1. Modeling of volatile organic compounds degradation by photocatalytic oxidation reactor in indoor air: A review.
- Author
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Malayeri, Mojtaba, Haghighat, Fariborz, and Lee, Chang-Seo
- Subjects
VOLATILE organic compounds ,CHEMICAL kinetics ,LITERATURE reviews ,MASS transfer ,PHOTOCATALYTIC oxidation ,MATHEMATICAL models - Abstract
Photocatalytic oxidation (PCO) has a great potential to eliminate various gaseous pollutants even at low concentrations. Numerous studies have been carried out to improve the effectiveness and performance of this technology. In addition, the development of appropriate models can enhance the understanding of reactor performance and the evaluation the intrinsic kinetic parameters that enable the scale up or re-design of more efficient large-scale photocatalytic reactors. This paper reviews recent research works on mathematical modeling of gas phase photocatalytic reactors and analyses different key factors that can enhance pollutants decomposition performance. First, the fundamental of the photocatalytic oxidation process and degradation reaction mechanism are briefly described. Then, to study kinetics of reaction, this paper focuses on Langmuir-Hinshelwood equation, which is by far the most common kinetic model that takes both adsorption and reaction processes into account. Moreover, an overall mass balance that contains advection, diffusion, and reaction rate terms, is analyzed to obtain a comprehensive mathematical model. In the end, the influence of key operating parameters (e.g. flow rate, catalyst surface area and porosity, and catalyst thickness) on the photocatalytic process and removal efficiency of the reactor are discussed. • Comprehensive literature review on mathematical modeling of photocatalytic oxidation of VOCs in the air is presented. • Fundamental of PCO process including mass transfer and degradation reaction mechanism are reviewed. • Analysis of key operating parameters affecting on PCO performance and on mathematical model is conducted. • A mass balance containing advection, diffusion and reaction rate equations can provide detailed modeling of PCO reactor. [ABSTRACT FROM AUTHOR]
- Published
- 2019
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