1. Diffusion Creep of Sodic Amphibole‐Bearing Blueschist Limited by Microboudinage
- Author
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Tokle, Leif, Hufford, Lonnie J., Behr, Whitney M., Morales, Luiz F. G., and Madonna, Claudio
- Abstract
To investigate the mechanical and microstructural properties of mafic blueschists, we conducted deformation experiments on powdered natural blueschist aggregates using the general shear geometry in the Griggs apparatus. Experiments were performed at ∼1.0 GPa and temperatures ranging from 650 to 700°C. The blueschist starting material consists primarily of sodic amphibole and epidote, with minor amounts of quartz, titanite, albite, and white mica. Strain rate stepping experiments provided mechanical data with stress exponents ranging from 1.8 to 2.2. Microstructural analysis of the deformed samples show that the blueschist aggregates were deforming by microboudinage of the sodic amphibole, with a chemically new sodic‐calcic amphibole diffused into the boudin neck. Based on these results, we interpret the samples to have deformed by diffusion creep of the sodic‐calcic amphibole, which was rate‐limited by diffusion into the boudin neck. We developed a microboudinage diffusion creep flow law using a least square regression, with parameters of A= 2.43e11 MPa−nμm s−1, n= 2.0 ± 0.3, m= 1.0, and Q= 384 ± 15 kJ/mol. Extrapolation of the flow law to the blueschist stability field suggests viscosities that are higher than metasedimentary rocks (quartz dislocation creep flow law) and lower than eclogitic rocks (omphacite dislocation creep flow law) consistent with field observations. We also show that this type of deformation mechanism matches observations of natural rocks in paleosubduction zone environments, supporting the application of this flow law to estimate amphibole rheology in modern subduction zones. We conducted deformation experiments on samples of metamorphosed oceanic crust called blueschist, which is a rock abundant in sodium‐rich amphibole and epidote. These rocks and minerals occur at high pressures (∼1 GPa) and low temperatures (∼400°C) within the earth, primarily along the subduction zone interface. By conducting deformation experiments we can characterize and quantify the microstructural and mechanical properties of our samples. We find sodic amphibole, the most abundant mineral in our samples, deforms by a process called microboudinage, where the sodic amphibole fractures and new material simultaneously diffuses into the fracture, allowing the sample to accommodate strain. Using existing theory on microboudinage and the mechanical data from our deformation experiments, we develop a mechanical relationship (e.g., flow law) that can be extrapolated to geologic conditions to provide constraints on blueschist deformation along the subduction zone interface. To support the extrapolation of our flow law, we show that microboudinage has been widely observed in naturally deformed amphiboles from paleosubduction zone environments. Experimentally deformed sodic amphibole deforms by microboudinage with sodic‐calcic amphibole diffusing into the boudin neckWe developed a microboudinage flow law with a stress exponent of 2.0Extrapolation of the flow law provides viscosity estimates consistent with existing flow laws representative of the subduction interface Experimentally deformed sodic amphibole deforms by microboudinage with sodic‐calcic amphibole diffusing into the boudin neck We developed a microboudinage flow law with a stress exponent of 2.0 Extrapolation of the flow law provides viscosity estimates consistent with existing flow laws representative of the subduction interface
- Published
- 2023
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