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The degradation of the insulation system in liquid-filled power transformers is a serious concern for electric power utilities. The insulation system’s ageing is accelerated by moisture, acids, oxidation products, and other decay particles (soluble and colloidal). The presence of these ageing by-products is detrimental to the insulation system and may further lead to premature ageing and serious consequences. The ageing mechanisms of oil-paper insulation are complex, highly interrelated, and strongly temperature-dependent. The operating temperature of the transformer insulating system has a direct relationship with the loading profile. The major aspect that is witnessed with the fluctuating temperatures is moisture migration and subsequent bubble evolution. In other words, gas bubbles evolve from the release of water vapor from the cellulosic insulation wrapped around the transformer windings. The models presented in the existing standards, such as the IEC Std. 60076-7:2018 and the IEEE Std. C57.91:2011, are mainly based on the insulation temperature, which acts as a key parameter. Several studies have investigated the moisture dynamics and bubbling phenomenon as a function of the water content in the paper and the state of the insulation system. Some studies have reported different prototypes for the estimation of the bubble inception temperatures under selected conditions. However, there are various attributes of the insulation system that are to be considered, especially when expanding the models for the alternative liquids. This paper reviews various evaluation models reported in the literature that help understand the bubbling phenomenon in transformer insulation. The discussions also keep us in the loop on the estimation of bubbling behavior in alternative dielectric liquids and key attributable factors for use in transformers. In addition, useful tutorial elements focusing on the bubbling issue in transformers as well as some critical analyses are addressed for future research on this topic.

Generally, impregnation of solid insulation is performed to increase the dielectric strength and reduce the dielectric losses of solid insulants. This increase in dielectric strength depends on the oil’s diffusion and dielectric properties. This paper investigates the diffusion behavior of mineral oil and ester fluids (synthetic, natural, and mixed) to understand the influence of oil diffusion on paper breakdown voltage. To better understand this phenomenal influence, cellulose insulation paper of different thicknesses has been considered. Wetting characteristics of various oil-paper insulation systems were investigated with and without thermal stressing. Thermal aging was carried out as per modified ASTM D1934 at 110 °C, 140 °C, 160 °C, and 185 °C respectively for 2 weeks. The wetting characteristics and influence of different oils on paper breakdown voltage were explicitly reported. It is inferred that paper wetting characteristics are attributable to the type of oil, the thickness of paper, and the aging factor of oil-paper insulation. Importantly, the increase in paper dielectric strength and diffusion behavior for ester fluids is found to be superior to that of the mineral insulating oils.

The service of mineral insulating oils for power transformer insulation and cooling aspects cannot be disavowed. However, the continued use of mineral oils is questionable due to environmental unfriendliness and the divestment from fossil fuels. This has provoked the quest for green alternative insulating liquids for high-voltage insulation. Natural esters are among the remaining alternatives that are renewable and environmentally friendly. Regardless of their environmental and technical merits, natural esters have some limitations that are slowing down their total acceptance by transformer owners and utilities. Critical limitations and concerns include esters’ pour point, viscosity, oxidative stability, and ionization resistance. In this work, the state of the art of “natural esters for transformers” is explored with the aim of potential improvements. The sections of the article are geared towards technical viewpoints on improving the overall workability and serviceability of natural esters in high-voltage applications. A comprehensive review of the existing literature is achieved, based on performance improvements of the natural ester using “additives” and “chemical modification”. The authors hope that this report may be helpful to transformer owners as well as influence the progression of natural esters for power transformer applications.

Oxidation of oil/paper insulation initiates premature aging and introduces carboxylic acids with eventual increase in oil acidity, which hampers the properties of the oil. In this paper, a membrane separation technology-based purification process for aged insulation oil has been evaluated and reported. The intent of the present study is to eliminate carboxylic acids, dissolved decay contents and other colloidal contamination present in aged oil and enhance the useful life of oil. The potential of the membrane treatment process has been demonstrated using Ultraviolet Visible Infrared Spectroscopy and Fourier Transform Infrared Spectroscopy diagnostic measurements for oil and membrane. Additionally, membrane retention properties like membrane flux, retention coefficient, sorption time and membrane mass have been analyzed to understand the treatment process. To further evaluate the performance of the membrane and effectiveness of the treatment process, acidity, dielectric dissipation factor, relative permittivity, and resistivity measurements of the oil before and after filtration have been also reported. The proposed membrane purification method has been tested for Algerian utility in-service oil samples. It is inferred that, membrane filtration method is a simple and effective method for treatment of aged oils and aids in extending the remnant life of the oil. The procedure is economically attractive because of increasing prices for transformer liquids, cost effective and environmentally sounds.