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1. Effects of 1-Butanol on Emission Spectrum of 4-Phenyl-1-N,N-dimethylaminobutane in THF: Separation into Polar and Hydrogen-Bonding Interactions

Author

Mayuko Nakamura, Yoshimi Sueishi, Shunzo Yamamoto, and Xie Guobin

Subjects
chemistry.chemical_compound, chemistry, Hydrogen bond, Butanol, Polar effect, Polar, Protonation, General Chemistry, Emission spectrum, Trichloroacetic acid, Photochemistry, Acetonitrile, Medicinal chemistry
Abstract

The effects of the addition of 1-butanol (BuOH), trichloroacetic acid (TCAA) and acetonitrile (AN) on the emission spectrum of 4-phenyl-1-N,N-dimethylaminobutane in THF have been studied. The results show that AN has only a polar effect and TCAA only a hydrogen-bonding (or protonation) effect, while BuOH has both effects. The relative magnitude of each effect was evaluated as a function of vol% of BuOH.

Published
2002

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