1. Photo-supercapacitors based on zinc oxide/MXene paper dual acting electrodes
- Author
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Colak, Tuluhan Olcayto, Altaf, Cigdem Tuc, Yesilbag, Fatma Nur Tuzluca, Yesilbag, Yasar Ozkan, Yildirim, Ipek Deniz, Erdem, Emre, Misirlioglu, Feray Bakan, Sankir, Nurdan Demirci, and Sankir, Mehmet
- Abstract
Photo-supercapacitors (PSCs) have great potential as devices that enable both the conversion and storage of solar energy. However, it remains challenging to design new dual-acting electrodes providing high energy density and capacitance with self-powering capacity. Herein, we successfully prepared dual electrodes using ZnO-nanoflake and Ti3C2Tx-based MXene paper. By utilization of the MXene to the PSC device, capacitive contribution to the total capacitance increased ∼4 times compared to the bare ZnO-nanoflake-based PSC due to the surface redox reactions and electrically double layer formation. Maximum energy and power density of 57.3 μWhcm−2and 11.1 mWcm−2, respectively were obtained for ZnO/MXene//MXene-PSC@UV irradiation and at a 2.5 V. Areal capacitance of this device calculated from CV was as high as 151.5 mFcm−2. Moreover, the ZnO/MXene//MXene-PSC device was highly stable over 10,000 GCD cycles with 100 % CE and 98 % Cp-retention under daylight.
- Published
- 2024
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