62 results on '"Bravo, Pierfrancesco"'
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2. Regioselective 4-amino-de-chlorination of trichloro- and dichloro-pyrimidines with N-sodium carbamates
3. Synthesis of stereo-defined α-trifluoromethyl (Tfm)-malic units
4. Unusual nonchelation controlled allylation of a N-monoprotected α-amino aldehyde: stereoselective entry to nonracemic trifluoromethyl dipeptide isosteres
5. Total synthesis of a pepstatin analog incorporating two trifluoromethyl hydroxymethylene isosteres (Tfm-GABOB) and evaluation of Tfm-GABOB containing peptides as inhibitors of HIV-1 protease and MMP-9
6. Solution and solid-phase synthesis of trifluoromethyl peptides and mimetics
7. Asymmetric synthesis of α-arylglycinols via additions of lithium methyl p-tolyl sulfoxide to N-(PMP)arylaldimines followed by “non oxidative” Pummerer reaction
8. Synthesis and biological activity of β-fluoroalkyl β-amino alcohols
9. Synthesis of (−)-(1 S,5 R)- and (+)-(1 R,5 S)-trifluoroanalogues of frontalin
10. An umpolung sulfoxide reagent as α-hydroxy and α-chloro benzyl carbanion equivalents
11. Regioselective solid-phase 4-amino-de-chlorination of 2,4,6-trichloropyrimidine by resin-supported N-potassium carbamates
12. The ‘non-oxidative’ chloro-Pummerer reaction: a highly stereoselective entry to β-chloro amines and aziridines
13. Total synthesis of a Pepstatin analogue incorporating two trifluoromethyl hydroxymethylene isosteres
14. Solid-phase synthesis of partially-modified retro and retro-inverso ψ[NHCH(CF 3)]-peptides
15. New fluorinated chiral synthons
16. Synthesis of optically pure ( R)- and ( S)-α-trifluoromethyl-alanine
17. Preparation and properties of chiral fluoroorganic compounds
18. Stereocontrolled approaches to (+)- and (−)-γ-trifluoromethyl-GABOB, a new hydroxymethylene (statine) dipeptide isostere
19. Synthesis of N-Cbz-fluoropyruvaldehyde N, S-ketals: construction of highly stereoselective and high yielding synthetic reactions using multivariate modelling and design
20. Stereoselective synthesis of the antibacterial 3-fluoro- d-alanine
21. Enantiomerically pure α-fluoroalkyl-α-amino acids: Synthesis of ( R)- α-difluoromethyl-alanine and ( S)- α-difluoromethyl-serine
22. On the preparation of disymmetrized tris(hydroxymethyl) methanol equivalents
23. Synthesis and reactions of enantiomerically pure chloromethyl oxiranes
24. Unusual non-oxidative pummerer rearrangement of γ-trifluoro-β-aminosulfoxides
25. A new versatile fluorinated C 4 chiron
26. N-Cbz-Trifluoropyruvaldehyde N, S-ketal: Absolute stereochemistry and addition of Grignard reagents. Highly stereoselective entry to trifluoro analogues of Ephedra alkaloids
27. Stereoselective synthesis of optically pure γ-fluoro-β-enaminosulfoxides and reduction to γ-fluoro-β-aminosulfoxides
28. A cycloadditive route to trifluoromethyl-substituted aminoalcohols
29. Asymmetric synthesis of 3-chloro-3-fluoro- and 3-fluoro-2,4-disubstituted tetrahydrofurans by the “fluorinated sulfoxide chiron” route
30. Synthesis of the (4S, 5R)-5-hydroxy-decan-4-olide (L-factor) and of the (R)-decan-4-olide from a chiral sulphoxide
31. Synthetically useful C-4 fluorinated building blocks bearing a quaternary stereocentre
32. On the synthesis of optically pure monofluorocyclohexanol derivatives by the fluorinated sulfoxide chiron route
33. Highly diastereoselective methylene transfer from diazomethane to the carbonyl of β-keto sulfoxides. A general approach to synthetically versatile fluorine-containing chiral building blocks
34. Synthesis and reactivity of enantiomerically pure 2-fluoromethyl-2-(1′- p-tolylsulfinyl)alkyl oxiranes
35. An efficient entry to perfluoroalkyl substituted azoles starting from β-perfluoroalkyl-β-dicarbonyl compounds
36. Optically pure and fluoro substituted acyclovir analogues
37. Intramolecular trapping of difluoroalkyl radicals by tethered olefin in the asymmetric synthesis of 2,4-disubstituted-3,3-difluorotetrahydrofurans
38. Chiral sulfoxide controlled asymmetric additions to CN double bond. An efficient approach to stereochemically defined α-fluoroalkyl amino compounds
39. Fluorinated analogues of nojirimycin and mannojirimycin from a non-carbohydrate precursor
40. Palladium(II) complexes with keto-stabilized phosphonium, arsonium and pyridinium ylides
41. Carbon-13 nuclear magnetic resonance studies of some phosphonium, arsonium, sulfonium and pyridinium keto-stabilized salts, and ylides and of their palladium(II) complexes
42. Palladium(II) complexes with sulphonium ylides
43. Mild α-fluorination of enantiomerically pure β-ketosulfoxides by F-TEDA-BF 4
44. gem-Difluoro-cyclohexene and -cycloheptene derivatives through cyclization of gem-difluoroallyl radicals
45. Asymmetric synthesis of enantiomerically pure 4′-fluoroalkyl-2,3′-dideoxy nucleosides
46. Synthesis of optically pure α-methylene-γ-lactones from (+)-R-(4-methylphenyl)-alkylsulphoxides
47. Synthesis of optically pure α-halo-α′-sulphinyl-ketones
48. Sulfinimines of trifluoropyruvate: Novel intermediates for chiral non racemic α-trifluoromethyl α-amino acids
49. Synthesis of fluorinated chirons: Stereoselective oxirane formation by reaction of diazomethane on 1-fluoro-3-arylsulfinyl-2-propanone and ring opening by selected nucleophiles
50. Synthesis of four homochiral 3,4-dideoxy-3-fluoro-hexoses from a non-carbohydrate precursor
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