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One-dimensional (1D) Y2Ti2O7 (YTO): Ho3+/Yb3+ nanofibers with diameters ranging from 300 to 400 nm were synthesized by an electrospinning technology and the structure of YTO nanofibers was identified as face-centered cubic pyrochlores. The detected green and red signals in the upconversion emission spectra under 980 nm laser excitation are due to the radiative transitions (5F4, 5S2) ? 5I8 and 5F5 = 5I8 of Ho3+ ions, respectively. YTO: Ho3+/Yb3+ nanofibers have the characteristics of porosity, threedimensional braidability, high specific surface area and controllable structure, which improves the performance of optical temperature sensing. Furthermore, the nanofiber membranes consisting of YTO: Ho3+/Yb3+ with temperature sensing performance can work steadily at medium temperature range in view of its fast responses and high stability, moreover, a maximum sensitivity about 0.18% K-1 at 423 K, which indicates that the nanofibers have good thermal sensitivity. 1D nanostructure rare earth iondoped cubic pyrochlore material was proven to obtain excellent upconversion luminescence properties, which provides a new route for the development of sensitive optical temperature-sensing materials. [ABSTRACT FROM AUTHOR]