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We examine mechanical feedback mechanisms during the protostellar phase through jets and outflows. To do so, we make use of velocity-resolved CII observations at 158 $\mu$m taken with the SOFIA observatory. We identify CII emitting cavities at velocities ranging from 1-2 km s$^{-1}$ to 15 km s$^{-1}$ relative to the Veil shell ($v_\mathrm{LSR}$ = 13 km s$^{-1}$). The momentum and dynamical timescales of these cavities imply that the cavities in Orion were formed by fossil and active outflows from stars with luminosities ranging from 10$^3$ to 10$^5$ L$_\odot$. The momentum deposited during protostellar feedback is $\sim$1/6 of the momentum of the Veil shell deposited through winds from $\theta^1$ Ori C. By creating cavities, the fossil outflows may already have broken the Veil shell, and outflows from less massive stars may have made the Veil shell porous.

Gas cooling processes in the interstellar medium (ISM) are key to understanding how star-formation processes occur in galaxies. Far-infrared (FIR) fine-structure emission lines can be used as a tool to understand the gas conditions and trace the different phases of the ISM. We model the most important far-infrared (FIR) emission lines throughout cosmic time back to $z=6$ with cosmological hydrodynamical simulations. We study how different physical parameters, such as the interstellar radiation field (ISRF) and metallicity, impact the ISM phases traced by FIR line luminosities and connect those with the star-formation rate (SFR). We implement a physically motivated multi-phase model of the ISM by post-processing EAGLE cosmological simulation with Cloudy look-up tables. In this model, we assume four phases of the ISM: dense molecular gas, neutral atomic gas, diffuse ionised gas (DIG) and HII regions. Our model shows good agreement with the observed luminosity-SFR relation up to $z=6$ in the FIR emission lines analysed and we also provide linear fits. Our predictions also agree with observations in terms of diagnostic diagrams involving various line ratios. We find that [C II] is the best SFR tracer of the FIR lines even though it traces multiple ISM phases, while [O III] and [N II] can be used to understand the DIG-HII balance in the ionised phase. In addition, line ratios like [C II]/[O III] and [N II/[O I] are useful to trace parameters such as ISRF, metallicity and specific star-formation rate. These results help to interpret observations of FIR line emission from the local Universe to high-$z$ galaxies., Comment: 22 pages, 18 figures, 3 tables (plus appendix). Submitted to A&A

The role of feedback in the self-regulation of star formation is a fundamental question in astrophysics. The Orion Nebula is the nearest site of ongoing and recent massive star formation. It is a unique laboratory for the study of stellar feedback. Recent SOFIA [CII] 158 $\mu$m observations revealed an expanding bubble, the Veil shell, being powered by stellar winds and ionization feedback. We have identified a protrusion-like substructure in the Northwest portion of the Orion Veil Shell that may indicate additional feedback mechanisms that are highly directional. Our goal is to investigate the origin of the protrusion by quantifying its possible driving mechanisms. We use the [CII] 158 $\mu$m map of the Orion Nebula obtained with the upGREAT instrument onboard SOFIA. The spectral and spatial resolution of the observations are 0.3 km/s and 16 arcsec, respectively. We consider three possible origins for this protrusion: Fossil outflow cavities created by jets/outflows during the protostellar accretion phase, pre-existing clumpiness in the OMC-1 core, and the stellar wind during the main sequence phase. Based on the energetics and the morphology, we conclude that the northwestern part of the pre-existing cloud was locally perturbed by outflows ejected from massive protostars in the Trapezium cluster. This suggests that the protrusion of the Veil is the result of mechanical rather than radiative feedback. Furthermore, we argue that the location of the protrusion is a suitable place to break the Orion Veil owing to the photo-ablation from the walls of the protrusion. We conclude that the outflows of massive protostars can influence the morphology of the future \hii\,region and even cause breakages in the ionization front. Specifically, the interaction of stellar winds of main-sequence stars with the molecular core pre-processed by the protostellar jet is important., Comment: Accepted by A&A on Feb 9, 2022 (20 pages, 19 figures)

(abridged) Data and results from the WISH key program are summarized, designed to provide a legacy data set to address its physics and chemistry. WISH targeted ~80 sources along the two axes of luminosity and evolutionary stage: from low- to high-mass protostars and from pre-stellar cores to protoplanetary disks. Lines of H2O, HDO, OH, CO and [O I] were observed with the HIFI and PACS instruments, complemented by molecules that probe UV, X-ray or grain chemistry. Most of the far-infrared water emission from protostars is found to be compact, originating from warm outflowing and shocked gas at high density and temperature in at least two physical components. This gas is not probed by low-J CO lines, only by J>14. Water is a significant, but not dominant, coolant. Its abundance is universally low, of order H2O/H2=2E-6, pointing to shock and outflow cavity models that include UV radiation at 100-1000 times the ISRF. In cold quiescent pre-stellar cores and envelopes, the water abundance structure is accurately probed through velocity-resolved line profiles, confirming basic chemistry networks. The gaseous HDO/H2O ratio of 0.025, much higher than that of bulk ice, is representative of the outer photodesorbed ice layers and cold chemistry. Water abundances in the inner hot cores are high, but with variations from 5E-6 to 2E-4. Combined analyses of water gas and ice show that up to 50% of the oxygen budget may be missing, with possible explanations discussed. Water vapor emission from disks is weak, indicating that water ice is locked up in larger pebbles early on and that these pebbles have settled and drifted inward by the Class II stage. Quantitatively, many oceans of water ice are available. Extragalactic low-J H2O emission is mostly compact and collisionally excited. Prospects for future mid- to far-infrared missions are given., 58 pages, 39 figures, accepted for publication in A&A

Context. The study of prestellar cores is critical as they set the initial conditions in star formation and determine the final mass of the stellar object. To date, several hypotheses have described their gravitational collapse. Deriving the dynamical model that fits both the observed dust and the gas emission from such cores is therefore of great importance. Aims. We perform detailed line analysis and modeling of H₂D⁺ 1₁₀–1₁₁ and N₂H⁺ 4–3 emission at 372 GHz, using 2′ × 2′ maps (James Clerk Maxwell Telescope; JCMT). Our goal is to test the most prominent dynamical models by comparing the modeled gas kinematics and spatial distribution (H₂D⁺ and N₂H⁺) with observations toward four prestellar (L1544, L183, L694-2, L1517B) and one protostellar core (L1521f). Methods. We fit the line profiles at all offsets showing emission using single Gaussian distributions. We investigate how the line parameters (VLSR, FWHM and TA*) change with offset to examine the velocity field, the degree of nonthermal contributions to the line broadening, and the distribution of the material in these cores. To assess the thermal broadening, we derive the average gas kinetic temperature toward all cores using the non-LTE radiative transfer code RADEX. We perform a more detailed non-LTE radiative transfer modeling using RATRAN, where we compare the predicted spatial distribution and line profiles of H₂D⁺ and N₂H⁺ with observations toward all cores. To do so, we adopt the physical structure for each core predicted by three different dynamical models taken from literature: quasi-equilibrium Bonnor–Ebert sphere (QE-BES), singular isothermal sphere (SIS), and Larson–Penston (LP) flow. In addition, we compare these results to those of a static sphere, whose density and temperature profiles are based on the observed dust continuum. Lastly, we constrain the abundance profiles of H₂D⁺ and N₂H⁺ toward each core. Results. We find that variable nonthermal contributions (variations by a factor of 2.5) are required to explain the observed line width of both H₂D⁺ and N₂H⁺, while the nonthermal contributions are found to be 50% higher for N₂H⁺. The RADEX modeling results in average core column densities of ~9 × 10¹² cm⁻² for H₂D⁺ and N₂H⁺. The LP flow seems to be the dynamical model that can reproduce the observed spatial distribution and line profiles of H₂D⁺ on a global scale of prestellar cores, while the SIS model systematically and significantly overestimates the width of the line profiles and underestimates the line peak intensity. We find similar abundance profiles for the prestellar cores and the protostellar core. The typical abundances of H₂D⁺ vary between 10⁻⁹ and 10⁻¹⁰ for the inner 5000 au and drop by about an order of magnitude for the outer regions of the core (2 × 10⁻¹⁰–6 × 10⁻¹¹). In addition, a higher N₂H⁺ abundance by about a factor of 4 compared to H₂D⁺ is found toward the two cores with detected emission. The presence of N₂H⁺ 4–3 toward the protostellar core and toward one of the prestellar cores reflects the increasing densities as the core evolves. Conclusions. Our analysis provides an updated picture of the physical structure of prestellar cores. Although the dynamical models account for mass differences by up to a factor of 7, the velocity structure drives the shape of the line profiles, allowing for a robust comparison between the models. We find that the SIS model can be clearly excluded in explaining the gas emission toward the cores, but a larger sample is required to differentiate clearly between the LP flow, the QE-BES, and the static models. All models of collapse underestimate the intensity of the gas emission by up to several factors toward the only protostellar core in our sample, indicating that different dynamics take place in different evolutionary core stages. If the LP model is confirmed toward a larger sample of prestellar cores, it would indicate that they may form by compression or accretion of gas from larger scales. If the QE-BES model is confirmed, it means that quasi-hydrostatic cores can exist within turbulent ISM.

To understand how Phosphorus-bearing molecules are formed in star-forming regions, we have analysed ALMA observations of PN and PO towards the massive star-forming region AFGL 5142, combined with a new analysis of the data of the comet 67P/Churyumov-Gerasimenko taken with the ROSINA instrument onboard Rosetta. The ALMA maps show that the emission of PN and PO arises from several spots associated with low-velocity gas with narrow linewidths in the cavity walls of a bipolar outflow. PO is more abundant than PN in most of the spots, with the PO/PN ratio increasing as a function of the distance to the protostar. Our data favor a formation scenario in which shocks sputter phosphorus from the surface of dust grains, and gas-phase photochemistry induced by UV photons from the protostar allows efficient formation of the two species in the cavity walls. Our analysis of the ROSINA data has revealed that PO is the main carrier of P in the comet, with PO/PN>10. Since comets may have delivered a significant amount of prebiotic material to the early Earth, this finding suggests that PO could contribute significantly to the phosphorus reservoir during the dawn of our planet. There is evidence that PO was already in the cometary ices prior to the birth of the Sun, so the chemical budget of the comet might be inherited from the natal environment of the Solar System, which is thought to be a stellar cluster including also massive stars., Accepted in MNRAS (20 pages, 12 figures)

With the recent discovery of a dozen dusty star-forming galaxies and around 30 quasars at z>5 that are hyper-luminous in the infrared ($��$$L_{\rm IR}>10^{13}$ L$_{\odot}$, where $��$ is a lensing magnification factor), the possibility has opened up for SPICA, the proposed ESA M5 mid-/far-infrared mission, to extend its spectroscopic studies toward the epoch of reionization and beyond. In this paper, we examine the feasibility and scientific potential of such observations with SPICA's far-infrared spectrometer SAFARI, which will probe a spectral range (35-230 $��$m) that will be unexplored by ALMA and JWST. Our simulations show that SAFARI is capable of delivering good-quality spectra for hyper-luminous infrared galaxies (HyLIRGs) at z=5-10, allowing us to sample spectral features in the rest-frame mid-infrared and to investigate a host of key scientific issues, such as the relative importance of star formation versus AGN, the hardness of the radiation field, the level of chemical enrichment, and the properties of the molecular gas. From a broader perspective, SAFARI offers the potential to open up a new frontier in the study of the early Universe, providing access to uniquely powerful spectral features for probing first-generation objects, such as the key cooling lines of low-metallicity or metal-free forming galaxies (fine-structure and H2 lines) and emission features of solid compounds freshly synthesized by Population III supernovae. Ultimately, SAFARI's ability to explore the high-redshift Universe will be determined by the availability of sufficiently bright targets (whether intrinsically luminous or gravitationally lensed). With its launch expected around 2030, SPICA is ideally positioned to take full advantage of upcoming wide-field surveys such as LSST, SKA, Euclid, and WFIRST, which are likely to provide extraordinary targets for SAFARI., 24 pages, 8 figures, accepted for publication in PASA (SPICA special issue)

We present high angular resolution (similar to 0.2 '') continuum and molecular emission line Atacama Large Millimeter/sub-millimeter Array (ALMA) observations of G17.64+0.16 in Band 6 (220-230 GHz) taken as part of a campaign in search of circumstellar discs around (proto)-O-stars. At a resolution of similar to 400 au the main continuum core is essentially unresolved and isolated from other strong and compact emission peaks. We detect SiO (5-4) emission that is marginally resolved and elongated in a direction perpendicular to the large-scale outflow seen in the (CO)-C-13 (2-1) line using the main ALMA array in conjunction with the Atacama Compact Array (ACA). Morphologically, the SiO appears to represent a disc-like structure. Using parametric models we show that the position-velocity profile of the SiO is consistent with the Keplerian rotation of a disc around an object between 10 and 30M(circle dot) in mass, only if there is also radial expansion from a separate structure. The radial motion component can be interpreted as a disc wind from the disc surface. Models with a central stellar object mass between 20 and 30 M-circle dot are the most consistent with the stellar luminosity (1 x 10(5) L-circle dot) and indicative of an O-type star. The H30 alpha millimetre recombination line (231.9 GHz) is also detected, but spatially unresolved, and is indicative of a very compact, hot, ionised region co-spatial with the dust continuum core. The broad line-width of the H30 alpha emission (full-width-half-maximum = 81.9 km s(-1)) is not dominated by pressure-broadening but is consistent with underlying bulk motions. These velocities match those required for shocks to release silicon from dust grains into the gas phase. CH3CN and CH3OH thermal emission also shows two arc shaped plumes that curve away from the disc plane. Their coincidence with OH maser emission suggests that they could trace the inner working surfaces of a wide-angle wind driven by G17.64 which impacts the diffuse remnant natal cloud before being redirected into the large-scale outflow direction. Accounting for all observables, we suggest that G17.64 is consistent with a O-type young stellar object in the final stages of protostellar assembly, driving a wind, but that has not yet developed into a compact HII region. The existance and detection of the disc in G17.64 is likely related to its isolated and possibly more evolved nature, traits which may underpin discs in similar sources.

The SPICA mid and far-infrared telescope will address fundamental issues in our understanding of star formation and ISM physics in galaxies. A particular hallmark of SPICA is the outstanding sensitivity enabled by the cold telescope, optimized detectors, and wide instantaneous bandwidth throughout the mid- and far-infrared. The spectroscopic, imaging and polarimetric observations that SPICA will be able to collect will help in clarifying the complex physical mechanisms which underlie the baryon cycle of galaxies. In particular: (i) The access to a large suite of atomic and ionic fine-structure lines for large samples of galaxies will shed light on the origin of the observed spread in star formation rates within and between galaxies. (ii) Observations of HD rotational lines (out to $\sim$10 Mpc) and fine structure lines such as [CII] 158 $\mu$m (out to $\sim$100 Mpc) will clarify the main reservoirs of interstellar matter in galaxies, including phases where CO does not emit. (iii) Far-infrared spectroscopy of dust and ice features will address uncertainties in the mass and composition of dust in galaxies, and the contributions of supernovae to the interstellar dust budget will be quantified by photometry and monitoring of supernova remnants in nearby galaxies. (iv) Observations of far-infrared cooling lines such as [OI] 63 $\mu$m from star-forming molecular clouds in our Galaxy will evaluate the importance of shocks to dissipate turbulent energy. The paper concludes with requirements for the telescope and instruments, and recommendations for the observing strategy., Comment: Accepted for publication in PASA; 19 pages, 8 figures, 1 table

Protostellar evolution, following the formation of the protostar is becoming reasonably well characterized, but the evolution from a prestellar core to a protostar is not well known, although the first hydrostatic core (FHSC) must be a pivotal step. NGC 1333 IRAS 4C is a potentially very young object, that we directly compare with the nearby Class 0 IRAS 4A and IRAS 4B. Observational constraints are provided by spectral imaging from the JCMT Spectral Legacy Survey (330-373 GHz) and continuum and line observations from CARMA. We present integrated intensity and velocity maps of several species, including CO, H2CO and CH3OH. The velocity of an observed outflow, the degree of CO depletion, the deuteration of DCO+/HCO+ and gas kinetic temperatures are observational signatures that we present. We report differences between the three sources in four aspects: a) the kinetic temperature is much lower towards IRAS 4C, b) the line profiles of the detected species show strong outflow activity towards IRAS 4A and IRAS 4B but not towards IRAS 4C, c) the HCN/HNC is < 1 towards IRAS 4C, which confirms the cold nature of the source, d) the degree of CO depletion and the deuteration are the lowest towards the warmest of the sources, IRAS 4B. IRAS 4C seems to be in a different evolutionary state than the IRAS 4A and IRAS 4B sources. We can probably exclude the FHSC stage due to the relatively low Lsmm/Lbol (~6\%) and we investigate the earliest accretion phase of Class 0 stage and the transition between Class 0 to Class I. Our results do not show a consistent scenario for either case, with the major issue being the absence of outflow activity and the cold nature of IRAS 4C. The number of FHSC candidates in Perseus is ~10 times higher than current models predict, which suggests that the lifespan of these objects is greater than 1000 years, possibly due to an accretion rate lower than 4x10^-5 msun/yr., 19 pages, 18 figures, 3 tables; Accepted for publication in A&A

Water probes the dynamics in young stellar objects (YSOs) effectively, especially shocks in molecular outflows. It is a key molecule for exploring whether the physical properties of low-mass protostars can be extrapolated to massive YSOs. As part of the WISH key programme, we investigate the dynamics and the excitation conditions of shocks along the outflow cavity wall as function of source luminosity. Velocity-resolved Herschel-HIFI spectra of the H2O 988, 752, 1097 GHz and 12CO J=10-9, 16-15 lines were analysed for 52 YSOs with bolometric luminosities (L_bol) ranging from 10^5 L_sun. The profiles of the H2O lines are similar, indicating that they probe the same gas. We see two main Gaussian emission components in all YSOs: a broad component associated with non-dissociative shocks in the outflow cavity wall (cavity shocks) and a narrow component associated with quiescent envelope material. More than 60% of the total integrated intensity of the H2O lines (L_H2O) comes from the cavity shock component. The H2O line widths are similar for all YSOs, whereas those of 12CO 10-9 increase slightly with L_bol. The excitation analysis of the cavity shock component, performed with the non-LTE radiative transfer code RADEX, shows stronger 752 GHz emission for high-mass YSOs, likely due to pumping by an infrared radiation field. As previously found for CO, a strong correlation with slope unity is measured between log(L_H2O) and log(L_bol), which can be extrapolated to extragalactic sources. We conclude that the broad component of H2O and high-J CO lines originate in shocks in the outflow cavity walls for all YSOs, whereas lower-J CO transitions mostly trace entrained outflow gas. The higher UV field and turbulent motions in high-mass objects compared to their low-mass counterparts may explain the slightly different kinematical properties of 12CO 10-9 and H2O lines from low- to high-mass YSOs., Abridged abstract, 31 pages, 18 figures, 12 tables, accepted in Astronomy & Astrophysics

Context. Chemical fractionation reactions in the interstellar medium can result in molecular isotopologue abundance ratios that differ by many orders of magnitude from the isotopic abundance ratios. Understanding variations in the molecular abundance ratios through astronomical observations provides a new tool to sensitively probe the underlying physical conditions. Aims. Recently, we have introduced detailed isotopic chemistry into the KOSMA-τ model for photon-dominated regions (PDRs), which allows calculating abundances of carbon isotopologues as a function of PDR parameters. Radiative transfer computations then allow to predict the observed [C II]/[^(13)C II] line intensity ratio for specific geometries. Here, we compare these model predictions with new Herschel observations. Methods. We performed Herschel/HIFI observations of the [C II] 158 μm line in a number of PDRs. In all sources, we observed at least two hyperfine components of the [^(13)C II] transition, allowing determination of the [C II]/[^(13)C II] intensity ratio, using revised intrinsic hyperfine ratios. Comparing the observed line ratios with the predictions from the updated KOSMA-τ model, we identify conditions under which the chemical fractionation effects are important, and not masked by the high optical depth of the main isotopic line. Results. An observable enhancement of the [C II]/[^(13)C II] intensity ratio due to chemical fractionation depends mostly on the source geometry and velocity structure, and to a lesser extent on the gas density and radiation field strength. The enhancement is expected to be largest for PDR layers that are somewhat shielded from UV radiation, but not completely hidden behind a surface layer of optically thick [C II]. In our observations the [C II]/[^(13)C II] integrated line intensity ratio is always dominated by the optical depth of the main isotopic line. However, an enhanced intensity ratio is found for particular velocity components in several sources: in the red-shifted material in the ultracompact H II region Mon R2, in the wings of the turbulent line profile in the Orion Bar, and possibly in the blue wing in NGC 7023. Mapping of the [^(13)C II] lines in the Orion Bar gives a C^+ column density map, which confirms the temperature stratification of the C^+ layer, in agreement with the PDR models of this region. Conclusions. Carbon fractionation can be significant even in relatively warm PDRs, but a resulting enhanced [C II]/[^(13)C II] intensity ratio is only observable for special configurations. In most cases, a reduced [C II]/[^(13)C II] intensity ratio can be used instead to derive the [C II] optical depth, leading to reliable column density estimates that can be compared with PDR model predictions. The C^+ column densities show that, for all sources, at the position of the [C II] peak emission, the dominant fraction of the gas-phase carbon is in the form of C^+.

Models of pure gas-phase chemistry in well-shielded regions of molecular clouds predict relatively high levels of molecular oxygen, O2, and water, H2O. Contrary to expectation, the space missions SWAS and Odin found only very small amounts of water vapour and essentially no O2 in the dense star-forming interstellar medium. Only toward rho Oph A did Odin detect a weak line of O2 at 119 GHz in a beam size of 10 arcmin. A larger telescope aperture such as that of the Herschel Space Observatory is required to resolve the O2 emission and to pinpoint its origin. We use the Heterodyne Instrument for the Far Infrared aboard Herschel to obtain high resolution O2 spectra toward selected positions in rho Oph A. These data are analysed using standard techniques for O2 excitation and compared to recent PDR-like chemical cloud models. The 487.2GHz line was clearly detected toward all three observed positions in rho Oph A. In addition, an oversampled map of the 773.8GHz transition revealed the detection of the line in only half of the observed area. Based on their ratios, the temperature of the O2 emitting gas appears to vary quite substantially, with warm gas (> 50 K) adjacent to a much colder region, where temperatures are below 30 K. The exploited models predict O2 column densities to be sensitive to the prevailing dust temperatures, but rather insensitive to the temperatures of the gas. In agreement with these model, the observationally determined O2 column densities seem not to depend strongly on the derived gas temperatures, but fall into the range N(O2) = (3 to >6)e15/cm^2. Beam averaged O2 abundances are about 5e-8 relative to H2. Combining the HIFI data with earlier Odin observations yields a source size at 119 GHz of about 4 - 5 arcmin, encompassing the entire rho Oph A core., 10 pages, 8 figures intended for publication in A&A

Recently, we introduced detailed isotopic chemistry into the KOSMA-tau model for photon-dominated regions (PDRs) to give theoretical predictions for the abundance of the carbon isotopologues as a function of PDR parameters. Combined with radiative transfer computations for specific geometries, we estimated the possible intensity ratio of the [CII]/[13CII] lines. Here, we compare these predictions with new observations. We performed Herschel/HIFI observations of the [CII] 158micron line in a number of PDRs. In all sources we observed at least two hyperfine components of the [13CII] transition allowing to determine the [CII]/[13CII] intensity ratio, after some revision of the intrinsic hyperfine ratios. Comparing the intensity ratios with the results from the updated KOSMA-tau model, we identify cases dominated by chemical fractionation and cases dominated by the optical depth of the main isotopic line. An observable enhancement of the [CII]/[13CII] intensity ratio due to chemical fractionation depends mostly on geometry and velocity structure, and less on the gas density and radiation field. In our observations the [CII]/[13CII] ratio for the integrated line intensity was always dominated by the optical depth of the main isotopic line. However, an enhanced intensity ratio is found for particular velocity components in a few sources: the red-shifted material in the ultracompact HII region Mon R2, the wings of the turbulent profile in the Orion Bar, and possibly a blue wing in NGC7023. The mapping of the [13CII] lines in the Orion Bar allows to derive a C+ column density map confirming the temperature stratification of the C+ layer, in agreement with the chemical stratification of the Bar. The C+ column densities for all sources show that at the position of the [CII] peak emission, a dominant fraction of the gas-phase carbon is in the form of C+., Comment: Accepted for publication in Astronomy & Astrophysics

Embedded protostars interact with their natal cloud through shocks and irradiation. The ambient interstellar medium warms up, allowing icy grain mantles to evaporate and making different chemical routes in the gas phase available. Water then becomes one of the most abundant molecular species in the gas phase. The Herschel key program `Water in Star-Forming Regions with Herschel (WISH)' studies the excitation and chemistry of water around protostars. Hydroxyl (OH) is of the cornerstone species in the water chemistry network, because it is closely linked to both the formation and destruction of water through the OH + H2 leftrightarrow H2O + H reactions and photodissociation processes. This poster presents the first OH observation with resolved hyperfine structure at 163 μm of a star-forming region obtained using HIFI on Herschel. The OH triplet from the high-mass star-forming region W3 IRS5 is in emission, with the line profile revealing a narrow component on top of a broad feature. The broad component is attributed to outflow emission based on comparison with molecular lines of other species, whereas the narrow component is in agreement with radiative transfer results for a spherically symmetric envelope model. The resolved hyperfine structure allows us to constrain the excitation temperature and the OH column density in our models simultaneously. The derived OH/H2O ratios in the envelope are consistent with the current picture of the water chemistry. In the outer envelope (T 100 K), water is efficiently formed from OH and the OH/H2O ratio is therefore expected to drop significantly, which is consistent with the derived value of the order of 10-4. For the outflow, a lower limit of OH/H2O > 0.025 is obtained and can be explained with either a fast J-type shock or a slower UV irradiated C-type shock.

International audience; High-mass stars formation process is much less understood than the low-mass case: short timescales, high opacities and long distance to the sources challenge the study of young massive stars. The instruments on board the Heschel Space Observatory permit us to investigate molecular species at high spectral resolution in the sub-milimeter wavelengths. Water, one of the most abundant molecules in the Universe, might elucidate key episodes in the process of stellar birth and it may play a major role in the formation of high-mass stars. This contribution presents the first results of the Heschel Space Observatory key-program WISH (Water In Star forming regions with Herschel) concerning high-mass protostars. The program main purpose is to follow the process of star formation during the various stages using the water molecule as a physical diagnostic throughout the evolution. In general, we aim to adress the following questions: How does protostars interact with their environment ? How and where water is formed ? How is it transported from cloud to disk ? When and where water becomes a dominant cooling or heating agent ? We use the HIFI and PACS instruments to obtain maps and spectra of ~20 water lines in ~20 massive protostars spanning a large range in physical parameters, from pre-stellar cores to UCHII regions. I will review the status of the program and focus specifically on the spectroscopic results. I will show how powerful are the HIFI high-resolution spectral observations to resolve different physical source components such as the dense core, the outflows and the extended cold cloud around the high-mass object. We derive water abundances between 10-7 and 10-9 in the outer envelope. The abundance variations derived from our models suggest that different chemical mechanisms are at work on these scales (e.g. evaporation of water-rich icy grain mantles). The detection and derived abundance ratios for rare isotopologues will be discussed. Finally, a comparison in tems of degree of evolution will be done.

Within the Herschel key project "The Warm And Dense ISM" (WADI) we systematically observe a number of prominent photon-dominated regions (PDRs) to measure the impact of varying UV fields on the energy balance, the chemical and dynamical structure of heated molecular clouds.

Aims. Previous studies by the satellites SWAS and Odin provided stringent upper limits on the gas phase water abundance of dark clouds (x(H2O) < 7 × 10-9). We investigate the chemistry of water vapor in starless cores beyond the previous upper limits using the highly improved angular resolution and sensitivity of Herschel and measure the abundance of water vapor during evolutionary stages just preceding star formation.\ud Methods. High spectral resolution observations of the fundamental ortho water (o-H2O) transition (557 GHz) were carried out with the Heterodyne Instrument for the Far Infrared onboard Herschel toward two starless cores: Barnard 68 (hereafter B68), a Bok globule, and LDN 1544 (L1544), a prestellar core embedded in the Taurus molecular cloud complex. Detailed radiative transfer and chemical codes were used to analyze the data.\ud Results. The RMS in the brightness temperature measured for the B68 and L1544 spectra is 2.0 and 2.2 mK, respectively, in a velocity bin of 0.59 km s-1. The continuum level is 3.5 ± 0.2 mK in B68 and 11.4 ± 0.4 mK in L1544. No significant feature is detected in B68 and the 3σ upper limit is consistent with a column density of o-H2O N(o-H2O) < 2.5 × 1013 cm-2, or a fractional abundance x(o-H2O) < 1.3 × 10-9, more than an order of magnitude lower than the SWAS upper limit on this source. The L1544 spectrum shows an absorption feature at a 5σ level from which we obtain the first value of the o-H2O column density ever measured in dark clouds: N(o-H2O) = (8 ± 4) × 1012 cm-2. The corresponding fractional abundance is x(o-H2O) 5 × 10-9 at radii >7000 AU and 2 × 10-10 toward the center. The radiative transfer analysis shows that this is consistent with a x(o-H2O) profile peaking at 10-8, 0.1 pc away from the core center, where both freeze-out and photodissociation are negligible.\ud Conclusions. Herschel has provided the first measurement of water vapor in dark regions. Column densities of o-H2O are low, but prestellar cores such as L1544 (with their high central densities, strong continuum, and large envelopes) appear to be very promising tools to finally shed light on the solid/vapor balance of water in molecular clouds and oxygen chemistry in the earliest stages of star formation.

We report the first detection of chloronium, H2Cl+, in the interstellar medium, using the HIFI instrument aboard the Herschel Space Observatory. The 212–101 lines of ortho-HCl+ and ortho-HCl+ are detected in absorption towards NGC 6334I, and the 111–000 transition of para-HCl+ is detected in absorption towards NGC 6334I and Sgr B2(S). The H2Cl+ column densities are compared to those of the chemically-related species HCl. The derived HCl/H2Cl+ column density ratios, ~1–10, are within the range predicted by models of diffuse and dense photon dominated regions (PDRs). However, the observed H2Cl+ column densities, in excess of 1013 cm-2, are significantly higher than the model predictions. Our observations demonstrate the outstanding spectroscopic capabilities of HIFI for detecting new interstellar molecules and providing key constraints for astrochemical models.

The integrated line intensities in Table 1 of Van der Wiel et al. (2009, A&A 498, 161) should be modified due to an error in the adopted channel widths: values are reduced by similar to 20% for C2H, H2CO and SO, reduced by a factor similar to 5 for (CO)-O-18 and HCN, and increased by similar to 40% for (CO)-C-13. Derived column densities for C2H, H2CO and SO are decreased by similar to 20%; for (CO)-O-18 it is increased by similar to 40%. Corrected abundance values of C2H, H2CO and SO are a factor

Using Herschel's HIFI instrument we have observed [C II] along a cut through S140 and high-J transitions of CO and HCO+ at two positions on the cut, corresponding to the externally irradiated ionization front and the embedded massive star forming core IRS1. The HIFI data were combined with available ground-based observations and modeled using the KOSMA-tau model for photon dominated regions. Here we derive the physical conditions in S140 and in particular the origin of [C II] emission around IRS1. We identify three distinct regions of [C II] emission from the cut, one close to the embedded source IRS1, one associated with the ionization front and one further into the cloud. The line emission can be understood in terms of a clumpy model of photon-dominated regions. At the position of IRS1, we identify at least two distinct components contributing to the [C II] emission, one of them a small, hot component, which can possibly be identified with the irradiated outflow walls. This is consistent with the fact that the [C II] peak at IRS1 coincides with shocked H2 emission at the edges of the outflow cavity. We note that previously available observations of IRS1 can be well reproduced by a single-component KOSMA-tau model. Thus it is HIFI's unprecedented spatial and spectral resolution, as well as its sensitivity which has allowed us to uncover an additional hot gas component in the S140 region., Comment: accepted for publication in Astronomy and Astrophysics (HIFI special issue)

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International audience; Aims. We present a survey of the ortho-H2D+ (1{1,0}-1{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the study of the chemistry, and the evolutionary and dynamical status of low-mass dense cores. Methods: The derived ortho-H2D+ column densities (N(ortho-H2D+)) are compared with predictions from simple chemical models of centrally concentrated cloud cores. Results: The line is detected in 7 starless cores and in 4 protostellar cores. N(ortho-H2D+) ranges between 2 and 40 × 1012 cm-2 in starless cores and between 2 and 9 × 1012 cm-2 in protostellar cores. The brightest lines are detected toward the densest and most centrally concentrated starless cores, where the CO depletion factor and the deuterium fractionation are also largest. The large scatter observed in plots of N(ortho-H2D+) vs. the observed deuterium fractionation and vs. the CO depletion factor is likely to be due to variations in the ortho-to-para (o/p) ratio of H2D+ from >0.5 for T_kin < 10 K gas in pre-stellar cores to ≃0.03 (consistent with T_kin ≃ 15 K for protostellar cores). The two Ophiuchus cores in our sample also require a relatively low o/p ratio (≃0.3). Other parameters, including the cosmic-ray ionization rate, the CO depletion factor (or, more in general, the depletion factor of neutral species), the volume density, the fraction of dust grains and PAHs also largely affect the ortho-H2D+ abundance. In particular, gas temperatures above 15 K, low CO depletion factors and large abundance of negatively charged small dust grains or PAHs drastically reduce the deuterium fractionations to values inconsistent with those observed toward pre-stellar and protostellar cores. The most deuterated and H2D+-rich objects (L 429, L 1544, L 694-2 and L 183) are reproduced by chemical models of centrally concentrated (central densties ≃106 cm-3) cores with chemical ages between 104 and 106 yr. Upper limits of the para-H3O+(11^-21^+) and para-D2H+ (1{1,0}-1{0,1}) lines are also given. The upper limit to the para-H3O+ fractional abundance is ≃10-8 and we find an upper limit to the para-D2H+/ortho-H2D+ column density ratio equal to 1, consistent with chemical model predictions of high density (2 × 106 cm-3) and low temperature (T_kin < 10 K) clouds. Conclusions: Our results point out the need for better determinations of temperature and density profiles in dense cores as well as for observations of para-H2D+.

CONTEXT: The chemistry in the inner few thousand AU of accreting envelopes around young stellar objects is predicted to vary greatly with far-UV and X-ray irradiation by the central star. Aim We search for molecular tracers of high-energy irradiation by the protostar in the hot inner envelope. METHODS: The Submillimeter Array (SMA) has observed the high-mass star forming region AFGL 2591 in lines of CS, SO, HCN, HCN(v2=1), and HC15N with 0.6" resolution at 350 GHz probing radial scales of 600-3500 AU for an assumed distance of 1 kpc. The SMA observations are compared with the predictions of a chemical model fitted to previous single-dish observations. RESULTS: The CS and SO main peaks are extended in space at the FWHM level, as predicted in the model assuming protostellar X-rays. However, the main peak sizes are found smaller than modeled by nearly a factor of 2. On the other hand, the lines of CS, HCN, and HC15N, but not SO and HCN(v2=1), show pedestal emissions at radii of about 3500 AU that are not predicted. All lines except SO show a secondary peak within the approaching outflow cone. A dip or null in the visibilities caused by a sharp decrease in abundance with increasing radius is not observed in CS and only tentatively in SO. CONCLUSIONS: The emission of protostellar X-rays is supported by the good fit of the modeled SO and CS amplitude visibilities including an extended main peak in CS. The broad pedestals can be interpreted by far-UV irradiation in a spherically non-symmetric geometry, possibly comprising outflow walls on scales of 3500 -- 7000 AU. The extended CS and SO main peaks suggest sulfur evaporation near the 100 K temperature radius., Astronomy and Astrophysics, in press

The cosmic-ray ionization rate (zeta) of dense molecular clouds is a key parameter for their dynamics and chemistry. Variations of zeta are well established, but it is unclear if these are related to source column density or to Galactic location. Using the APEX telescope, we have mapped the 364 GHz line of H3O+ in the Sgr B2 region and observed the 307 GHz line at selected positions. With the IRAM 30-m telescope we have observed the 203 GHz line of H2O-18 at the same positions. Strong H3O+ emission is detected over a ~3x2 pc region, indicating H3O+ column densities of 10^15 - 10^16 cm^-2 in an 18" beam. The H3O+ abundance of ~3 x 10^-9 and H3O+/H2O ratio of ~1/50 in the Sgr B2 envelope are consistent with models with zeta ~4 x 10^-16 s^-1, 3x lower than derived from H3+ observations toward Sgr A, but 10x that of local dense clouds. The ionization rates of interstellar clouds thus seem to be to first order determined by the ambient cosmic-ray flux, while propagation effects cause a factor of ~3 decrease from diffuse to dense clouds., Accepted by A&A Letters (APEX special issue); four A4 pages, two figures

The presence of H2D+ in dense cloud cores underlies ion-molecule reactions that strongly enhance the deuterium fractionation of many molecular species. We determine the H2D+ abundance in one starless core, Barnard 68, that has a particularly well established physical, chemical, and dynamical structure. We observed the ortho-H2D+ ground-state line 1_10-1_11, the N2H+ J=4-3 line, and the H13CO+ 4-3 line with the APEX telescope. We report the probable detection of the o-H2D+ line at an intensity Tmb=0.22 +- 0.08 K and exclusively thermal line width, and find only upper limits to the N2H+ 4-3 and H13CO+ 4-3 intensities. Within the uncertainties in the chemical reaction rates and the collisional excitation rates, chemical model calculations and excitation simulations reproduce the observed intensities and that of o-H2D+ in particular., APEX A&A special issue, accepted

Aims: Our goal is to set constraints on the evolutionary state of the dense core Cha-MMS1 in the Chamaeleon I molecular cloud. Methods: We analyze molecular line observations carried out with the new submillimeter telescope APEX. We look for outflow signatures around the dense core and probe its chemical structure, which we compare to predictions of models of gas-phase chemistry. We also use the public database of the Spitzer Space Telescope (SST) to compare Cha-MMS1 with the two Class 0 protostars IRAM 04191 and L1521F, which are at the same distance. Results: We measure a large deuterium fractionation for N2H+ (11 +/- 3 %), intermediate between the prestellar core L1544 and the very young Class 0 protostar L1521F. It is larger than for HCO+ (2.5 +/- 0.9 %), which is probably the result of depletion removing HCO+ from the high-density inner region. Our CO(3-2) map reveals the presence of a bipolar outflow driven by the Class I protostar Ced 110 IRS 4 but we do not find evidence for an outflow powered by Cha-MMS1. We also report the detection of Cha-MMS1 at 24, 70 and 160 microns by the instrument MIPS of the SST, at a level nearly an order of magnitude lower than IRAM 04191 and L1521F. Conclusions: Cha-MMS1 appears to have already formed a compact object, either the first hydrostatic core at the very end of the prestellar phase, or an extremely young protostar that has not yet powered any outflow, at the very beginning of the Class 0 accretion phase., Accepted by Astronomy & Astrophysics as a letter, to appear in the special issue on the APEX first results

Stars form in the densest, coldest, most quiescent regions of molecular clouds. Molecules provide the only probes which can reveal the dynamics, physics, chemistry and evolution of these regions, but our understanding of the molecular inventory of sources and how this is related to their physical state and evolution is rudimentary and incomplete. The Spectral Legacy Survey (SLS) is one of seven surveys recently approved by the JCMT Board. Starting in 2007, the SLS will produce a spectral imaging survey of the content and distribution of all the molecules detected in the 345 GHz atmospheric window (between 332 GHz and 373 GHz) towards a sample of 5 sources. Our intended targets are: a low mass core (NGC1333 IRAS4), 3 high mass cores spanning a range of star forming environments and evolutionary states (W49, AFGL2591, and IRAS20126), and a PDR (the Orion Bar). The SLS will use the unique spectral imaging capabilities of HARP-B/ACSIS to study the molecular inventory and the physical structure of these objects, which span different evolutionary stages and physical environments, to probe their evolution during the star formation process. As its name suggests, the SLS will provide a lasting data legacy from the JCMT that is intended to benefit the entire astronomical community. As such, the entire data set (including calibrated spectral datacubes, maps of molecular emission, line identifications, and calculations of the gas temperature and column density) will be publicly available., Comment: 34 pages, 1 figure - Accepted to PASP

We have detected the 372 GHz line of ortho-H2D+ towards the pre-stellar core L1544. The strongest emission (T_mb ~ 1 K) occurs at the peak of the millimeter continuum emission, while measurements at offset positions indicate that H2D+ is confined within ~ 20 arcsec, where CO is highly depleted. The derived H2D+ abundance of ~ 10^{-9} is comparable with previous estimates of the electron abundance in the core, which suggests that H2D+ is the main molecular ion in the central 20 arcsec (2800 AU) of L1544. This confirms the expectations that H2D+ is dramatically enhanced in gas depleted of molecules other than H2. The measured abundance even exceeds the present model predictions by about a factor ten. One possibility is that all CNO-bearing neutral species, including atomic oxygen, are almost completely (> 98%) frozen within a radius of ~2800 AU., A&A Letters, in press

This review covers hot cores in the context of high-mass star formation. After giving an overview of chemical processes and diversity during high-mass star formation, it reviews the `warm envelope' phase which probably precedes the formation of hot cores. Some recent determinations of the cosmic-ray ionization rate are discussed, as well as recent evidence for hot cores around low-mass stars. Routes for future hot core research are outlined., Comment: 8 pages, 1 figure; to appear in the Proceeding of IAU Symposium 221, Star Formation at High Angular Resolution, Editors M. Burton, R. Jayawardhana & T. Bourke, Astronomical Society of the Pacific

Molecular line data for the rotational transitions of a number of astrophysically interesting species have been collected and are made publically available through the www. These data, including energy levels, statistical weights, Einstein A-coefficients and collisional rate coefficients, are essential input for non-LTE molecular radiative transfer programs. A computer program for performing statistical equilibrium calculations is made publically available for use as well. This database should form an important tool in analyzing observations from current and future infrared and (sub)millimetre telescopes., To appear in the proceedings of the conference "Chemistry as a Diagnostic of Star Formation", University of Waterloo, Canada, 21-23 August 2002

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To understand how Phosphorus-bearing molecules are formed in star-forming regions, we have analysed ALMA observations of PN and PO towards the massive star-forming region AFGL 5142, combined with a new analysis of the data of the comet 67P/Churyumov-Gerasimenko taken with the ROSINA instrument onboard Rosetta. The ALMA maps show that the emission of PN and PO arises from several spots associated with low-velocity gas with narrow linewidths in the cavity walls of a bipolar outflow. PO is more abundant than PN in most of the spots, with the PO/PN ratio increasing as a function of the distance to the protostar. Our data favor a formation scenario in which shocks sputter phosphorus from the surface of dust grains, and gas-phase photochemistry induced by UV photons from the protostar allows efficient formation of the two species in the cavity walls. Our analysis of the ROSINA data has revealed that PO is the main carrier of P in the comet, with PO/PN>10. Since comets may have delivered a significant amount of prebiotic material to the early Earth, this finding suggests that PO could contribute significantly to the phosphorus reservoir during the dawn of our planet. There is evidence that PO was already in the cometary ices prior to the birth of the Sun, so the chemical budget of the comet might be inherited from the natal environment of the Solar System, which is thought to be a stellar cluster including also massive stars.

High-mass stars form in much richer environments than those associated with isolated low-mass stars, and once they reach a certain mass, produce ionised (HII) regions. The formation of these pockets of ionised gas are unique to the formation of high-mass stars (M $>8$ M$_\odot$), and present an excellent opportunity to study the final stages of accretion, which could include accretion through the HII region itself. This study of the dynamics of the gas on both sides of these ionisation boundaries in very young HII regions aims to quantify the relationship between the HII regions and their immediate environments.We present high-resolution ($\sim$ 0.5$"$) ALMA observations of nine HII regions selected from the Red MSX Source (RMS) survey with compact radio emission and bolometric luminosities greater than 10$^4$ L$_\odot$. We focus on the initial presentation of the data, including initial results from the radio recombination line H29$\alpha$, some complementary molecules, and the 256 GHz continuum emission. Of the six (out of nine) regions with H29$\alpha$ detections, two appear to have cometary morphologies with velocity gradients across them, and two appear more spherical with velocity gradients suggestive of infalling ionised gas. The remaining two were either observed at low resolution or had signals that were too weak to draw robust conclusions. We also present a description of the interactions between the ionised and molecular gas (as traced by CS (J=5-4)), often (but not always) finding theHII region had cleared its immediate vicinity of molecules. Of our sample of nine, the observations of the two clusters expected to have the youngest HII regions (from previous radio observations) are suggestive of having infalling motions in the H29$\alpha$ emission, which could be indicative of late stage accretion onto the stars despite the presence of an HII region., Comment: Accepted for publication in A&A. 25 pages, 15 figures, 9 tables, with Table A.2 made available electronically via the CDS