity's ongoing exploration of Gale crater. The diversity in Mastcam multispectral data from sols 0–2302 is encapsulated by nine rock spectral classes and five soil spectral classesThe major spectral differences in Mastcam spectra across Curiosity's traverse are attributable to hematite and other Fe‐oxidesComparisons of soil versus rock spectra indicate that locally‐derived sediments are not significantly contributing to the spectra of soils The diversity in Mastcam multispectral data from sols 0–2302 is encapsulated by nine rock spectral classes and five soil spectral classes The major spectral differences in Mastcam spectra across Curiosity's traverse are attributable to hematite and other Fe‐oxides Comparisons of soil versus rock spectra indicate that locally‐derived sediments are not significantly contributing to the spectra of soils

Gale crater, the field site for NASA's Mars Science Laboratory Curiosity rover, contains a diverse and extensive record of aeolian deposition and erosion. This study focuses on a series of regularly spaced, curvilinear, and sometimes branching bedrock ridges that occur within the Glen Torridon region on the lower northwest flank of Aeolis Mons, the central mound within Gale crater. During Curiosity's exploration of Glen Torridon between sols ∼2300–3080, the rover drove through this field of ridges, providing the opportunity for in situ observation of these features. This study uses orbiter and rover data to characterize ridge morphology, spatial distribution, compositional and material properties, and association with other aeolian features in the area. Based on these observations, we find that the Glen Torridon ridges are consistent with an origin as wind‐eroded bedrock ridges, carved during the exhumation of Mount Sharp. Erosional features like the Glen Torridon ridges observed elsewhere on Mars, termed periodic bedrock ridges (PBRs), have been interpreted to form transverse to the dominant wind direction. The size and morphology of the Glen Torridon PBRs are consistent with transverse formative winds, but the orientation of nearby aeolian bedforms and bedrock erosional features raise the possibility of PBR formation by a net northeasterly wind regime. Although several formation models for the Glen Torridon PBRs are still under consideration, and questions persist about the nature of PBR‐forming paleowinds, the presence of PBRs at this site provides important constraints on the depositional and erosional history of Gale crater. Wind has played a major role in sculpting the surface of Mars. Gale crater, the field site for NASA's Mars Science Laboratory Curiosity rover since it landed there in 2012, contains a vast and varied record of deposition and erosion by the wind. This study focuses on a series of regularly spaced, generally straight bedrock ridges that occur within the clay‐bearing Glen Torridon region of Aeolis Mons (informally named Mount Sharp) in Gale crater. During Curiosity's exploration of the Glen Torridon region between sols ∼2300–3080 of the mission, the rover drove through this field of ridges, acquiring images and compositional observations along the way. This study characterizes the Glen Torridon ridges using orbiter and rover data to determine their shape, size, occurrence, and relationship to other wind‐formed features in the area. We find that the Glen Torridon ridges were carved by wind into the bedrock of Mount Sharp. Questions remain about the winds that formed these ridges, but this study provides important information about the history and environment of Gale crater and reports the first rover observations of this type of erosional feature on Mars. Decameter‐long, regularly spaced bedrock ridges oriented northeast‐southwest occur throughout the Glen Torridon region of Aeolis MonsGlen Torridon ridges cross‐cut elevation contours and bedding, exhibit bifurcations, and are disrupted by small impact cratersGlen Torridon ridges are erosional periodic bedrock ridges whose formation places erosional and depositional constraints on Aeolis Mons Decameter‐long, regularly spaced bedrock ridges oriented northeast‐southwest occur throughout the Glen Torridon region of Aeolis Mons Glen Torridon ridges cross‐cut elevation contours and bedding, exhibit bifurcations, and are disrupted by small impact craters Glen Torridon ridges are erosional periodic bedrock ridges whose formation places erosional and depositional constraints on Aeolis Mons

Introduction: The primary aim of this study was to compare the incidence of venous thromboembolism (VTE) among women initiating ospemifene vs other selective estrogen receptor modulator (SERM) therapies for estrogen-deficiency conditions or breast cancer prevention, and vs women with untreated vulvar and vaginal atrophy (VVA). The secondary objective examined numerous additional safety outcomes.Methods: This was a retrospective cohort study using the IBM Watson MarketScan claims database. Women receiving ospemifene, another SERM, or with a new diagnosis of VVA with no treatment from 1 May 2013 to 2 October 2018 were followed through the claims for incident adverse outcomes. The primary outcome was the first occurrence of VTE following cohort entry; secondary outcomes included cerebrovascular events and other adverse events potentially associated with SERM use. Cox models compared the risk of VTE between ospemifene and comparators, using a variety of approaches to control for confounding.Results: The incidence of VTE during the first continuous treatment episode was 3.39 (95% confidence interval [CI]: 1.55–6.43) events per 1,000 person-years (PY) for ospemifene (N= 8977), 11.30 (95% CI: 8.81–14.28) events per 1,000 PY for comparator SERM (N= 12,621), and 10.92 (95% CI: 10.49–11.37) events per 1,000 PY for untreated VVA (N= 242,488). Cox models indicated no increase in risk of VTE for ospemifene vs other SERMs (hazard ratio [HR]: 0.40, 95% CI: 0.19–0.82), and vs untreated VVA (HR: 0.47, 95% CI: 0.24–0.91).Conclusion: This real-world safety analysis found no increase in risk of VTE or other adverse events with use of ospemifene in postmenopausal women.Plain Language Summary Introduction:This study assessed the risk of venous thromboembolism (VTE) among women treated with ospemifene or another selective estrogen receptor modulator (SERM) therapy and women with untreated vulvar and vaginal atrophy (VVA). Numerous additional safety outcomes were examined. Methods:This study was conducted in the IBM Watson MarketScan claims database. Women receiving ospemifene, another SERM, or with a new diagnosis of VVA with no treatment from 1 May 2013 to 2 October 2018 were followed through the claims for adverse outcomes, including VTE, cerebrovascular events (such as stroke), and other outcomes that might occur with use of a SERM. The analyses compared the risk of VTE between ospemifene and the other two groups, using methods that accounted for differences in patient characteristics between the groups. Because few women over 72 years old used ospemifene, the main analyses examined women aged 54–72 years. Results:The analyses included 8,977 ospemifene users, 12,621 other SERM users, and 242,488 women with untreated VVA. Among women aged 54–72 years, only 9 experienced a VTE during ospemifene treatment, while 55 other SERM users and 1,788 women with untreated VVA had a VTE. The analyses that accounted for differences between the groups confirmed that the risk of VTE was no higher in ospemifene users than in either comparison group. Conclusion:This real-world safety analysis found no increase in risk of VTE or other adverse events with use of ospemifene in postmenopausal women.

Physical properties of terrains encountered by the Curiosity rover during the first 360 sols of operations have been inferred from analysis of the scour zones produced by Sky Crane Landing System engine plumes, wheel touch down dynamics, pits produced by Chemical Camera (ChemCam) laser shots, rover wheel traverses over rocks, the extent of sinkage into soils, and the magnitude and sign of rover‐based slippage during drives. Results have been integrated with morphologic, mineralogic, and thermophysical properties derived from orbital data, and Curiosity‐based measurements, to understand the nature and origin of physical properties of traversed terrains. The hummocky plains (HP) landing site and traverse locations consist of moderately to well‐consolidated bedrock of alluvial origin variably covered by slightly cohesive, hard‐packed basaltic sand and dust, with both embedded and surface‐strewn rock clasts. Rock clasts have been added through local bedrock weathering and impact ejecta emplacement and form a pavement‐like surface in which only small clasts (<5 to 10 cm wide) have been pressed into the soil during wheel passages. The bedded fractured (BF) unit, site of Curiosity's first drilling activity, exposes several alluvial‐lacustrine bedrock units with little to no soil cover and varying degrees of lithification. Small wheel sinkage values (<1 cm) for both HP and BF surfaces demonstrate that compaction resistance countering driven‐wheel thrust has been minimal and that rover slippage while traversing across horizontal surfaces or going uphill, and skid going downhill, have been dominated by terrain tilts and wheel‐surface material shear modulus values. Curiosity landing site consolidated bedrock covered by packed sand with clastsCuriosity drill site is alluvial‐lacustrine bedrock unit with little soil coverRover slip/skid dominated by terrain tilt and wheel‐surface material shear modulus

Background:Data on clinical outcomes of patients in the general population undergoing knee replacement or hip replacement surgery are sparse. Objectives:To conduct an observational study using insurance claims data to assess the incidence of selected clinical events following knee replacement or hip replacement surgery in the USA. Patients/Methods:A total of 97 469 knee replacement patients and a total of 45 203 hip replacement patients were included during the period 2004–2008; the median age was 64 years, and 63% of knee replacement patients and 55% of hip replacement patients were women. Results:During a median follow‐up of 70–71 days, the incidence rates in knee replacement patients and hip replacement patients were, respectively: ischemic stroke, 15 and 19 per 1000 person‐years; acute coronary syndrome (ACS), 15 and 18 per 1000 person‐years; bleeding events, 46 and 47 per 1000 person‐years; venous thromboembolism (VTE), 64 and 45 per 1000 person‐years; and hepatic events, one and one per 1000 person‐years. Approximately 45% of knee replacement and hip replacement patients had no claims for outpatient anticoagulant therapy within 1 week after discharge from hospital. Conclusions:Ischemic events such as stroke, ACS and VTE are important adverse events following knee replacement and hip replacement surgery. The results reported here can help in making challenging decisions regarding the clinical management of risks attributable to bleeding events and clotting events.

This study examines the resource use patterns and costs of care for patients with incident metastatic colorectal cancer (mCRC) based on analyses of retrospective claims data from selected health plans in the United States.

OBJECTIVE: To compare the prevalence of cardiovascular diseases and their risk factors between patients with rheumatoid arthritis (RA), psoriatic arthritis (PsA), and ankylosing spondylitis (AS) and control subjects. METHODS: Data for patients continuously enrolled in an integrated outcomes database between January 1, 2001, and December 31, 2002, with International Classification of Diseases, 9th Revision codes of 714.× (RA), 696.0 (PsA), or 720.0 (AS) were evaluated in this cross-sectional comparative study. Control groups were established for each patient group (1:4 ratio) by matching on the basis of age, sex, geographic region, and length of time in plan. Age- and sex-adjusted prevalence of cardiovascular comorbidities and risk factors were calculated; the prevalence ratio of the comorbidities and risk factors for the patient groups compared with the control population were estimated. Use of selected cardiovascular medications was also compared between patient and control groups. RESULTS: The RA, PsA, and AS cohorts comprised 28,208, 3066, and 1843 patients, respectively. The prevalence ratio of ischemic heart disease (1.5, 1.3, 1.2), atherosclerosis (1.9, 1.4, 1.5), peripheral vascular disease (2.4, 1.6, 1.6), congestive heart failure (2.0, 1.5, 1.8), cerebrovascular disease (1.6, 1.3, 1.7), type II diabetes (1.4, 1.5, 1.2), hyperlipidemia (1.2, 1.2, 1.2), and hypertension (1.3, 1.3, 1.3) were higher in patients than controls. For RA, PsA, and AS, use of angiotensin-converting enzyme inhibitors, calcium channel blockers, diuretics, nitrates/vasodilators, anticoagulants, and antihyperlipidemia agents was significantly higher in patients than controls. CONCLUSION: Cardiovascular diseases and their risk factors were more common in patients with RA, PsA, and AS than in matched controls.

Fine‐scale (submillimeter to centimeter) depositional and diagenetic features encountered during the Curiosityrover's traverse in Gale crater provide a means to understand the geologic history of Vera Rubin ridge (VRR). VRR is a topographically high feature on the lower north slope of Aeolis Mons, a 5‐km high stratified mound within Gale crater. We use high‐spatial resolution images from the Mars Hand Lens Imager (MAHLI) as well as grain sizes estimated with the Gini index mean score technique that uses ChemCam Laser‐Induced Breakdown Spectroscopy (LIBS) chemical data to constrain the postdepositional history of the strata exposed on this ridge. MAHLI images were used to examine the color, grain size, and style of lamination of the host rocks, as well as to explore the occurrence of nodules, diagenetic crystals, pits, and a variety of dark‐gray iron‐rich features. This survey revealed abundant and widespread diagenetic features within the rocks exposed on VRR and demonstrated that rock targets estimated to be coarser generally contain more diagenetic features than those estimated to have finer grains, which indicate that grain size may have influenced the degree and type of diagenesis. A subset of rocks within VRR are gray in color and exhibit the highest proportion of diagenetic features. We suggest that these targets experienced a different diagenetic history than the other rocks on VRR and hypothesize that redistribution and recrystallization of iron within specific intervals may have resulted in both the gray color and the abundance of dark‐gray iron‐rich diagenetic features. We use high resolution images to identify submillimeter‐to‐centimeter scale features that resulted from either primary deposition or alteration of the rocks after the sediment was deposited at Vera Rubin ridge (VRR). VRR is located on the flank of Aeolis Mons, the 5‐km high mound that occupies the center of Gale crater on Mars. We find that the majority of these fine‐scale features were created after the initial deposition of sediment, when water existed in the subsurface and interacted with and altered the rocks. A subset of these features is dark gray in color and have iron‐rich compositions that suggest iron remobilization and recrystallization within the host rock. We find that rocks with larger grain sizes also show more postdepositional alteration features, suggesting that grain size influenced where water moved and interacted with rocks in the subsurface. We investigate depositional and diagenetic features on Vera Rubin ridge using high‐spatial resolution imagesObservations of submillimeter‐to‐centimeter scale features indicate extensive diagenesis occurred in this areaSubtle deviations in grain size likely contributed to the distribution and variability of diagenesis We investigate depositional and diagenetic features on Vera Rubin ridge using high‐spatial resolution images Observations of submillimeter‐to‐centimeter scale features indicate extensive diagenesis occurred in this area Subtle deviations in grain size likely contributed to the distribution and variability of diagenesis

We have developed a simple direct execution architecture for a 32 bit Forth microprocessor. The processor can directly access a linear address space of over 4 gigawords. Two instruction types are defined; a subroutine call, and a user defined microcode instruction. On-chip stack caches allow most Forth primitives to execute in a single cycle.

This paper provides an overview of the Curiosityrover's exploration at Vera Rubin ridge (VRR) and summarizes the science results. VRR is a distinct geomorphic feature on lower Aeolis Mons (informally known as Mount Sharp) that was identified in orbital data based on its distinct texture, topographic expression, and association with a hematite spectral signature. Curiosityconducted extensive remote sensing observations, acquired data on dozens of contact science targets, and drilled three outcrop samples from the ridge, as well as one outcrop sample immediately below the ridge. Our observations indicate that strata composing VRR were deposited in a predominantly lacustrine setting and are part of the Murray formation. The rocks within the ridge are chemically in family with underlying Murray formation strata. Red hematite is dispersed throughout much of the VRR bedrock, and this is the source of the orbital spectral detection. Gray hematite is also present in isolated, gray‐colored patches concentrated toward the upper elevations of VRR, and these gray patches also contain small, dark Fe‐rich nodules. We propose that VRR formed when diagenetic event(s) preferentially hardened rocks, which were subsequently eroded into a ridge by wind. Diagenesis also led to enhanced crystallization and/or cementation that deepened the ferric‐related spectral absorptions on the ridge, which helped make them readily distinguishable from orbit. Results add to existing evidence of protracted aqueous environments at Gale crater and give new insight into how diagenesis shaped Mars' rock record. Vera Rubin ridge is a feature at the base of Mount Sharp with a distinct texture and topography. Orbiter observations showed hematite, a mineral that sometimes forms by chemical reactions in water environments, was present atop the ridge. The presence of both water and chemical activity suggested the area preserved a past habitable environment. In this paper, we detail how the Curiosityscience team tested this and other orbital‐based hypotheses. Curiositydata suggested that most ridge rocks were lain down in an ancient lake and had similar compositions to other Mount Sharp rocks. Curiosityconfirmed that hematite was present in the ridge but no more abundantly than elsewhere. Larger grain size or higher crystallinity probably account for the ridge's hematite being more visible from orbit. We conclude Vera Rubin ridge formed because groundwater recrystallized and hardened the rocks that now make up the ridge. Wind subsequently sculpted and eroded Mount Sharp, leaving the harder ridge rocks standing because they resisted erosion compared with surrounding rocks. The implication of these results is that liquid water was present at Mount Sharp for a very long time, not only when the crater held a lake but also much later, likely as groundwater. We summarize Curiosity's campaign at Vera Rubin ridge (Sols 1726–2302) and the high‐level results from articles in this special issueVera Rubin ridge formed when diagenesis hardened rocks along the base of Aeolis Mons; wind subsequently etched the feature into a ridgeResults add evidence for protracted aqueous environments at Gale crater and give new insight into how diagenesis shaped Mars' rock record

The Curiosityrover investigated a topographic structure known as Vera Rubin ridge, associated with a hematite signature in orbital spectra. There, Curiosityencountered mudstones interpreted as lacustrine deposits, conformably overlying the 300 m‐thick underlying sedimentary rocks of the Murray formation at the base of Mount Sharp. While the presence of hematite (α‐Fe2O3) was confirmed in situ by both Mastcam and ChemCam spectral observations and by the CheMin instrument, neither ChemCam nor APXS observed any significant increase in FeOT(total iron oxide) abundances compared to the rest of the Murray formation. Instead, Curiositydiscovered dark‐toned diagenetic features displaying anomalously high FeOTabundances, commonly observed in association with light‐toned Ca‐sulfate veins but also as crystal pseudomorphs in the host rock. These iron‐rich diagenetic features are predominantly observed in “gray” outcrops on the upper part of the ridge, which lack the telltale ferric signature of other Vera Rubin ridge outcrops. Their composition is consistent with anhydrous Fe‐oxide, as the enrichment in iron is not associated with enrichment in any other elements, nor with detections of volatiles. The lack of ferric absorption features in the ChemCam reflectance spectra and the hexagonal crystalline structure associated with dark‐toned crystals points toward coarse “gray” hematite. In addition, the host rock adjacent to these features appears bleached and shows low‐FeOTcontent as well as depletion in Mn, indicating mobilization of these redox‐sensitive elements during diagenesis. Thus, groundwater fluid circulations could account for the remobilization of iron and recrystallization as crystalline hematite during diagenesis on Vera Rubin ridge. The NASA rover Curiosityinvestigated Vera Rubin ridge, a specific landform within the Gale crater on Mars. Scientific missions in orbit around the planet had previously discovered high concentrations of hematite on top of the ridge, an iron‐oxide mineral that commonly forms in water. However, it was not clear from orbit if such conditions existed at the time of the deposition of the sediments (around 3.5 billion years ago) or occurred much later during “diagenesis,” after deposition of the sediments and up to their transformation into rocks. On the surface, the rover did not observe significant differences between the ridge and the terrains encountered before it, except for small, dark geologic features that formed during diagenesis. Their analysis by the ChemCam instrument revealed that these features are composed of hematite—the same iron‐oxide mineral that was observed from orbit—and, interestingly, that the iron required to form them was removed from the adjacent rocks by groundwaters. As such, it appears that groundwaters played an important role in shaping Vera Rubin ridge, and thus partially obscure interpretations on the environmental conditions that existed on the surface of Mars at the time of sedimentation. Images from the Curiosityrover show the presence of dark‐toned diagenetic features at Vera Rubin ridgeChemCam analyses of these features point toward an Fe‐oxide composition, consistent with crystalline hematiteDepletion of Fe and Mn in bleached halos around the Fe‐oxide features indicates mobility of Fe and Mn during the later stages of diagenesis

During 2018 and 2019, the Mars Science Laboratory Curiosityrover investigated the chemistry, morphology, and stratigraphy of Vera Rubin ridge (VRR). Using orbital data from the Compact Reconnaissance Imaging Spectrometer for Mars, scientists attributed the strong 860 nm signal associated with VRR to the presence of red crystalline hematite. However, Mastcam multispectral data and CheMin X‐ray diffraction (XRD) measurements show that the depth of the 860 nm absorption is negatively correlated with the abundance of red crystalline hematite, suggesting that other mineralogical or physical parameters are also controlling the 860 nm absorption. Here, we examine Mastcam and ChemCam passive reflectance spectra from VRR and other locations to link the depth, position, and presence or absence of iron‐related mineralogic absorption features to the XRD‐derived rock mineralogy. Correlating CheMin mineralogy to spectral parameters showed that the ~860 nm absorption has a strong positive correlation with the abundance of ferric phyllosilicates. New laboratory reflectance measurements of powdered mineral mixtures can reproduce trends found in Gale crater. We hypothesize that variations in the 860 nm absorption feature in Mastcam and ChemCam observations of VRR materials are a result of three factors: (1) variations in ferric phyllosilicate abundance due to its ~800–1,000 nm absorption; (2) variations in clinopyroxene abundance because of its band maximum at ~860 nm; and (3) the presence of red crystalline hematite because of its absorption centered at 860 nm. We also show that relatively small changes in Ca‐sulfate abundance is one potential cause of the erosional resistance and geomorphic expression of VRR. Results from near‐infrared spectral measurements showed that Vera Rubin ridge (VRR) in Gale crater, Mars, has a unique spectral signature compared to the surrounding Mt. Sharp units, which was confirmed using instruments onboard the Curiosityrover. This paper describes the spectral, compositional, and physical properties of eight rocks that were drilled and analyzed by the Curiosityrover, including three rocks that are on VRR. Quantitative mineralogy, determined using the CheMin instrument, found that all eight rocks had plagioclase, clinopyroxene, ferric phyllosilicates, and red crystalline hematite in significant abundances. These minerals all have unique spectral signatures that contributed to spectra obtained by the Mastcam multispectral imager of the eight drilled rocks. By comparing spectral parameters of drill tailings from the eight rocks to their quantitative mineralogy, this paper found that the spectral differences of VRR and surrounding units are the result of variations in ferric phyllosilicates, clinopyroxene, and red crystalline hematite. New lab spectral measurements successfully reproduced the same trends as seen in data from the Curiosityrover. The results of this work help us better understand how different minerals affect the spectral signals we measure on Mars, which is extremely important to understanding its geologic history. Hematite likely controls the wavelength position of the ~860 nm absorption in Mastcam multispectral observations of drill targetsLab results show that the ~860 nm band depth increases with ferric phyllosilicate abundance due to its ~800–1,000 nm featureThe reflectance maximum near 860 nm in pyroxene affects the ~860 nm band depth in spectra of lab mixtures and drilled rocks on Mars

Images from the Mars Science Laboratory (MSL) mission of lacustrine sedimentary rocks of Vera Rubin ridge on “Mt. Sharp” in Gale crater, Mars, have shown stark color variations from red to purple to gray. These color differences crosscut stratigraphy and are likely due to diagenetic alteration of the sediments after deposition. However, the chemistry and timing of these fluid interactions is unclear. Determining how diagenetic processes may have modified chemical and mineralogical signatures of ancient Martian environments is critical for understanding the past habitability of Mars and achieving the goals of the MSL mission. Here we use visible/near‐infrared spectra from Mastcam and ChemCam to determine the mineralogical origins of color variations in the ridge. Color variations are consistent with changes in spectral properties related to the crystallinity, grain size, and texture of hematite. Coarse‐grained gray hematite spectrally dominates in the gray patches and is present in the purple areas, while nanophase and fine‐grained red crystalline hematite are present and spectrally dominate in the red and purple areas. We hypothesize that these differences were caused by grain‐size coarsening of hematite by diagenetic fluids, as observed in terrestrial analogs. In this model, early primary reddening by oxidizing fluids near the surface was followed during or after burial by bleaching to form the gray patches, possibly with limited secondary reddening after exhumation. Diagenetic alteration may have diminished the preservation of biosignatures and changed the composition of the sediments, making it more difficult to interpret how conditions evolved in the paleolake over time. Sedimentary rocks found in deserts on Earth often exhibit striking color differences from red and purple to white, which are caused by groundwater dissolving and reprecipitating iron oxides within the rocks. NASA's Mars Science Laboratory (MSL) mission has observed similar color differences on Mars within the sedimentary rocks of Vera Rubin ridge in Gale crater, which were laid down in an ancient lake. We use color images and spectral data from the Mastcam cameras on MSL to investigate the origin of these color differences and find that they are consistent with changes in iron oxides through the ridge. This variation in iron oxides suggests that groundwater flowed through and altered these rocks multiple times before and after they were buried by later sediments. The MSL mission has shown that habitable lake environments once existed in Gale crater, through detections of the building blocks of life, including organic molecules, and by showing that conditions that existed in the lake were clement for life. However, later alteration by groundwater may have diminished the preservation of organics and changed the composition of these rocks, making it more difficult to interpret the details of how conditions evolved in the lake over time. Vera Rubin ridge exhibits strong color differences that crosscut stratigraphy, consistent with postdepositional alteration (diagenesis)Color differences correspond to variations in spectral signatures of nanophase, fine‐grained, and coarse‐grained hematiteBased on terrestrial analogs, these variations can be explained by early oxidation and later coarsening of hematite by diagenetic fluids

The resistant ~50 m thick Vera Rubin ridge (VRR) situated near the base of Mount Sharp, Gale crater, Mars, has been deemed a high priority science target for the Mars Science Laboratory mission. This is because of (1) its position at the base of the 5 km layered strata of Mount Sharp and (2) the detection of hematite from orbit, indicating that it could be the site of enhanced oxidation. The compositional data acquired by the Alpha Particle X‐ray Spectrometer (APXS) during Curiosity's exploration of VRR help to elucidate questions pertaining to the formation of the ridge. APXS analyses indicate that VRR falls within the compositional range of underlying lacustrine mudstones, consistent with a continuation of that depositional environment and derivation from a similar provenance. Lower Fe concentrations for VRR compared to the underlying strata discounts the addition of large amounts of hematite to the strata, either as cement or as detrital input. Compositional trends are associated with VRR cross‐cut stratigraphy, indicating postdepositional processes. Higher Si and Al and lower Ti, Fe, and Mn than the underlying mudstone, particularly within distinct patches of gray/blue bedrock, are consistent with the addition of Si and Al. Lateral and vertical compositional variations suggest enhanced element mobility and fluid flow (possibly via multiple events) through VRR, increasing toward the top of the ridge, consistent with the action of warm (~50–100°C), locally acidic saline fluids as inferred from the mineralogy of drilled samples. Curiosity has explored the resistant Vera Rubin ridge (VRR) at the base of Mount Sharp, Gale crater, Mars, owing to (1) its position within the 5 km layered rocks of Mount Sharp, which record changes in Mars environment through time, and (2) the detection of hematite from orbit. The Alpha Particle X‐ray Spectrometer (APXS) measures the elemental composition of rocks. APXS analyses indicate that VRR has a similar composition to underlying mudstones, consistent with continued deposition in a lake. Lower iron discounts the addition of large amounts of hematite, holding together mineral grains either as cement or as detrital grains. Other elemental trends cut across layering, indicating postdepositional processes. Lateral and vertical compositional variations suggest enhanced element mobility and fluid flow (possibly via multiple events) through VRR, particularly at the top of the ridge and within gray/blue patches of bedrock, consistent with the action of warm (~50–100°C), acidic saline fluids inferred from the mineralogy of drilled samples. Vera Rubin ridge is compositionally a continuation of the Murray formationCompositional trends cut across stratigraphy, are postdepositional, diagenetic, and/or products of later alterationAPXS data indicate enhanced fluid flow and Si, Al, and Mn mobilization within VRR

Geochemical results are presented from Curiosity's exploration of Vera Rubin ridge (VRR), in addition to the full chemostratigraphy of the predominantly lacustrine mudstone Murray formation up to and including VRR. VRR is a prominent ridge flanking Aeolis Mons (informally Mt. Sharp), the central mound in Gale crater, Mars, and was a key area of interest for the Mars Science Laboratory mission. ChemCam data show that VRR is overall geochemically similar to lower‐lying members of the Murray formation, even though the top of VRR shows a strong hematite spectral signature as observed from orbit. Although overall geochemically similar, VRR is characterized by a prominent decrease in Li abundance and Chemical Index of Alteration across the ridge. This decrease follows the morphology of the ridge rather than elevation and is inferred to reflect a nondepositionally controlled decrease in clay mineral abundance in VRR rocks. Additionally, a notable enrichment in Mn above baseline levels is observed on VRR. While not supporting a single model, the results suggest that VRR rocks were likely affected by multiple episodes of postdepositional groundwater interactions that made them more erosionally resistant than surrounding Murray rocks, thus resulting in the modern‐day ridge after subsequent erosion. Results from the ChemCam instrument on Vera Rubin ridge (VRR) in Gale crater, Mars, are presented and compared with observations from similar rocks leading up to the ridge. VRR is a prominent ridge, flanking the central mound, Aeolis Mons, in Gale crater, Mars. The ridge attracted early attention because it displays strong iron‐oxide spectral signatures. Surprisingly, ChemCam data show that VRR rocks do not show an overall increase in iron abundance relative to the comparable bedrock analyzed for almost 300 m in elevation leading up to the ridge. While similar overall, some notable variations were observed on VRR relative to lower‐lying rocks. In particular, geochemical variations suggest a strong decrease in clay content on the ridge, above which, a notable enrichment in Mn is observed. No single geological process confidently explains all observations on the ridge. Rather, we think that VRR rocks underwent a series of interactions with groundwater that caused the rocks of VRR to become more resistant to erosion than their surroundings, thus emerging as a ridge as the rocks around them eroded. This likely implies that groundwater persisted in Gale crater even long after the disappearance of the ancient lake. A decrease in Li and Chemical Index of Alteration, reflecting clay mineral content, is observed across Vera Rubin ridge (VRR)A Mn‐rich interval is observed stratigraphically above the decrease in clay mineral content on VRRVRR likely resulted from increased induration from late‐stage fluid interactions long after the lake environment in Gale crater ceased

Vera Rubin ridge (VRR) is an erosion‐resistant feature on the northwestern slope of Mount Sharp in Gale crater, Mars, and orbital visible/shortwave infrared measurements indicate it contains red hematite. The Mars Science Laboratory Curiosityrover performed an extensive campaign on VRR to study its mineralogy, geochemistry, and sedimentology to determine the depositional and diagenetic history of the ridge and constrain the processes by which the hematite could have formed. X‐ray diffraction (XRD) data from the CheMin instrument of four samples drilled on and below VRR demonstrate differences in iron, phyllosilicate, and sulfate mineralogy and hematite grain size. Hematite is common across the ridge, and its detection in a gray outcrop suggest localized regions with coarse‐grained hematite, which commonly forms from warm fluids. Broad XRD peaks for hematite in one sample below VRR and the abundance of FeOTin the amorphous component suggest the presence of nanocrystalline hematite and amorphous Fe oxides/oxyhydroxides. Well crystalline akaganeite and jarosite are present in two samples drilled from VRR, indicating at least limited alteration by acid‐saline fluids. Collapsed nontronite is present below VRR, but samples from VRR contain phyllosilicate with d(001) = 9.6 Å, possibly from ferripyrophyllite or an acid‐altered smectite. The most likely cementing agents creating the ridge are hematite and opaline silica. We hypothesize late diagenesis can explain much of the mineralogical variation on the ridge, where multiple fluid episodes with variable pH, salinity, and temperature altered the rocks, causing the precipitation and crystallization of phases that are not otherwise in equilibrium. Vera Rubin ridge (VRR) is an erosion‐resistant feature on the northwestern slope of Mount Sharp in Gale crater, Mars, and it contains the Fe (III) oxide mineral hematite. Hematite is an especially important mineral to study on the Martian surface because it commonly forms in the presence of liquid water. Identifying the processes that formed hematite on VRR can help constrain the history of liquid water in Gale crater. The Mars Science Laboratory Curiosityrover performed an extensive campaign on VRR to determine the geologic history of the ridge. Mineralogical data collected by the CheMin instrument of four rock samples drilled on and below the ridge demonstrate changes in the mineralogy and provide clues about the aqueous history of VRR. Red hematite is common across the ridge, but detection of gray hematite in one sample indicates the presence of localized coarse‐grained hematite, which commonly forms under warm temperatures. Minerals that form in acidic, saline solutions were found in two samples, indicating localized alteration in acidic and relatively salty waters. We hypothesize that multiple episodes of groundwater with variable pH, salinity, and temperature altered the sediments after they lithified. Data from the CheMin X‐ray diffractometer demonstrate a variety of secondary alteration products on Vera Rubin ridgeHematite particle size changes across and below the ridge, and this change may be a marker of diagenetic reactionThe aqueous history of Vera Rubin ridge was complex, with several fluid episodes that varied in temperature, salinity, and pH

Hydrothermal high sanidine and specular hematite are found within ferric‐rich and gray‐colored cemented basaltic breccia occurring within horizontal, weathering‐resistant strata exposed in an erosional gully of the Pu'u Poliahu cinder cone in the summit region of Maunakea volcano (Hawai'i). The cone was extensively altered by hydrothermal, acid‐sulfate fluids at temperatures up to ~400 °C, and, within strata, plagioclase was removed by dissolution from progenitor Hawaiitic basalt, and sanidine and hematite were precipitated. Fe2O3T concentration and Fe3+/∑Fe redox state are ~12 wt.% and ~0.4 for progenitor basalt and 46–60 wt.% and ~1.0 for cemented breccias, respectively, implying open‐system alteration and oxic precipitation. Hydrothermal high sanidine (adularia) is characterized by full Al,Si structural disorder and monoclinic unit‐cell (Rietveld refinement): a= 8.563(19) Å, b= 13.040(6) Å, c= 7.169(4) Å, β= 116.02(10)°, and V= 719.4(19) Å3. Hematite (structure confirmed by Rietveld refinement) is the predominant Fe‐bearing phase detected. Coarse size fractions of powdered hematite‐rich breccia (500–1000 μm) are dark and spectrally neutral at visible wavelengths, confirming specular hematite, and SEM images show platy to polyhedral hematite morphologies with longest dimensions >10 μm. Smectite and 10‐Å phyllosilicate, both chemically dominated by Mg as octahedral cation, are additional diagenetic hydrothermal alteration products. By analogy and as a working hypothesis, high sanidine (Kimberly formation) and specular hematite (Mt. Sharp group at Hartmann's Valley and Vera Rubin ridge) at Gale crater are interpreted as diagenetic alteration products of Martian basaltic material by hydrothermal processes. A layer of weathering‐resistant material is located within the walls of an erosional gully of the Pu'u Poliahu cinder cone in the summit region of Maunakea volcano (Hawai'i). The volcanic cone, initially composed of unaltered basaltic material (tephra), was extensively altered throughout by hot, sulfuric‐acid solutions. The layer is a location where the alteration by hot water was particularly aggressive, cementing the volcanic sediment and causing extensive chemical and mineralogical changes. Instead of basaltic chemical and mineralogical compositions, altered tephra was enriched in iron from aqueous precipitation of the mineral hematite (Fe2O3) and was characterized by high sanidine with full structural disorder as the feldspar (instead of plagioclase, which was removed by dissolution) and by Mg‐rich phyllosilicates as additional precipitation products. Hematite, often present as a red pigment in geologic materials, was precipitated from the hot water as specular (i.e., gray) hematite. By analogy, high sanidine and specular hematite at Gale crater (Mars) can be interpreted as alteration products of preexisting Martian basaltic sediment by hot‐water solutions. High sanidine (full Al,Si structural disorder) and specular hematite hydrothermally precipitated on basaltic Maunakea volcano, Hawai'iSmectite and 10‐Å phyllosilicate (both Mg‐rich) also hydrothermally precipitated as diagenetic phasesHigh sanidine and specular hematite at Gale crater can result from diagenetic alteration of basaltic compositions by hydrothermal fluids

Visible/short‐wave infrared spectral data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) show absorptions attributed to hematite at Vera Rubin ridge (VRR), a topographic feature on northwest Mt. Sharp. The goals of this study are to determine why absorptions caused by ferric iron are strongly visible from orbit at VRR and to improve interpretation of CRISM data throughout lower Mt. Sharp. These goals are achieved by analyzing coordinated CRISM and in situ spectral data along the Curiosity Mars rover's traverse. VRR bedrock within areas that have the deepest ferric absorptions in CRISM data also has the deepest ferric absorptions measured in situ. This suggests strong ferric absorptions are visible from orbit at VRR because of the unique spectral properties of VRR bedrock. Dust and mixing with basaltic sand additionally inhibit the ability to measure ferric absorptions in bedrock stratigraphically below VRR from orbit. There are two implications of these findings: (1) Ferric absorptions in CRISM data initially dismissed as noise could be real, and ferric phases are more widespread in lower Mt. Sharp than previously reported. (2) Patches with the deepest ferric absorptions in CRISM data are, like VRR, reflective of deeper absorptions in the bedrock. One model to explain this spectral variability is late‐stage diagenetic fluids that changed the grain size of ferric phases, deepening absorptions. Curiosity's experience highlights the strengths of using CRISM data for spectral absorptions and associated mineral detections and the caveats in using these data for geologic interpretations and strategic path planning tools. Satellites orbiting Mars map the composition of the planet's surface, tell us about past environments, and guide rovers to interesting locations on the surface. The Curiosity rover investigated a ridge named Vera Rubin ridge where indications of the mineral hematite (Fe2O3) was suggested from orbital data. In this paper, we investigate why the hematite detection on the ridge was so clear from orbit and what the implications are for how the hematite formed. We found several factors influence the orbital data, but the biggest reason hematite at Vera Rubin ridge was so easily detected from orbit was because the bedrock there was unique. Water had interacted with rocks at the ridge sometime after they were deposited, and this interaction affected the properties of the hematite and made it more visible from orbit. Curiosity's data help us reinterpret the orbital data over Mt. Sharp and reveal hematite is probably present in most of the bedrock there. Furthermore, there are other areas with particularly clear hematite detections that likely formed in a similar manner as Vera Rubin ridge. We end this paper with a discussion of lessons learned from this experience for using orbital data to guide rovers in the future. Areas on Vera Rubin ridge with deep ferric absorptions from orbit also have deep ferric absorptions in Curiosity spectral data setsFerric phases are more widespread on Mt. Sharp than originally reported. Diagenesis deepened ferric absorptions in several locationsCombining orbital and in situ observations enhances planetary exploration

Ground‐based bedding orientation measurements are critical to determine the geologic history and processes of sedimentation in Gale crater, Mars. We constrain the dip of lacustrine strata of the Blunts Point, Pettegrove Point, and Jura members of the Murray formation using a combination of regional stratigraphic correlations and bed attitude measurements from stereo Mastcam images taken by the Mars Science Laboratory Curiosity rover. In situ bed attitude measurements using a principal component analysis‐based regression method reveal a wide range of dips and dip azimuths owing to a combination of high stereo errors, postdepositional deformation of strata (e.g., fracturing, rotation, and impact cratering), and different primary depositional dips. These constrain regional dips to be within several degrees of horizontal on average. Stratigraphic correlations between targets observed in the Glen Torridon trough and at the Pettegrove Point‐Jura member contact of Vera Rubin ridge (VRR) constrain dips to be between 3°SE and 2°NW, consistent with nearly flat strata deposited horizontally on an equipotential surface. The Jura member is determined to be stratigraphically equivalent to the northern portion of the Glen Torridon trough. Rover‐based dip magnitudes are generally significantly shallower than the orientation of VRR member contacts measured from High Resolution Imaging Science Experiment‐based traces, suggesting the sedimentary strata and VRR member contacts may be discordant. The orientation of sedimentary strata is one of the most fundamental measurements of structural geology because it records information about the processes of deposition and subsequent deformation of those strata. For the last 7 years, the Curiosity rover has traversed predominantly fluviolacustrine (river‐ and lake‐deposited) strata. Recently, the rover traversed the Vera Rubin ridge (VRR), a topographic rise within a larger collection of strata with rock exposures whose orientation can be measured using overlapping (stereo) images taken by cameras aboard the rover. By measuring the orientation of beds in stereo rover images and comparing the elevation of similar rock lithologies found along the traverse, we constrain the strata that comprise the VRR to be horizontal or only shallowly dipping. This result is consistent with the sediment that formed the VRR being deposited on a nearly horizontal surface, suggesting that at least the strata that make up the lower portion of Mount Sharp, the large sedimentary mound in Gale crater that dips more steeply outward, may not have directly contributed to its primary formation. The near‐flat orientation also indicates that some portion of the VRR occurs at the same elevation as the region south of the ridge called Glen Torridon. We use stereo rover images and stratigraphic correlations to constrain the dip of Vera Rubin ridge strata to be flat or nearly flatThe Jura member of the Vera Rubin ridge is stratigraphically equivalent to part of Glen TorridonVera Rubin ridge member contacts and the strata that comprise them are likely discordant

For ~500 Martian solar days (sols), the Mars Science Laboratory team explored Vera Rubin ridge (VRR), a topographic feature on the northwest slope of Aeolis Mons. Here we review the sedimentary facies and stratigraphy observed during sols 1,800–2,300, covering more than 100 m of stratigraphic thickness. Curiosity's traverse includes two transects across the ridge, which enables investigation of lateral variability over a distance of ~300 m. Three informally named stratigraphic members of the Murray formation are described: Blunts Point, Pettegrove Point, and Jura, with the latter two exposed on VRR. The Blunts Point member, exposed just below the ridge, is characterized by a recessive, fine‐grained facies that exhibits extensive planar lamination and is crosscut by abundant curvi‐planar veins. The Pettegrove Point member is more resistant, fine‐grained, thinly planar laminated, and contains a higher abundance of diagenetic concretions. Conformable above the Pettegrove Point member is the Jura member, which is also fine‐grained and parallel stratified, but is marked by a distinct step in topography, which coincides with localized meter‐scale inclined strata, a thinly and thickly laminated facies, and occasional crystal molds. All members record low‐energy lacustrine deposition, consistent with prior observations of the Murray formation. Uncommon outcrops of low‐angle stratification suggest possible subaqueous currents, and steeply inclined beds may be the result of slumping. Collectively, the rocks exposed at VRR provide additional evidence for a long‐lived lacustrine environment (in excess of 106years via comparison to terrestrial records of sedimentation), which extends our understanding of the duration of habitable conditions in Gale crater. The primary goal of the Mars Science Laboratory Curiosity rover mission is to explore and assess ancient habitable environments on Mars. This requires a detailed understanding of the environments recorded by sedimentary rocks exposed at the present‐day surface in Gale crater. Here we review the types of sedimentary rocks exposed at a location known as Vera Rubin ridge. We find that the rocks at Vera Rubin ridge record an ancient lake environment and are a continuation of underlying lake deposits. Ancient lake deposits are highly desirable targets in the search for habitable environments, due to their ability to concentrate and preserve organic matter. This study significantly expands the duration of habitable conditions that can be confirmed through ground truth of sedimentary rocks and provides a framework for interpreting strata that lie ahead as Curiosity continues to explore Aeolis Mons. Six sedimentary facies were identified at and just below Vera Rubin ridge and comprise three members of the Murray formationVera Rubin ridge records deposition in a lacustrine environment, which expands the duration of habitable conditions observed in GaleThe facies and stratigraphy identified here serve as a framework for interpreting strata within the Glen Torridon region and beyond