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Over the past decade, the emission standards and fuel standards in Beijing have been upgraded twice, and the vehicle structure has been improved by accelerating the elimination of 2.95 million old vehicles. Through the formulation and implementation of these policies, the emissions of carbon monoxide (CO), volatile organic compounds (VOCs), nitrogen oxides (NO

A general feature in the diurnal cycle of atmospheric ammonia (NH

Based on the current air pollution control and CO2 emission reduction policies, this study analyzed the energy structure, number of motor vehicles and nonroad mobile machinery, energy consumption and pollutant emissions in Beijing. Furthermore, the diesel consumption characteristics and challenges for emission reduction in key fields were investigated, such as medium- and heavy-duty diesel trucks, long-distance passenger and tourist diesel vehicles, and nonroad machinery, which are areas with difficult-to-reduce diesel consumption. Control targets and measures for total diesel consumption were also proposed. The results indicated that the higher diesel consumption per unit area in Beijing is related to the larger passenger car and freight truck populations. In recent decades, the number of diesel vehicles has increased, the vehicle type structure has been optimized, the proportion of vehicles with high emission standards has increased, and the absolute pollutant emissions have decreased. Among these, nitrogen oxides (NOx), fine particulate matter (PM2.5) and volatile organic compound (VOC) emissions of different models decreased by 39.5%, 75.3% and 42.8%, respectively, while carbon dioxide (CO2) emissions from diesel combustion decreased by 32%. Moreover, medium and large passenger vehicles, medium- and heavy-duty trucks and construction machinery are the main contributors to diesel consumption. These vehicle types are also difficult to control and reduce, and their replacement by new-energy vehicles is relatively limited. The main control measures for diesel consumption are as follows. First, a green transportation mode can be adopted for goods that can be converted from roads to railways. Second, fuel consumption reduction for nonroad mobile machinery can be realized by tightening fuel consumption limits, setting appropriate maximum retirement life, establishing low- or ultralow-emission zones, and establishing demonstration plots for electric vehicle (EV) substitution for mobile machinery. To improve the air quality and take the lead in carbon neutrality in the future, Beijing must further accelerate the energy structure adjustment and the development of new-energy vehicles in the transportation sector. Carbon neutralization is an important opportunity for diesel consumption reduction, and the synergistic control of atmospheric pollution and carbon emissions from diesel combustion must be strengthened.

The promulgation and implementation of the national and Beijing municipal standards for air pollutants emitted from crematoriums has effectively alleviated the problem of “black smoke” in crematoriums, but noticeable odor in crematoriums remains. We determined the level of odor emissions in crematoriums by monitoring the odor concentrations of cremators, incinerators, and cremation workshops in five crematoriums in Beijing. Subsequently, we analyzed the major contributing factors to the odor level and proposed control measures. A high odor concentration in crematoriums was observed; two different mechanisms were proposed to explain this finding. First, poor ventilation conditions in workshops and inadequate airtightness of equipment resulted in dimensionless concentrations of unorganized odor emissions in the workshops ranging from 97 to 732, with an average of 504, which is much higher than the standard level of 20. Second, the postprocessing facilities used in cremation sites produce poor odor removal, which, coupled with fuel usage and unregulated operations, led to high concentrations of organized odor emissions ranging from 231 to 1303 (910 on average) for cremators and incinerators. The odor emissions of cremators and incinerators meet the Integrated Emission Standards of Air Pollutants (DB11-501-2017), which are suitable for industries containing industrial kilns but not for crematoriums. The odor emissions in crematoriums are lower than those emitted from industries, such as fiber manufacturing and activated carbon processing. However, the unique geographical locations of crematoriums, high population density, and high exposure risk to local residents necessitate strengthening the management and control of odor emissions from crematoriums. To further address the problem of odor emissions from crematoriums in Beijing, further clarification and tightening of industry standards for the concentration limits of organized and unorganized odor emissions is recommended. Crematoriums will thus be prompted to increase odor control in workshops and adopt and improve deodorization facilities, including the installation and application of treatment facilities, such as adsorption and biological control.

Non-road mobile machinery (NRMM), mainly construction machinery, has a high emission intensity of air pollutants, significantly impacting urban air quality. Most previous estimates of NRMM emissions have employed a top-down approach mainly based on estimates of energy consumption, leading to large uncertainties. This study uses the information code registration data specified in the latest regulations to establish a bottom-up method for emission accounting to more precisely identify the characteristics of air pollutant emissions from construction machinery in Beijing in 2020. Moreover, the study evaluates the effectiveness of the implementation of the corresponding control measures in conjunction with the current situation of pollution control of NRMM in Beijing. The results show the following: (1) Based on the information code registration data, there are 37,000-based fuel construction machines, with excavators accounting for the largest proportion (56%), loaders and forklifts also accounting for large proportions (19% and 15%, respectively), representing the main types of construction machinery. (2) Information code registration data better reflect the actual situation of construction machinery emissions than the top-down method; the emissions of the main air pollutants NOx, PM

Serum P1NP, one of the important biomarkers for bone turnover, is commonly used for the prediction of bone fracture and the prognosis of osteoporosis after therapy. We developed a P1NP chemiluminescence assay and evaluated changes in bone metabolism markers in lung transplant patients. The screened 2 P1NP antibodies with constructed antigens and α-1 chain antigens expressed by the Corynebacterium glutamate expression system were applied into assay development. The assay performance was evaluated to examine the reliability. A normal Q-Q plot was used to establish male reference interval. Changes of bone metabolism markers before and after lung transplantation in 19 patients were evaluated. The linear factor R of P1NP reagent was greater than 0.99. The limit of detection was 3.32 ng/ml. The precision of the three batches of P1NP reagents was lower than 8%. Method comparison with Roche P1NP reagent showed that the correlation coefficient R2 was 0.91. In the monitoring of bone mass in a short time, bone metabolism markers can better indicate the change of bone mass, while the traditional bone mineral density detection is lagging behind the bone metabolism markers. P1NP and β-CrossLap to bone mass change in patients after lung transplantation, and P1NP and β-CrossLap are very good clinical markers for bone mass monitoring.

Non-road construction equipment (NRCE) has become a crucial contributor to urban air pollution. However, the current research on NRCE is still in its infancy, and the understanding of its pollutant emissions is not yet clear. In this study, multi-pollutant (CO, HC, NOx, PM

Road traffic constitutes a major source of air pollutants in urban Beijing, which are responsible for substantial premature mortality. A series of policies and regulations has led to appreciable traffic emission reductions in recent decades. To shed light on long-term (2014-2020) roadside air pollution and assess the efficacy of traffic control measures and their effects on public health, this study quantitatively evaluated changes in the concentrations of six key air pollutants (PM

Objective. Diabetes is a growing global public health concern with many significant disease complications. Multiple studies show that bone turnover markers (BTMs) are decreased in diabetes patients, indicating impaired bone metabolism in diabetes patients. A recent study also showed that in diabetes patients, BTMs are correlated with urine albumin to creatinine ratio, an indicator of nephropathy. However, whether BTMs are correlated with estimated glomerular filtration rate (eGFR) in diabetes remains unknown. This retrospective study accessed correlations between serum BTMs and eGFR in Chinese patients with diabetes and compare levels of BTMs and eGFR between diabetic patients and healthy individuals. Methods. This study analyzed data from 221 diabetic patients (include type1 and type 2 diabetes) and 155 healthy individuals. Serum BTM levels and eGFR were compared between diabetic patients and healthy individuals. Pearson correlation analysis was used to assess correlations between BTMs and eGFR. Multiple logistic regression analysis adjusted for gender and age was performed to measure odd ratio (OR) and 95% confidence interval (95% CI) of BTMs on diabetes. Results. Patients with diabetes had significant lower 25-hydroxyvitamin D (25(OH)D) levels ( 15.07 ± 6.20 ng / mL ) than healthy group ( 17.89 ± 6.41 ng / mL ) ( P < 0.05 ). For patients with diabetes, eGFR was negatively correlated with osteocalcin (OC) ( r = − 0.434 , P < 0.05 ), procollagen type 1 intact N-terminal propeptide (P1NP) ( r = − 0.350 , P < 0.05 ), and β-carboxy-terminal cross-linking telopeptide of type I collagen (β-CTX) ( r = − 0.179 , P < 0.05 ) levels. For healthy people, eGFR was negatively correlated with 25(OH)D ( r = − 0.290 , P < 0.05 ) levels. Multiple logistic regression analysis adjusted for age and gender (mean age of diabetes was 64.9 years and the percentage of female was 66.9%, mean age of healthy people was 48.4 years and the percentage of female was 37.4%) showed that 25(OH)D ( OR = 0.909 , 95 % CI = 0.862 − 0.959 , P < 0.05 ) was protective factors for diabetes. Conclusions. In the stage of diabetic nephropathy, bone turnover may accelerate. It is important to detect BTMs in the stage of diabetic nephropathy.

Diesel-fired combustion is one of the main sources of air pollution in the world. In this study, to better understand the energy consumption and main air pollutant emissions of diesel-fired combustion, a practical investigation and historical data analyses were conducted to determine the variations and driving forces of diesel consumption, the distribution of diesel consumption, and the contribution of emissions among various industries. Based on the results of this study, future control measures can be proposed for diesel-fired combustion. The results show that economic development led to an increase in the total volume of passengers and freight transportation, and the number of diesel vehicles increased from 0.16 million in 2009 to 0.25 million in 2018. However, diesel consumption in Beijing decreased from 2.4 Mt in 2009 to 1.8 Mt in 2018 due to the dominant driving forces, such as structural optimization of the diesel vehicle fleet and stricter limit standards for single-vehicle fuel consumption. The use of diesel vehicles in the logistics and transportation industries and the use of diesel-fired machinery in the construction industry were the two main sources of diesel consumption, accounting for 55% and 23% of the total, respectively. The main air pollutant emissions from diesel-fired combustion from 2009 to 2018 first increased and then decreased, while the NOX emissions peaked at 74,800 tons in 2014, which was affected by the structural optimization of the vehicle fleet and the elimination of old diesel trucks. The emissions finally decreased to 54,000 tons in 2018, which was approximately 89% of the amount in 2009. However, the continuously increasing contribution of diesel combustion to the total emissions requires more attention. The electrification of diesel vehicles and the structural upgrading of diesel vehicles have played important roles in mitigating the emissions of diesel combustion. Our study suggests that consumption control targets should be set, reduction plans for key industries such as the logistics and transportation, construction, and tourism industries should be developed, and low-emission zones should be created to promote the elimination and updating of low-emission diesel vehicles and machinery.

To explore high-resolution temporal variation characteristics of atmospheric metal elements concentration and more accurate pollution sources apportionment, online monitoring of metal elements in PM

The Beijing government initiated the Clean Air Action Plan (CAAP) in 2013. Through a series of actions to control air pollution, the emissions of major atmospheric pollutants are reduced to improve urban air quality. In order to evaluate the effectiveness of control measures taken to mitigate atmospheric pollution, we investigated and analyzed the implementation of the CAAP in Beijing from 2013 to 2017, estimating the corresponding reduction in emissions of major air pollutants. The contribution of different control measures to the improvement of air quality was quantified and the experiences of managing air pollution were summarized, which provided references for the continuous improvement of air quality in Beijing and the surrounding areas. The results showed that the emission of SO2, NOX, PM10, PM2.5, and VOCs from air pollution source have been decreased by 119,924, 116,091, 116,810, 46,652, and 97,267 tons after the implementation of the CAAP. The sum of these five air pollutants emissions have been reduced by 39% in 2017 compared with 2013, the largest decrease in SO2 emissions was 87%, which was related to the vigorous control on coal-fired combustion. The control measure with the greatest contribution to decreasing the ambient PM2.5 concentration was the clean energy transformation of coal-fired power plants, which contributed 27% of the total reduced concentration and 6.1 &mu, g/m&sup3, of the average PM2.5 concentration reduction in Beijing. Clean Residential coal use also significantly decreased the PM2.5 concentration by 5.4 &mu, which was 23% of the total reduction. In addition, the industrial restructuring and the management of automotive vehicle use and dust could also contribute to efficiently reducing the PM2.5 concentration by 4.0, 3.2, and 2.3 &mu, or 17%, 14%, and 10% of the total reduction, respectively. Due to the implementation of control measures of Clean Air Action Plan, the energy and industrial structure of Beijing have been adjusted and optimized, leading to the reduction of pollutant emissions, which is the secret of urban long-term air quality improvement.

Severe hazes occurred during 2016–2017 winter manifested winter haze was still a tough challenge in Beijing since the unprecedented haze in January 2013. Three haze episodes were identified from December 15, 2016 to January 15, 2017 in Beijing: the Red-Alert episode, the mixed haze-dust episode and the longest and heaviest Cross 2017 New Year's Haze episode. We analyzed the chemical components (water-soluble inorganic ions, carbonaceous components and trace elements) of multi-size airborne particles (PM1, PM2.5, PM10) samples, as well as the associated gaseous pollutants and meteorological parameters. Compared with the well-documented severe haze in January 2013, 2016–2017 winter haze was characterized by more stagnant synoptic conditions, sustained accumulation growth of PM enhanced by secondary reactions and regional contribution, as well as prominent fine particles mainly constituted by high concentrations of carbonaceous aerosol, secondary inorganic ions and anthropogenic elements. With strict pollution control measures since the enacting of Clean Air Action Plan in 2013, ambient concentrations of SO2, as well as SO42− and most anthropogenic elements in PM2.5 have decreased, whereas N O 3 − and N H 4 + concentration in PM2.5 increased by as high as 77.9% and 47.3% respectively compared with January 2013. The ratios of N O 3 − / S O 4 2 − in PM1, PM2.5, PM10 were higher than 1.0 no matter during normal period or haze period, totally different with the results in January 2013, which suggested the increased relative contribution from mobile sources and decreased contribution from coal combustion in Beijing. Nitrate and its precursors had become major concerns during winter haze in Beijing, although the rapid growth of sulfate still played an important role in the formation and evolution of extremely heavy haze events. Under ammonium-rich and high relative humidity conditions, N O 3 − was thought to mainly be produced by enhanced heterogeneous reactions. To prevent Beijing winter haze effectively, it's quite crucial to cut NOx, NH3, SO2 and VOCs emissions simultaneously and strengthen regional cooperation on air pollution control.

Cancer in human society is one of the most problematic health issue responsible for outnumbered deaths worldwide. The consumption of developed NPs in cancer diagnosis is a rapidly emerging field of bio-medical nanotechnology. Recent years, greener synthesized metal oxide hybrid nanoparticles have attracted great attention in cytotoxicity to different cancer therapy. Herein, we report that Duchesnea indica plant mediated green synthesis plant extract mediated Zn doped CuO (Zn/CuO) nanoparticles (NPs) prepared by hydrothermal method and these physico-chemical properties were characterized by XRD, UV-DRS, FTIR, and SEM with EDAX analytical techniques. The XRD pattern findings indicated that the crystal structure of the base CuO matrix are not distorted by the substitution of Cu2+ (0.73 A) ions by Zn2+ (0.65 A) ions. The average crystallite size of undoped and Zn/CuO NPs samples are found to be in between the range of 23 to 36 nm. And we can see that the Zn/CuO NPs are large aggregates, containing small particles with sizes of 100–300 nm with spherical shaped morphology by SEM and TEM microscopic images. The normal cell viability and cancer cell inhibition results on A-498 cancer cells and also normal human epithelial cells exhibited that no significant changes in the cell viability with normal kidney epithelial cells and doped NPs given excellent cell inhibition treated on A-498 kidney tumor cells.

In the past decade, due to the management policies and coal combustion controls in Beijing, the consumption of natural gas has increased gradually. Nevertheless, the research on the emission characteristics of gaseous pollutants emitted from gas-fired industrial boilers, especially considering the influence of low nitrogen (low-NOx) retrofit policy of gas boilers, is scarcely. In this study, based on literature and field investigations, onsite measurements of NOx, CO, NH3 and VOCs (Volatile Organic Compounds) emissions from gas-fired industrial boilers as well as the key factors that affected the emission of gaseous pollutants were discussed. Category-specific emission factors (EFs) of NOx, CO, NH3 and VOCs were obtained from the field measurements of 1107 “low-NOx” retrofitted and unabated gas-fired industrial boilers. Our results showed that operating load and control measures were the two key factors affecting the formation of gaseous pollutants. The EFs of NOx (EFNOx) and CO (EFCO) of atmospheric combustion boilers (ACBs) were much higher than the EFs of chamber combustion boilers (CCBs). The total emissions of NOx, CO, NH3 and VOCs from gas-fired industrial boilers in Beijing in the year of 2015 were estimated at 10489.6 t, 3272.8 t, 196.4 t and 235.4 t, respectively. Alkanes, BTEX, oxygenated VOCs and non-reactive organic matter were the four main chemical components of VOCs. As for the spatial distributions, the emissions of NOx, CO, NH3 and VOCs from gas-fired industrial boilers in Beijing were predominantly concentrated in central six urban districts. In the future, more detailed investigation and field tests for all kinds of gas-fired industrial boilers are still greatly needed to achieve more reliable estimations of atmospheric pollutants from gas-fired industrial boilers.

In this article, based on some geometric properties of Banach spaces and one feature of the metric projection, we introduce a new class of bounded linear operators satisfying the so-called $(\alpha,\beta)$ -USU (uniformly strong uniqueness) property. This new convenient property allows us to take the study of the stability problem of the Moore–Penrose metric generalized inverse a step further. As a result, we obtain various perturbation bounds of the Moore–Penrose metric generalized inverse of the perturbed operator. They offer the advantage that we do not need the quasiadditivity assumption, and the results obtained appear to be the most general case found to date. Closely connected to the main perturbation results, one application, the error estimate for projecting a point onto a linear manifold problem, is also investigated.

A high resolution regional emission inventory of typical primary air pollutants (PAPs) for the year 2012 in Beijing and the surrounding five provinces (BSFP) of North China is developed. It is compiled with the combination of bottom-up and top-down methods, based on city-level collected activity data and the latest updated specific emission factors for different sources. The considered sources are classified into 12 major categories and totally 36 subcategories with respect to their multi-dimensional characteristics, such as economic sector, combustion facility or industrial process, installed air pollution control devices, etc. Power plant sector is the dominant contributor of NOX emissions with an average contribution of 34.1%, while VOCs emissions are largely emitted from industrial process sources (33.9%). Whereas, other stationary combustion sources represent major sources of primary PM2.5, PM10 and BC emissions, accounting for 22.7%, 30.0% and 33.9% of the total emissions, respectively. Hebei province contributes over 34% of the regional total CO emissions because of huge volume of iron and steel production. By comparison, Shandong province ranks as the biggest contributor for NOX, PM10, PM2.5, SO2, VOCs and OC. Further, the BSFP regional total emissions are spatially distributed into grid cells with a high resolution of 9 km × 9 km using GIS tools and surrogate indexes, such regional population, gross domestic product (GDP) and the types of arable soils. The highest emission intensities are mainly located in Beijing-Tianjin-Tangshan area, Jinan-Laiwu-Zibo area and several other cities such as Shijiazhuang, Handan, and Zhengzhou. Furthermore, in order to establish a simple method to estimate and forecast PAPs emissions with macroscopic provincial-level statistical parameters in China, multi-parameter regression equations are firstly developed to estimate emissions outside the BSFP region with routine statistics (e.g. population, total final coal consumption, area of cultivated land and possession of civil vehicles) using the software 1stOpt. We find the estimated PAPs emissions of 31 provinces show close correlation with the well-recognized MEIC inventory. This high resolution multi-pollutants inventory provides necessary input data for regional air quality models that could help to identify and appoint the major influence sources, better understand the complex regional air pollution formation mechanism, and benefit for developing the corresponding joint prevention and control policies of regional complex air pollution in North China.

Henan is the most populous province and one of the most seriously polluted areas in China at present. In this study, we establish an integrated atmospheric emission inventory of primary air pollutants in Henan province for the target year of 2012. The inventory developed here accounts for detailed activity levels of 11 categories of primary anthropogenic emission sources, and determines the best available representation of emission factors. Further, we allocate the annual emissions into a high spatial resolution of 3km×3km with ArcGIS methodology and surrogate indices, such as regional population distribution and gross domestic product (GDP). Our results show that the emissions of VOCs, SO2, PM10, PM2.5, NOX, NH3, CO, BC and OC are about 1.15, 1.24, 1.29, 0.70, 1.93, 1.05, 7.92, 0.27 and 0.25milliontons, respectively. The majority of these pollutant emissions comes from the Central Plain Urban Agglomeration (CPUA) region, particularly Zhengzhou and Pingdingshan. By combining with the emission inventory with the WRF/Chem modeling and backward trajectory analysis, we investigate the temporal and spatial variability of air pollution in the province and explore the causes of higher pollutants concentrations in the region of CPUA during the heavily polluted period of January. The results demonstrate that intensive pollutants emissions and unfavorable meteorological conditions are the main causes of the heavy pollution. Besides, Weighted Potential Source Contribution Function (WPSCF) analysis indicates that local emissions remain the major contributor of PM2.5 in Henan province, although emissions from the neighboring provinces (e.g. Shanxi, Shaanxi, Anhui, and Shandong) are also important contributors.

Beijing, the capital of China, revised the emission standard for air pollutants for boilers in 2015. To promote fulfillment of the new standard, the “coal to gas project” and the “reward replaces subsidy policy for low-NOx retrofits of boilers” were implemented recently, and the emission of pollutants from boilers has significantly changed as a result. In this study, a comprehensive unit-based emission inventory of multiple air pollutants, including PM10, PM2.5, CO, SO2, NOx, VOCs and NH3, from both coal-fired and gas-fired industrial boilers in Beijing in 2015 was established with data on annual activity and category-specific emission factors, and scenario analysis and the CMAQ model were used to forecast the environmental impacts of the revised standard during the heating season in Beijing. Our results showed that in 2015, the emissions of CO, NOx, PM2.5, PM10, SO2, NH3 and VOCs from the industrial boilers in Beijing were about 51,745 t, 27,943 t, 10,143 t, 14,624 t, 20,227 t, 197.55 t and 1304 t, respectively. Coal-fired boilers were the major source of CO, SO2, PM2.5 and PM10, while gas-fired boilers were the major source of VOCs and NH3. Furthermore, in IPC-1 and IPC-2 scenarios, which represent the different levels of implementation of the “low-NOx retrofits policy” as well as the replacement of all coal-fired boilers with gas-fired boilers, the ambient concentration of PM2.5 and SO2 was reduced by about 7.1% and 9.5%, respectively, and the concentration of NO2 was reduced by about 4.4% in IPC-1 and 3.7% in IPC-2 during the heating season in Beijing.

Let X = Lp(Ω,μ) (1

The consumption of natural gas in Beijing has increased in the past decade due to energy structure adjustments and air pollution abatement. In this study, an integrated emission inventory of hazardous air pollutants (HAPs) emitted from gas-fired combustion in Beijing was developed for the period from 2000 to 2014 using a technology-based approach. Future emission trends were projected through 2030 based on current energy-related and emission control policies. We found that emissions of primary HAPs exhibited an increasing trend with the rapid increase in natural gas consumption. Our estimates indicated that the total emissions of NO X , particulate matter (PM)10, PM2.5, CO, VOCs, SO2, black carbon, Pb, Cd, Hg, As, Cr, Cu, Ni, Zn, polychlorinated dibenzo-p-dioxins and dibenzofurans, and benzo[a]pyrene from gas-fired combustion in Beijing were approximately 22,422 t, 1042 t, 781 t, 19,097 t, 653 t, 82 t, 19 t, 0.6 kg, 0.1 kg, 43 kg, 52 kg, 0.3 kg, 0.03 kg, 4.3 kg, 0.6 kg, 216 μg, and 242 g, respectively, in 2014. To mitigate the associated air pollution and health risks caused by gas-fired combustion, stricter emission standards must be established. Additionally, combustion optimization and flue gas purification system could be used for lowering NO X emissions from gas-fired combustion, and gas-fired facilities should be continuously monitored based on emission limits.

In order to investigate the effects of the temporary strengthening of air quality assurance controlling measures during the Beijing 2015 IAAF World Championships and the Military Parade Assurance Period (MPAP) in China, we collected daily PM2.5 aerosol samples at three typical sites (urban downtown, suburban and rural background area, respectively) in Beijing and investigated the variations of concentration of the water-soluble ions, elemental constituents, organic carbon (OC) and elemental carbon (EC) in PM2.5 from Aug.15 to Sept.10, 2015. Simultaneously, 1-h high-resolution continuous monitoring results of PM2.5 mass concentration as well as the chemical components which were measured at another online monitoring urban site were incorporated. The concentrations of PM2.5 and other gaseous pollutants (SO2, NO2 and CO) during the parade control period (Aug.20-Sept.3) exhibited a substantially decrease compared with the concentrations during both the non-control (August 15 to August 19 and September 4 to September 10) period and the same period in 2014. According to the CMC results, the major components were identified as secondary inorganic aerosol (SIA, the combination of sulfate, ammonium and nitrate), mineral dust and particular organic matter (POM), which together accounted for more than 80% of PM2.5 in urban and suburban sites. POM is found to account for the largest proportion, and the obviously higher proportion of POM in the urban area revealed the significance contribution from vehicles. Compared with the non-control period, the mass concentrations of SIA and secondary organic carbon (SOC) decreased obviously. However, SIA and SOC are observed to play an important role in contributing to the rapid growth process of PM2.5 under unfavorable meteorological conditions during the control period. In view of the gradual improvement of air quality in Beijing, as well as the contribution of secondary aerosol formations in total PM2.5, effective control of primary gaseous pollutants and volatile organic compounds (VOCs) will be very significant for further lowering the concentration of PM2.5 in Beijing in normal time.

According to the traffic flow variation from January 2019 to August 2020, emissions of primary air pollutants from highway vehicles were calculated based on the emission factor method, which integrated the actual structure of on-road vehicles. The characteristics of on-highway traffic flow and pollution emissions were compared during various progression stages of coronavirus disease (COVID-19). The results showed that the average daily traffic volume decreased by 38.2% in 2020, with a decrease of 62% during the strict lockdown due to the impact of COVID-19. The daily emissions of primary atmospheric pollutants decreased by 29.2% in 2020 compared to the same period in 2019. As for the structure of on-highway vehicle types, the small and medium-sized passenger vehicles predominated, which accounted for 76.3% of traffic, while trucks and large passenger vehicles accounted for 19.7% and 4.0%, but contributed 58.4% and 33.9% of nitrogen oxide (NOx) emissions, respectively. According to the simulation results of the ADMS model, the average concentrations of NOx were reduced by 12.0 µg/m3 compared with the same period in 2019. As for the implication for future pollution control, it is necessary to further optimize the structure of on-highway and the road traffic vehicle types and increase the proportions of new-energy vehicles and vehicles with high emission standards.

Residential coal combustion is considered to be an important source of air pollution in Beijing. However, knowledge regarding the emission characteristics of residential coal combustion and the related impacts on the air quality is very limited. In this study, we have developed an emission inventory for multiple hazardous air pollutants (HAPs) associated with residential coal combustion in Beijing for the period of 2000–2012. Furthermore, a widely used regional air quality model, the Community Multi-Scale Air Quality model (CMAQ), is applied to analyze the impact of residential coal combustion on the air quality in Beijing in 2012. The results show that the emissions of primary air pollutants from residential coal combustion have basically remained the same levels during the past decade, however, along with the strict emission control imposed on major industrial sources, the contribution of residential coal combustion emissions to the overall emissions from anthropogenic sources have increased obviously. In particular, the contributions of residential coal combustion to the total air pollutants concentrations of PM 10 , SO 2 , NO X , and CO represent approximately 11.6%, 27.5%, 2.8% and 7.3%, respectively, during the winter heating season. In terms of impact on the spatial variation patterns, the distributions of the pollutants concentrations are similar to the distribution of the associated primary HAPs emissions, which are highly concentrated in the rural-urban fringe zones and rural suburb areas. In addition, emissions of primary pollutants from residential coal combustion are forecasted by using a scenario analysis. Generally, comprehensive measures must be taken to control residential coal combustion in Beijing. The best way to reduce the associated emissions from residential coal combustion is to use economic incentive means to promote the conversion to clean energy sources for residential heating and cooking. In areas with reliable energy supplies, the coal used for residential heating can be replaced with gas-burning wall-heaters, ground-source heat pumps, solar energy and electricity. In areas with inadequate clean energy sources, low-sulfur coal should be used instead of the traditional raw coal with high sulfur and ash content, thereby slightly reducing the emissions of PM, SO 2 , CO and other toxic pollutants.

China has become the largest producer of iron and steel throughout the world since 1996. However, as an energy-and-pollution intensive manufacturing sector, a detailed comprehensive emission inventory of air pollutants for iron and steel industry of China is still not available. To obtain and better understand the temporal trends and spatial variation characteristics of typical hazardous air pollutants (HAPs) emissions from iron and steel production in China, a comprehensive emission inventory of multiple air pollutants, including size segregated particulate matter (TSP/PM10/PM2.5), gaseous pollutants (SO2, NOx, CO), heavy metals (Pb, Cd, Hg, As, Cr, Ni etc.), as well as the more dangerous PCDD/Fs, is established with the unit-based annual activity, specific dynamic emission factors for the historical period of 1978-2011, and the future potential trends till to 2050 are forecasted by using scenario analysis. Our results show that emissions of gaseous pollutants and particulate matter have experienced a gradual increase tendency since 2000, while emissions of priority-controlled heavy metals (Hg, Pb, As, Cd, Cr, and Ni) have exhibited a short-term fluctuation during the period of 1990 to 2005. With regard to the spatial distribution of HAPs emissions in base year 2011, Bohai economic circle is identified as the top emission intensity region where iron and steel smelting plants are densely built; within iron and steel industry, blast furnaces contribute the majority of PM emissions, sinter plants account for most of gaseous pollutants and the majority of PCDD/Fs, whereas steel making processes are responsible for the majority of heavy metal emissions. Moreover, comparisons of future emission trends under three scenarios indicate that advanced technologies and integrated whole process management strategies are in great need to further diminish various hazardous air pollutants from iron and steel industry in the future.

Coal-fired combustion is recognized as a significant anthropogenic source of atmospheric compounds in Beijing, causing heavy air pollution events and associated deterioration in visibility. Obtaining an accurate understanding of the temporal trends and spatial variation characteristics of emissions from coal-fired industrial combustion is essential for predicting air quality changes and evaluating the effectiveness of current control measures. In this study, an integrated emission inventory of primary air pollutants emitted from coal-fired industrial boilers in Beijing is developed for the period of 2007–2013 using a technology-based approach. Future emission trends are projected through 2030 based on current energy-related and emission control policies. Our analysis shows that there is a general downward trend in primary air pollutants emissions because of the implementation of stricter local emission standards and the promotion by the Beijing municipal government of converting from coal-fired industrial boilers to gas-fired boilers. However, the ratio of coal consumed by industrial boilers to total coal consumption has been increasing, raising concerns about the further improvement of air quality in Beijing. Our estimates indicate that the total emissions of PM 10 , PM 2.5 , SO 2 , NO x , CO and VOCs from coal-fired industrial boilers in Beijing in 2013 are approximately 19,242 t, 13,345 t, 26,615 t, 22,965 t, 63,779 t and 1406 t, respectively. Under the current environmental policies and relevant energy savings and emission control plans, it may be possible to reduce NO x and other air pollutant emissions by 94% and 90% by 2030, respectively, if advanced flue gas purification technologies are implemented and coal is replaced with natural gas in the majority of existing boilers.

s A multiple-year comprehensive emission inventory of typical hazardous air pollutants (HAPs) from China's cement industry for the period 1980–2012, has been established by using technology-based dynamic emission factors and detailed annual plant-specific cement production from different types of kilns. Our results show that the total emissions of various HAPs (SO 2 , NO X , CO, PM, Hg, Cd, Cr, Pb, Zn, As, Ni and Cu) have rapidly increased by about 1–21 times at an annual average growth rate of 1–10% over the past three decades. Remarkably uneven spatial allocation features of these pollutants among provinces are observed. HAPs emissions are primarily concentrated in the eastern and coastal provinces due to the concentration of cement plants and their huge volume of coal consumption. We predict the future emission trends of HAPs through 2050 based on industry construction and policy guidance, and our scenario analysis indicates that HAPs emissions will drop substantially because of the combined effects of cement production yields reduction and the increasing application rate of various air pollution control devices. The study suggests that highlighted attention should be paid to this energy-intensive industry to ensure stricter emission standards are implemented for these HAPs emissions in the future.

China is the most populous country in the world. The amount of death population has reached 9.65 million and 49.5% of human corpses are cremated by about 1700 crematories spread throughout the country in 2012, leading to considerable discharge of various hazardous air pollutants (HAPs) into the atmosphere and great concerns on regional air quality and health risks for surrounding residents. By using the practicable or best available emission factors, for the first time, a multiple-year emission inventory of typical hazardous air pollutants discharged from crematories in the Chinese mainland, has been established for the historical period of 1990–2012, and the future trends of HAPs emissions until 2030 are forecasted based on three scenarios analysis. Our results show that the total emissions have gradually increased to 906 t of NO X , 443 t of SO 2 , 2713 t of CO, 477.7 t of PM, 377 t of HCl, 36 t of H 2 S, 25 t of NH 3 , 62 t of NMVOCs, 592 kg of Hg, 48 kg of Pb, 14 kg of Cd, 53 kg of As, 40 kg of Cr, 37 kg of Cu, 51 kg of Ni, and 96 g of PCDD/Fs as TEQ (toxic equivalent quantity) by the year 2012. Under the business-as-usual (BAU) scenario, various HAPs emitted from cremators would continuously increase with an average growth rate of 3% till to 2030; whereas the emissions will peak at around 2015 and then decline gradually with varied speed under the two improved control scenarios. To mitigate the associated air pollution and health risks caused by crematories, it is of great necessary for implementing more strict emission standards, applying combustion optimization and requiring installation of best available flue gas purification system, as well as powerful supervision for sound operation of crematories.

Water cooling is the main measure to reduce temperature cracks in RCC dams. But later cooling usually means reducing water temperature rapidly after 120 days of the concrete age, which may cause larger self stress and tensile stress inside the concrete. The small temperature difference cooling can advance the starting time of middle and late cooling stages, and reduce the temperature stress effectively. However, the difference of temperature stress produced by different middle and late stages water cooling methods is large. It is necessary to analyse precisely how to use the small temperature difference methods in the middle and late cooling stages of dams properly. The cooling methods of RCC dam in the middle and late stages are studied by using the self-developed 3-D FEM floating mesh method temperature controlling simulation program. Result shows that when the small temperature difference is used to cool the dam in the middle and late stages, the temperature and temperature stress of the dam reduces obviously. When the age of the concrete is over, the dam should be cooled immediately, several levels of water temperature should be set in the middle and late cooling stages, the temperature of the water should be reduced slowly, which can reduce the temperature and temperature stress of the dam effectively. Study result will provide a favourable reference for practical projects.

This paper presents a hyperbolic erosion rate model and a calculating circular slip surface method of lateral enlargement, and obtain a numerical analysis method of the relative stability dam-breach flood analysis. This paper develops a DB-IWHR procedure based on this principle, preparing a dam breach flood procedure is simple, easy to understand and use program in Excel 2010 spreadsheet. This improves this program, and writes a flood regulation calculation program, forming a complete program of dam breach flood and flood regulation. This paper calculates Hongshiyan barrier lake breach flood flow and the reservoirs downstream impacts.

Natural sources, such as soil and wind-erosion dust (SWD), biomass open burning (BOB), sea salt spray (SSAS) and biogenic source (BIO), are major contributors to atmospheric emissions of trace elements (TEs) globally. In this study, we used a comprehensive approach to account for area-, production- and biofuel consumption-based emission factor calculation methods, and thus developed an integrated high-resolution emission inventory for 15 types of TEs (As, B, Cd, Co, Cr, Cu, Hg, Mn, Mo, Ni, Pb, Sb, Se, V and Zn) originated from natural sources in China for the year 2015. The results show that national emissions of TEs in 2015 range from 7.45 tons (Hg) to 1, 400 tons (Zn) except for the extremely high emissions of Mn (10, 677 tons). SWD and BIO are identified as the top two source contributors, accounting for approximately 67.7% and 26.1% of the total emissions, respectively. Absolute emissions of TEs from natural sources are high in the Xinjiang, Inner Mongolia and Tibet autonomous regions with large areas of bare soil and desert. However, emission intensity of TEs per unit area in the Southern provinces of China is higher than those in Northern China and Southwestern China, with the Yunnan and Sichuan provinces displaying the highest emission intensity. Our results suggest that controlling SWD can play a significant role in reducing fugitive particulate matter and the associated emissions of TEs from natural sources in China; and desertification control is particularly critical in the Northwest provinces where the majority of deserts are located.

The process of corpse cremation generates numerous harmful air pollutants, including particulate matter (PM), sulfur dioxide (SO2), nitrogen oxides (NOx), volatile organic compounds (VOCs), and heavy metals. These pollutants could have severe effects on the surrounding environment and human health. Currently, the awareness of the emission levels of harmful air pollutants from cremators and their emission characteristics is insufficient. In this study, we obtained the emission characteristics of flue gas from cremators in Beijing and determined the localized emission factors and emission levels of harmful air pollutants based on actual monitoring data from nine typical cremators. The results show that the emissions of air pollutants from the cremators that directly discharge flue gas exceed the emission standards of China and Beijing. The installation of a flue gas post-treatment system could effectively reduce gaseous pollutants and the emission levels of PM. After being equipped with a flue gas post-treatment system, the emission concentrations of PM10, PM2.5, CO, SO2 and VOCs from the cremators are reduced by 97.6, 99.2, 19.6, 85.2 and 70.7%, respectively. Moreover, the emission factors of TSP, PM10, PM2.5, CO, SO2 and VOCs are also reduced to 12.5, 9.3, 3.0, 164.1, 8.8 and 19.8 g/body. Although the emission concentration of VOCs from the cremators is not high, they are one of major sources of “odor” in the crematories and demand more attention. Benzene, a chemical that can seriously harm human health, constitutes the largest proportion (~50%) of the chemical components of VOCs in the flue gas from the cremators.

This paper presents the scenario forecast of global atmospheric antimony (Sb) emissions from anthropogenic activities till 2050. The projection scenarios are built based on the comprehensive global antimony emission inventory for the period 1995–2010 which is reported in our previous study. Three scenarios are set up to investigate the future changes of global antimony emissions as well as their source and region contribution characteristics. Trends of activity levels specified as 5 primary source categories are projected by combining the historical trend extrapolation with EIA International energy outlook 2013, while the source-specific dynamic emission factors are determined by applying transformed normal distribution functions. If no major changes in the efficiency of emission control are introduced and keep current air quality legislations (Current Legislation scenario), global antimony emissions will increase by a factor of 2 between 2010 and 2050. The largest increase in Sb emissions is projected from Asia due to large volume of nonferrous metals production and waste incineration. In case of enforcing the pollutant emission standards (Strengthened Control scenario), global antimony emissions in 2050 will stabilize with that of 2010. Moreover, we can anticipate further declines in Sb emissions for all continents with the best emission control performances (Maximum Feasible Technological Reduction scenario). Future antimony emissions from the top 10 largest emitting countries have also been calculated and source category contributions of increasing emissions of these countries present significant diversity. Furthermore, global emission projections in 2050 are distributed within a 1° × 1°latitude/longitude grid. East Asia, Western Europe and North America present remarkable differences in emission intensity under the three scenarios, which implies that source-and-country specific control measures are necessary to be implemented for abating Sb emissions from varied continents and countries in the future.

Let be a unital -algebra, a, x and y are elements in . In this paper, we present the expression of the Moore-Penrose inverse and the group inverse of a- under the conditions , respectively.

Mesenchymal stem cells (MSCs) can be obtained from a variety of human tissues. Placenta has become an attractive stem cell source for potential applications in regenerative medicine and tissue engineering. The aim of this study was to localize and characterize MSCs within human chorionic membranes (hCMSCs). For this purpose, immunofluorescence labeling with CD105 and CD90 were used to determine the distribution of MSCs in chorionic membranes tissue. A medium supplemented with a synthetic serum and various concentrations of neurotrophic factors and cytokines was used to induce hCMSCs to neural cells. The results showed that the CD90 positive cells were scattered in the chorionic membranes tissue, and the CD105 positive cells were mostly located around the small blood vessels. hCMSCs expressed typical mesenchymal markers (CD73, CD90, CD105, CD44 and CD166) but not hematopoietic markers (CD45, CD34) and HLA-DR. hCMSCs differentiated into adipocytes, osteocytes, chondrocytes, and neuronal cells, as revealed by morphological changes, cell staining, immunofluorescence analyses, and RT-PCR showing the tissue-specific gene presence for differentiated cell lineages after the treatment with induce medium. Human chorionic membranes may be the source of MSCs for treatment of nervous system injury.

Background To establish a novel method based on time-resolved immunofluorometric assay (TR-IFMA) with higher sensitivity and a broader detection range for detecting serum hepatitis B virus large surface protein (L protein). Methods The precision, sensitivity, specificity, coefficient of recovery, and stability of the assay were evaluated and comparison with the classical enzyme-linked immunosorbent assay (ELISA) was also executed. Results The precision, specificity, and sensitivity of the TR-IFMA were clearly better than ELISA. Particularly, the sensitivity was 0.1 ng/ml; moreover, the specificity was 100%, 96%, 92.5%, 96.9%, 97.8%, and 100% in the sera of healthy blood donors, systemic lupus erythematosus (SLE) patients, rheumatoid arthritis (RA) patients, hepatitis C virus (HCV) patients, cytomegalovirus (CMV) infection patients, and pregnant patients, respectively. Meanwhile, we observed that the established TR-IFMA kit has a wider acceptable linear range of 0.63–10,367 ng/ml rather than the regular commercial ELISA kit having range of only 10.12–1095.9 ng/ml. Subsequently, correlation coefficient between the TR-IFMA and ELISA was 0.8009. The intra- and interassay precision rates were less than 5% for three different concentrations. The average recovery rate for L protein was 101.17%. In sum, the established assay kit performed better in terms of stability than the commercial ELISA kit. Conclusion The TR-IFMA that we developed for L protein presented a higher sensitivity and wider detecting range than regular commercial ELISA. Therefore, this TR-IFMA has promising value both in the screening of HBV and monitoring of antiviral therapy.

In this paper, we present the explicit expression for the group inverse of the sum of two matrices. As an application, the explicit expression for the group inverse of the anti-triangular block matrix $\begin{pmatrix}A&B\\C&0\end{pmatrix}$ and $\begin{pmatrix}0&B\\C&D\end{pmatrix}$ are obtained without any conditions on sub-blocks

The incineration of sacrificial offerings generates numerous hazardous air pollutants, including particulate matter (PM), CO, SO2, NOx and non-methane hydrocarbons (NMHC), which has significant effects on the environment and human health. However, due to the concealment of sacrificial offerings incineration, the emission of such pollutants has not received sufficient attention. Relevant quantification of the emission, emission factors and pollution control measures for this pollution source are lacking. To address these problems, herein, we quantified the particulate matter and its chemical composition and the emission levels of gaseous pollutants, including SO2, NOx, NMHC and CO, by performing incineration experiments of four typical sacrificial offerings (Joss paper, Funeral wreath, Taoist paper art and Yuanbao paper), and obtained the emission factors and emission characteristics for the incineration of sacrificial offerings. Therefore, this study lays the foundation and provides support for establishing an emission inventory of the air pollutants from the incineration of sacrificial offerings and introducing corresponding pollution control measures. The results show that the emission concentrations of CO and total suspended particulate (TSP) from the incineration of sacrificial offerings greatly exceed the emission standard, with averages of 621.4 mg m&minus, 3 and 142.9 mg m&minus, 3 at 11% oxygen content, respectively. The average emission factors of SO2, NOx, NMHC, CO, PM10 and PM2.5 for the incineration of the four offerings are (0.47 &plusmn, 0.17) kg t&minus, 1, (2.46 &plusmn, 0.35) kg t&minus, 1, (5.78 &plusmn, 2.41) kg t&minus, 1, (32.40 &plusmn, 8.80) kg t&minus, 1, (4.23 &plusmn, 0.71) kg t&minus, 1 and (2.62 &plusmn, 0.48) kg t&minus, 1, respectively, among which the emission intensities of NMHC and CO are relatively high. Among the different types of sacrificial offerings, the overall average emission factor of air pollutants generated from the incineration of Yuanbao paper is the highest, which is mainly due to the low burning efficiency and the coating material. For the chemical composition of the particulate matters, ions, OC, EC and metal elements account for proportions of the PM2.5 at (23.55 &plusmn, 10.37) %, (29.74 &plusmn, 9.95) %, (14.83 &plusmn, 6.55) % and (13.45 &plusmn, 4.88) %, respectively, indicating that the organic pollution is severe

Let and be Banach spaces, and let be a bounded linear operator. In this paper, we first define and characterize the quasi-linear operator (resp., out) generalized inverse (resp., ) for the operator , where and are homogeneous subsets. Then, we further investigate the perturbation problems of the generalized inverses and . The results obtained in this paper extend some well-known results for linear operator generalized inverses with prescribed range and kernel.

Let $\R $ be a ring with unit 1 and $a\in \R, \bar{a}=a+��a\in \R $ such that $a^#$ exists. In this paper, we mainly investigate the perturbation of the group inverse $a^#$ on $\R$. Under the stable perturbation, we obtain the explicit expressions of $\bar{a}^#$. The results extend the main results in Xue (2007), and Xue and Chen (2007) and some related results in Xue (2012). As an application, we give the representation of the group inverse of the matrix d&b c&0 on the ring $\R$ for certain $d, b, c\in\R$., 10 pages, Filomat (accepted)

In this paper, we investigate the various different generalized inverses in a Banach algebra with respect to prescribed two idempotents $p$ and $q$. Some new characterizations and explicit representations for these generalized inverses, such as $a^{(2)}_{p,q}$, $a^{(1,2)}_{p,q}$ and $a^{(2,l)}_{p,q}$ will be presented. The obtained results extend and generalize some well--known results for matrices or operators., 17 pages

The mass concentration and major chemical components of fine particulate matter were measured before, during and after Beijing's massive parade commemorating 70th anniversary of the Chinese Victory in World War II on September 3, 2015. Regional emission inventory, positive matrix factorization (PMF), observations from space and backward air mass trajectories were jointly applied to identify the major pollution sources and their temporal and spatial variations. The contributions of emissions variations and the meteorological conditions related to the “parade blue” phenomenon in Beijing and its surrounding areas were investigated in detail. The main cause of the decreased PM 2.5 mass concentration was attributed to the absolute reduction in emissions of primary air pollutants. The chemical composition of PM 2.5 varied significantly before, during and after the parade. Fugitive dust particles were well controlled, the secondary formation of PM 2.5 was reduced along with the controlled gaseous precursors' emissions from vehicles and industrial sources during the temporary intensified control period. During the parade period, the SO 2 and NO 2 column concentrations in Beijing and the surrounding areas decreased sharply, indicating that the coordinated reduction in primary emissions from the surrounding areas of Beijing played an important role in lowering the ambient concentration of SO 2 and NO 2 and accordingly lowered PM 2.5 and improved the regional air quality. A comparison of the temperature, humidity, and wind speed and direction during the same periods in 2014 and 2015 showed that the meteorological conditions positively influenced the achievement of “parade blue”.

Let $\A$ and $\B$ be unital Banach algebras and $\phi\colon\A\to\B$ be a unital continuous homomorphism. We prove that if $\phi$ is relatively spectral (i.e., there is a dense subalgebra $X$ of $\A$ such that $\sp_\B(\phi(a))=\sp_\A(a)$ for every $a\in X$) and has dense range, then $\phi$ induces monomorphisms from $K_i(\A)$ to $K_i(\B)$, $i=0,1$., Comment: 6 pages

In this article, we give the density functions of the singular quaternion normal matrix and the singular quaternion Wishart matrix. Furthermore, we also give the density functions of certain singular quaternion β-matrix and the singular quaternion F-matrix in terms of the density function of the singular quaternion Wishart matrix and hypergeometric functions of quaternion matrix argument.

Let M be a separable compact Hausdorff space with dim M ? 2 and ? : M ? M be a homeomorphism with prime period p (p ? 2). Set M? = {x ( M|?(x) = x} = ( and M0 = M\M? . Suppose that M0 is dense in M and H2(M0/?, Z) ( 0, H2(?(M0/?), Z) ( 0. Let M' be another separable compact Hausdorff space with dim M' ? 2 and ?' be the self-homeomorphism of M' with prime period p. Suppose that M'0 = M'\M'?' is dense in M'. Then C(M) ? ?Zp ( C(M') ? ?'Zp if there is a homeomorphism F from M/? onto M'/?' such that F(M?) = M'?'. Thus, if (M, ?) and (M', ?') are orbit equivalent, then C(M) ? ?Zp ( C(M') ? ?'Zp. 2010 Mathematics Subject Classifications. 46L05. .

We define zonal polynomials of quaternion matrix argument and deduce some important formulae of zonal polynomials and hypergeometric functions of quaternion matrix argument. As an application, we give the distributions of the largest and smallest eigenvalues of a quaternion central Wishart matrix $W\sim\mathbb{Q}W(n,\Sigma)$, respectively., Comment: 22 pages. Communications in Statistics - Theory and Methods (appear)