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Intensifying permafrost thaw alters carbon cycling by mobilizing large amounts of terrestrial substrate into aquatic ecosystems. Yet, few studies have measured aquatic carbon fluxes and constrained drivers of ecosystem carbon balance across heterogeneous Arctic landscapes. Here, we characterized hydrochemical and landscape controls on fluvial carbon cycling, quantified fluvial carbon fluxes, and estimated fluvial contributions to ecosystem carbon balance across 33 watersheds in four ecoregions in the continuous permafrost zone of the western Canadian Arctic: unglaciated uplands, ice‐rich moraine, and organic‐rich lowlands and till plains. Major ions, stable isotopes, and carbon speciation and fluxes revealed patterns in carbon cycling across ecoregions defined by terrain relief and accumulation of organics. In previously unglaciated mountainous watersheds, bicarbonate dominated carbon export (70% of total) due to chemical weathering of bedrock. In lowland watersheds, where soil organic carbon stores were largest, lateral transport of dissolved organic carbon (50%) and efflux of biotic CO2(25%) dominated. In watersheds affected by thaw‐induced mass wasting, erosion of ice‐rich tills enhanced chemical weathering and increased particulate carbon fluxes by two orders of magnitude. From an ecosystem carbon balance perspective, fluvial carbon export in watersheds not affected by thaw‐induced wasting was, on average, equivalent to 6%–16% of estimated net ecosystem exchange (NEE). In watersheds affected by thaw‐induced wasting, fluvial carbon export approached 60% of NEE. Because future intensification of thermokarst activity will amplify fluvial carbon export, determining the fate of carbon across diverse northern landscapes is a priority for constraining trajectories of permafrost region ecosystem carbon balance. Freshwaters are a main component of the global carbon cycle and climate. Yet, their role in climate change is uncertain in permafrost regions, where thaw is releasing large amounts of carbon and enabling production of climate‐warming greenhouse gases. To reduce uncertainty, we measured stream chemistry and carbon fluxes across four ecoregions including a global hotspot of permafrost thaw in the western Canadian Arctic. Comparing across ecoregions, lowlands were strong sources of biological carbon dioxide and methane to the atmosphere; mountain rivers ferried products from chemical rock weathering downstream; and streams affected by permafrost thaw‐induced wasting transported large amounts of particulate carbon. Typical of northern ecosystems, carbon fluxes in non‐thaw‐affected streams were equivalent to 6%–16% of carbon uptake by terrestrial vegetation. However, in watersheds affected by thaw‐induced wasting, carbon fluxes were up to 100 times higher and approached 60% of vegetation carbon uptake. Together, these findings reveal that thermokarst‐susceptible terrains are poised to emerge as a significant component of the Arctic ecosystem carbon balance and global climate feedbacks, due to hydrologic carbon fluxes that will intensify as permafrost thaw accelerates. Permafrost landscape history regulates fluvial carbon (C) sources and export across a transect of continental glaciation and thermokarstFluvial C flux equaled 6%–16% of vegetation C uptake in most watersheds and 60% in those affected by permafrost thaw‐driven mass wastingThaw‐susceptible terrains will be significant to Arctic ecosystem carbon balance as permafrost thaw and hydrologic carbon fluxes intensify Permafrost landscape history regulates fluvial carbon (C) sources and export across a transect of continental glaciation and thermokarst Fluvial C flux equaled 6%–16% of vegetation C uptake in most watersheds and 60% in those affected by permafrost thaw‐driven mass wasting Thaw‐susceptible terrains will be significant to Arctic ecosystem carbon balance as permafrost thaw and hydrologic carbon fluxes intensify

Land surface models (LSMs) are often applied to predict the one‐way coupling strength between surface soil moisture (SM) and latent heat (LH) flux. However, the ability of LSMs to accurately represent such coupling has not been adequately established. Likewise, the estimation of SM/LH coupling strength using ground‐based observational data is potentially compromised by the impact of independent SM and LH measurements errors. Here we apply a new statistical technique to acquire estimates of one‐way SM/LH coupling strength which are nonbiased in the presence of random error using a triple collocation approach based on leveraging the simultaneous availability of independent SM and LH estimates acquired from (1) LSMs, (2) satellite remote sensing, and (3) ground‐based observations. Results suggest that LSMs do not generally overestimate the strength of one‐way surface SM/LH coupling. Random error in measurements bias estimates of soil moisture/surface evaporation couplingTriple collocation provides a statistical tool to correct such estimatesLand surface models do not overestimate the strength of this coupling

Net CO2exchange data of legume crops at 17 flux tower sites in North America and three sites in Europe representing 29 site‐years of measurements were partitioned into gross photosynthesis and ecosystem respiration by using the nonrectangular hyperbolic light‐response function method. The analyses produced net CO2exchange data and new ecosystem‐scale ecophysiological parameter estimates for legume crops determined at diurnal and weekly time steps. Dynamics and annual totals of gross photosynthesis, ecosystem respiration, and net ecosystem production were calculated by gap filling with multivariate nonlinear regression. Comparison with the data from grain crops obtained with the same method demonstrated that CO2exchange rates and ecophysiological parameters of legumes were lower than those of maize (Zea maysL.) but higher than for wheat (Triticum aestivumL.) crops. Year‐round annual legume crops demonstrated a broad range of net ecosystem production, from sinks of 760 g CO2m−2yr−1to sources of –2100 g CO2m−2yr−1, with an average of –330 g CO2m−2yr−1, indicating overall moderate CO2–source activity related to a shorter period of photosynthetic uptake and metabolic costs of N2fixation. Perennial legumes (alfalfa, Medicago sativaL.) were strong sinks for atmospheric CO2, with an average net ecosystem production of 980 (range 550–1200) g CO2m−2yr−1.

Measurements of the behavior of ferroelectric and ferroelastic phase transitions under uniaxial stress are relatively sparse. Reviewed here are several studies of the uniaxial stress dependence of commensurate and incommensurate transitions observed in measurements of dielectric properties, inelastic light scattering, and birefringence.† Work at the University of Nebraska was supported by the Air Force Office of Scientific Research, 1970-1975, and by the Army Research Office, 1976-present.The authors are greatly honored to have been included among those contributing to this volume, honoring our esteemed colleague, “Teru” Nakamura for his leadership in our field, and his fundamentally important studies of ferroelectric materials.